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Received April 24, 2016
Accepted August 19, 2016
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Photocatalytic degradation of bromophenol blue in aqueous medium using chitosan conjugated magnetic nanoparticles
1Department of Chemistry, Islamia College University, Peshawar 25120, Pakistan 2Institute of Chemical Sciences, University of Peshawar, Peshawar 25120, Pakistan 3Department of Chemistry, University of Malakand, Chakdara, Dir(L), Pakistan
Korean Journal of Chemical Engineering, October 2016, 33(10), 2802-2807(6), 10.1007/s11814-016-0238-8
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Abstract
Three different chitosan conjugated magnetic nanoparticles (CCMN) of Co, Ni and Fe were prepared using co-precipitation method. The prepared CCMN were characterized by scanning electron microscopy (SEM), Xray diffraction (XRD) and Fourier transform infra-red (FT-IR) spectroscopic techniques. The SEM results showed a smooth surface morphology with almost uniform particle size and irregular shape structure for all CCMN. The XRD study revealed the crystalline structure in case of Co-CCMN and Ni-CCMN, while amorphous nature of Fe-CCMN was observed. The particle size of the prepared CCMN was found to be <95 nm, as confirmed from SEM and XRD analyses. Similarly, FT-IR analysis showed the incorporation and conjugation of Co, Ni and Fe magnetic nanoparticles into the chitosan polymer matrix. The point of zero charge (PZC) was found to be 7.41 for Co-CCMN and Ni-CCMN and 7.70 for Fe-CCMN. The photocatalytic activity of the prepared CCMN was investigated under UV light irradiation (254 nm and 15 W) in the aqueous medium using bromophenol blue (BPB). The photocatalytic process was monitored by UV-visible spectrophotometer for different irradiation times (0 to 10 h). The results showed that all the prepared CCMN displayed good to excellent photocatalytic property where the highest degradation was exhibited by Fe-CCMN (94.5%), followed by Co-CCMN (85.1%) and Ni-CCMN (83.0%). The prepared catalysts were recycled and reused, maintaining good photocatalytic activity for four consecutive batches.
References
Forgacs E, Cserhati T, Oros G, Environ. Int., 30, 953 (2004)
Singh K, Arora S, Crit. Rev. Environ. Sci. Technol., 41, 807 (2011)
Moradi M, Ghanbari F, Manshouri M, Angali KA, Korean J. Chem. Eng., 33(2), 539 (2016)
Robinson T, McMullan G, Marchant R, Nigam P, Bioresour. Technol., 77(3), 247 (2001)
Ngah WSW, Teong LC, Hanafiah MAKM, Carbohydr. Polym., 83, 1446 (2011)
Khan H, Haider S, Saeed K, Ali N, J. Chem. Soc. Pak., 30, 246 (2008)
