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- In relation to this article, we declare that there is no conflict of interest.
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Received January 1, 2015
Accepted May 12, 2015
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Preparation of monodisperse poly(styrene-co-divinylbenzene) microspheres by vibration dispersion method
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, P. R. China
Korean Journal of Chemical Engineering, January 2016, 33(1), 312-318(7), 10.1007/s11814-015-0099-6
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Abstract
Monodisperse micron-size poly(styrene-co-divinylbenzene) (PST-DVB) microspheres were successfully prepared by vibration dispersion. A vibrator was used to generate a controlled vibration to jet from a single nozzle of 200 μm to produce uniform droplets. The effects of variations in selected process parameters upon the droplets formation and the diameter of the microspheres were investigated. It was demonstrated that changes in the velocity of oil phase, drive frequency and destabilization amplitude have significant effects on the formation of uniform droplets and the average diameter of the microspheres. Rational polynomial regression equations of the above parameters were established. Based on these equations, we could calculate the operation conditions to produce uniform droplets with the desirable diameter.
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References
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Sun TH, Cao LK, Jia JP, Chromatographia, 61, 173 (2005)
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Yu P, Sun QL, Pan JM, Tan ZJ, Dai JD, Yan YS, Cheng F, Adsorpt. Sci. Technol., 31, 641 (2013)
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Ogino K, Sato H, Tsuchiya K, Suzuki H, Moriguchi S, J. Chromatogr. A, 699, 59 (1995)
Kim CH, Park JG, Kim JW, Jun JB, Park JH, Suh KD, Korean J. Chem. Eng., 20(2), 399 (2003)
Zhu XX, Zhang JH, Gauthier M, Luo JT, Meng FS, Brisse F, J. Comput. Chem., 8, 79 (2006)
Sung UC, Yoon CN, Kim SG, Korean J. Chem. Eng., 14(1), 15 (1997)
Zhao CX, Middelberg APJ, Chem. Eng. Sci., 66(7), 1394 (2011)
Lazarus LL, Riche CT, Marin BC, Gupta M, Malmstadt N, Brutchey RL, ACS Appl. Mater Interfaces, 4, 3077 (2012)
Dumouchel C, Exp. Fluids, 45, 371 (2008)
McCarthy MJ, Molloy NA, Chem. Eng. J., 7, 1 (1974)
Sakai T, Koshino N, J. Chem. Eng. Jpn., 13, 267 (1980)
Paul A, Hass, Ind. Eng. Chem. Res., 31, 959 (1992)
Armster SQ, Delplanque JP, Lai WHL, Lavernia EJ, Metall. Mater. Trans. B-Proc. Metall. Mater. Proc. Sci., 31, 1333 (2000)
