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Received April 10, 2015
Accepted June 20, 2015
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Characteristics and intermolecular interaction of eutectic binary mixtures: Reline and Glyceline
Petroleum and Chemical Engineering Department, Sultan Qaboos University, Oman
Korean Journal of Chemical Engineering, January 2016, 33(1), 337-343(7), 10.1007/s11814-015-0134-7
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Abstract
Deep Eutectic Solvents are promising greener and cheaper alternatives to ionic liquids. The applications involving these solvents depend largely on their physical and chemical properties. However, a DES may possess both desirable and undesirable properties for a certain application. In such situations, mixing two DESs, each possessing a unique set of properties, may yield one with a more suitable set of physical and chemical properties for the same application. In this work, the variation in the physical properties of Reline upon addition of Glyceline was investigated. While a positive deviation of excess molar volume was observed, a negative deviation of viscosity was recorded with the increase in Glyceline mol% indicating a disruption of the ordered structure of Reline. The highest deviation in both cases was observed at 30 mol% Glyceline. The physical properties measured were density, viscosity, pH, RI and conductivity. The Glyceline molar percentage studied was 0 to 100mol% while temperature was varied within the range of 20 oC to 80 oC.
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References
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Liu YG, Daum PH, J. Aerosol Sci., 39(11), 974 (2008)