Shaikh H, Memon N, Khan H, Bhanger MI, Nizamani SM, J. Chromatogr. A, 1247, 125 (2012)
Rauf MA, Ashraf SS, J. Hazard. Mater., 166(1), 6 (2009)
Posa VR, Annavaram V, Koduru JR, Ammireddy VR, Somala AR, Korean J. Chem. Eng., 33(2), 456 (2016)
Akpan UG, Hameed BH, J. Hazard. Mater., 170(2-3), 520 (2009)
Buthiyappan A, Aziz ARA, Daud WMAW, Rev. Chem. Eng., 32(1), 1 (2016)
Saeed K, Ali G, Khan I, Khan H, J. Chem. Eng. Chem. Res., 2, 671 (2015)
Valizadeh S, Rasoulifard MH, Dorraji MSS, Korean J. Chem. Eng., 33(2), 481 (2016)
Nezamzadeh-Ejhieh A, Banan Z, Desalination, 284, 157 (2012)
Nezamzadeh-Ejhieh A, Karimi-Shamsabadi M, Appl. Catal. A: Gen., 477, 83 (2014)
Shams-Ghahfarokhi Z, Nezamzadeh-Ejhieh A, Mater. Sci. Semicond. Process, 39, 265 (2015)
Nezamzadeh-Ejhieh A, Moazzeni N, J. Ind. Eng. Chem., 19(5), 1433 (2013)
Nezamzadeh-Ejhieh A, Zabihi-Mobarakeh H, J. Ind. Eng. Chem., 20(4), 1421 (2014)
Nezamzadeh-Ejhieh A, Banan Z, Iran. J. Catal., 2, 79 (2012)
Ghomi AB, Ashayeri V, Iran. J. Catal., 2, 135 (2012)
Akbarzadeh A, Samiei M, Davaran S, Nanoscale Res. Lett., 7, 144 (2012)
Nezamzadeh-Ejhieh A, Tavakoli-Ghinani S, Comptes Rendus Chim., 17, 49 (2014)
Tourinho F, Franck R, Massart R, Perzynski R, Prog. Colloid Polym. Sci., 79, 128 (1989)
Arain M, Nafady A, Sirajuddin, Ibupoto ZH, Sherazi STH, Shaikh T, Khan H, Alsalme A, Niaz A, Willander M, RSC Adv., 6, 39001 (2016)
Zeroual Y, Kim BS, Kim CS, Blaghen M, Lee KM, Appl. Biochem. Biotechnol., 134(1), 51 (2006)
You LJ, Wu ZJ, Kim T, Lee K, J. Colloid Interface Sci., 300(2), 526 (2006)
Haider S, Bukhari N, Park SY, Iqbal Y, Al-Masry WA, Chem. Eng. Res. Des., 89(1A), 23 (2011)
Onen AI, Maitera ON, Joseph J, Ebenso EE, Int. J. Electrochem. Sci., 6, 2884 (2011)
Mashkour MS, Iraqi Natl. J. Chem., 46, 189 (2012)
Dlamini LN, Krause RW, Kulkarni GU, Durbach SH, Appl. Water Sci., 1, 19 (2011)
Bouanimba N, Zouaghi R, Laid N, Sehili T, Desalination, 275(1-3), 224 (2011)
Djepang SA, Laminsi S, Njoyim-Tamungang E, Ngnintedem C, Brisset JL, Chem. Mater. Eng., 2, 14 (2014)
Liu JZ, Wang TL, Ji LN, J. Mol. Catal. B-Enzym., 41, 81 (2006)
Salem IA, Appl. Catal. B: Environ., 28, 15 (2000)
Jayaraman A, Mas S, Tauler R, de Juan A, J. Chromatogr. B, 910, 138 (2012)
Yang J, Cui SH, Qiao JQ, Lian HZ, J. Mol. Catal. A-Chem., 395, 42 (2014)
Azmat R, Khalid Z, Haroon M, Mehar KP, Adv. Nat. Sci., 6, 38 (2013)
Khan A, Badshah S, Airoldi C, Chem. Eng. J., 171(1), 159 (2011)
Khan A, Badshah S, Airoldi C, Polym. Bull., 72(2), 353 (2015)
Khan A, Wahid F, Ali N, Badshah S, Airoldi C, Desalin. Water Treat., 56, 1099 (2015)
Singh K, Arora S, Crit. Rev. Environ. Sci. Technol., 41, 807 (2011)
