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Received February 14, 2015
Accepted May 14, 2015
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Synthesis and characterization of polyhedral oligomeric silsesquioxane-based waterborne polyurethane nanocomposites
Polyurethane and Advanced Polymers Department, Faculty of Science, Iran Polymer and Petrochemical Institute, Tehran, Iran 1Biocompatible Polymers Department, Faculty of Science, Iran Polymer and Petrochemical Institute, Tehran, Iran
m.barmar@ippi.ac.ir
Korean Journal of Chemical Engineering, January 2016, 33(1), 319-329(11), 10.1007/s11814-015-0102-2
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Abstract
A series of aqueous polyurethane nanocomposites were prepared using various amounts (0.3-4.6 wt%) of a diol functionalized polyhedral oligomeric silsesquioxane (POSS) by the prepolymer mixing method. N,N-bis(2-hydroxy ethyl-2-amino ethane sulfonic acid sodium salt (BES sodium salt) was used as the anionic internal emulsifier and ionic center. The molecular structure of the samples was characterized by ATR-FTIR spectroscopy. We investigated the effect of the POSS contents on the properties of the specimens by particle size and viscosity measurements, X-ray diffractometry, mechanical behavior assessment, dynamic mechanical thermal analysis (DMTA), thermogravimetric analysis and morphological studies. The results showed that with increasing the POSS contents, particle size, viscosity, tensile strength, modulus, Tg, and thermal stability of the synthesized samples were improved. Also, SEM and TEM images indicated that a homogeneous morphology was obtained in the 1.2 wt% POSS-based sample. AFM results showed that the surface roughness increased as the POSS amounts increased.
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Nanda AK, Wicks DA, Madbouly SA, Otaigbe JU, Macromolecules, 39(20), 7037 (2006)
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Grassie N, Scott G, Polymer degradation and stabilisation, Cambridge University, London (1985).
Liu HZ, Zheng SX, Macromol. Rapid Commun., 26(3), 196 (2005)
Zhang S, Zou Q, Wu L, Macromol. Mater. Eng., 291, 895 (2006)
Kourkoutsaki T, Logakis E, Kroutilova I, Matejka L, Nedbal J, Pissis P, J. Appl. Polym. Sci., 113(4), 2569 (2009)
Zhang WH, Fu BX, Seo Y, Schrag E, Hsiao B, Mather PT, Yang NL, Xu DY, Ade H, Rafailovich M, Sokolov J, Macromolecules, 35(21), 8029 (2002)
Dong WP, Sullivan PJ, Stout KJ, Wear, 178, 29 (1994)
Aneja A, Wilkes GL, Polymer, 44(23), 7221 (2003)
Bliznyuk VN, Tereshchenko TA, Gumenna MA, Gomza YP, Shevchuk AV, Klimenko NS, Shevchenko VV, Polymer, 49(9), 2298 (2008)
