Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received September 25, 2014
Accepted May 12, 2015
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Selective hydrogenation of sunflower oil over Ni catalysts
Department of Chemical Engineering, Faculty of Pharmacy, University of the Basque Country UPV/EHU, Paseo de la Universidad, 7, 01006 Vitoria, Spain
unai.iriarte@ehu.eus
Korean Journal of Chemical Engineering, January 2016, 33(1), 80-89(10), 10.1007/s11814-015-0095-x
Download PDF
Abstract
This work focuses on the influence of the support and the preparation method on the activity and selectivity of nickel catalysts in the hydrogenation of sunflower oil. Catalysts were prepared over silica and alumina supports following the incipient wetness impregnation and deposition-precipitation techniques. The activation process was followed by temperature-programmed reduction (TPR). Precipitation-deposition method allowed a stronger metal-support interaction than incipient wetness impregnation. A precipitation-deposition time of 14 h (which allowed a Ni loading of about 20wt%) was deemed as the most adequate from the standpoint of high specific surface area and strong Ni-support interaction. The selectivity to oleic acid was not affected by the preparation method, but it was significantly influenced by the type of support. In this regard, the catalysts prepared on silica are more active and produce less saturated fatty acids.
References
Gunstone FD, Harwood JL, Dijkstra AJ, 3rd Ed. (2007).
Zaccheria F, Psaro R, Ravasio N, Bondioli P, Eur. J. Lipid Sci. Technol., 114(1), 24 (2012)
Lee KW, Hailan C, Yinhua J, Kim YW, Chung KW, Korean J. Chem. Eng., 25(3), 474 (2008)
Regulation (EU), Official Journal of theEuropean Union, 343, No 1169/2011, 18 (2011).
Philippaerts A, Jacobs PA, Sels BF, Angew. Chem.-Int. Edit., 52(20), 5220 (2013)
Balakos MW, Hernandez EE, Catal. Today, 35(4), 415 (1997)
Dijkstra AJ, Eur. J. Lipid Sci. Technol., 108(3), 249 (2006)
Lee JH, Kim SK, Ahn IY, Kim WJ, Moon SH, Korean J. Chem. Eng., 29(2), 169 (2012)
McArdle S, Curtin T, Leahy JJ, Appl. Catal. A: Gen., 382(2), 332 (2010)
McArdle S, Girish S, Leahy JJ, Curtin T, J. Mol. Catal. A-Chem., 351, 179 (2011)
Aguinaga A, Delacal JC, Asua JM, Montes M, Appl. Catal., 51(1), 1 (1989)
Burattin P, Che M, Louis C, J. Phys. Chem. B, 103(30), 6171 (1999)
Ermakova MA, Ermakov DY, Cherepanova SV, Plyasova LN, J. Phys. Chem. B, 106(46), 11922 (2002)
Coenen JWE, Ind. Eng. Chem. Fundam., 25(1), 43 (1986)
Rodrigo MT, Daza L, Mendioroz S, Appl. Catal. A: Gen., 88(1), 101 (1992)
Hermans LAM, Geus JW, Stud. Surf. Sci. Catal., 2(3), 113 (1979)
Cai W, Ye L, Zhang L, Ren Y, Yue B, Chen X, He H, Materials, 7(3), 2340 (2014)
Song W, Zhao C, Lercher JA, Chem.-Eur. J., 19(30), 9833 (2013)
Bartholomew CH, Farrauto RJ, J. Catal., 45(1), 41 (1976)
Piqueras C, Bottini S, Damiani D, Appl. Catal. A: Gen., 313(2), 177 (2006)
Fillion B, Morsi BI, Heier KR, Machado RM, Ind. Eng. Chem. Res., 41(4), 697 (2002)
Zaccheria F, Psaro R, Ravasio N, Bondioli P, Eur. J. Lipid Sci. Technol., 114(1), 24 (2012)
Lee KW, Hailan C, Yinhua J, Kim YW, Chung KW, Korean J. Chem. Eng., 25(3), 474 (2008)
Regulation (EU), Official Journal of theEuropean Union, 343, No 1169/2011, 18 (2011).
Philippaerts A, Jacobs PA, Sels BF, Angew. Chem.-Int. Edit., 52(20), 5220 (2013)
Balakos MW, Hernandez EE, Catal. Today, 35(4), 415 (1997)
Dijkstra AJ, Eur. J. Lipid Sci. Technol., 108(3), 249 (2006)
Lee JH, Kim SK, Ahn IY, Kim WJ, Moon SH, Korean J. Chem. Eng., 29(2), 169 (2012)
McArdle S, Curtin T, Leahy JJ, Appl. Catal. A: Gen., 382(2), 332 (2010)
McArdle S, Girish S, Leahy JJ, Curtin T, J. Mol. Catal. A-Chem., 351, 179 (2011)
Aguinaga A, Delacal JC, Asua JM, Montes M, Appl. Catal., 51(1), 1 (1989)
Burattin P, Che M, Louis C, J. Phys. Chem. B, 103(30), 6171 (1999)
Ermakova MA, Ermakov DY, Cherepanova SV, Plyasova LN, J. Phys. Chem. B, 106(46), 11922 (2002)
Coenen JWE, Ind. Eng. Chem. Fundam., 25(1), 43 (1986)
Rodrigo MT, Daza L, Mendioroz S, Appl. Catal. A: Gen., 88(1), 101 (1992)
Hermans LAM, Geus JW, Stud. Surf. Sci. Catal., 2(3), 113 (1979)
Cai W, Ye L, Zhang L, Ren Y, Yue B, Chen X, He H, Materials, 7(3), 2340 (2014)
Song W, Zhao C, Lercher JA, Chem.-Eur. J., 19(30), 9833 (2013)
Bartholomew CH, Farrauto RJ, J. Catal., 45(1), 41 (1976)
Piqueras C, Bottini S, Damiani D, Appl. Catal. A: Gen., 313(2), 177 (2006)
Fillion B, Morsi BI, Heier KR, Machado RM, Ind. Eng. Chem. Res., 41(4), 697 (2002)