Moradi M, Ghanbari F, Manshouri M, Angali KA, Korean J. Chem. Eng., 33(2), 539 (2016)
Robinson T, McMullan G, Marchant R, Nigam P, Bioresour. Technol., 77(3), 247 (2001)
Ngah WSW, Teong LC, Hanafiah MAKM, Carbohydr. Polym., 83, 1446 (2011)
Khan H, Haider S, Saeed K, Ali N, J. Chem. Soc. Pak., 30, 246 (2008)
Shaikh H, Memon N, Khan H, Bhanger MI, Nizamani SM, J. Chromatogr. A, 1247, 125 (2012)
Rauf MA, Ashraf SS, J. Hazard. Mater., 166(1), 6 (2009)
Posa VR, Annavaram V, Koduru JR, Ammireddy VR, Somala AR, Korean J. Chem. Eng., 33(2), 456 (2016)
Akpan UG, Hameed BH, J. Hazard. Mater., 170(2-3), 520 (2009)
Buthiyappan A, Aziz ARA, Daud WMAW, Rev. Chem. Eng., 32(1), 1 (2016)
Saeed K, Ali G, Khan I, Khan H, J. Chem. Eng. Chem. Res., 2, 671 (2015)
Valizadeh S, Rasoulifard MH, Dorraji MSS, Korean J. Chem. Eng., 33(2), 481 (2016)
Nezamzadeh-Ejhieh A, Banan Z, Desalination, 284, 157 (2012)
Nezamzadeh-Ejhieh A, Karimi-Shamsabadi M, Appl. Catal. A: Gen., 477, 83 (2014)
Shams-Ghahfarokhi Z, Nezamzadeh-Ejhieh A, Mater. Sci. Semicond. Process, 39, 265 (2015)
Nezamzadeh-Ejhieh A, Moazzeni N, J. Ind. Eng. Chem., 19(5), 1433 (2013)
Nezamzadeh-Ejhieh A, Zabihi-Mobarakeh H, J. Ind. Eng. Chem., 20(4), 1421 (2014)
Nezamzadeh-Ejhieh A, Banan Z, Iran. J. Catal., 2, 79 (2012)
Ghomi AB, Ashayeri V, Iran. J. Catal., 2, 135 (2012)
Akbarzadeh A, Samiei M, Davaran S, Nanoscale Res. Lett., 7, 144 (2012)
Nezamzadeh-Ejhieh A, Tavakoli-Ghinani S, Comptes Rendus Chim., 17, 49 (2014)
Tourinho F, Franck R, Massart R, Perzynski R, Prog. Colloid Polym. Sci., 79, 128 (1989)
Arain M, Nafady A, Sirajuddin, Ibupoto ZH, Sherazi STH, Shaikh T, Khan H, Alsalme A, Niaz A, Willander M, RSC Adv., 6, 39001 (2016)
Zeroual Y, Kim BS, Kim CS, Blaghen M, Lee KM, Appl. Biochem. Biotechnol., 134(1), 51 (2006)
You LJ, Wu ZJ, Kim T, Lee K, J. Colloid Interface Sci., 300(2), 526 (2006)
Haider S, Bukhari N, Park SY, Iqbal Y, Al-Masry WA, Chem. Eng. Res. Des., 89(1A), 23 (2011)
Onen AI, Maitera ON, Joseph J, Ebenso EE, Int. J. Electrochem. Sci., 6, 2884 (2011)
Mashkour MS, Iraqi Natl. J. Chem., 46, 189 (2012)
Dlamini LN, Krause RW, Kulkarni GU, Durbach SH, Appl. Water Sci., 1, 19 (2011)
Bouanimba N, Zouaghi R, Laid N, Sehili T, Desalination, 275(1-3), 224 (2011)
Djepang SA, Laminsi S, Njoyim-Tamungang E, Ngnintedem C, Brisset JL, Chem. Mater. Eng., 2, 14 (2014)
Liu JZ, Wang TL, Ji LN, J. Mol. Catal. B-Enzym., 41, 81 (2006)
Salem IA, Appl. Catal. B: Environ., 28, 15 (2000)
Jayaraman A, Mas S, Tauler R, de Juan A, J. Chromatogr. B, 910, 138 (2012)
Yang J, Cui SH, Qiao JQ, Lian HZ, J. Mol. Catal. A-Chem., 395, 42 (2014)
Azmat R, Khalid Z, Haroon M, Mehar KP, Adv. Nat. Sci., 6, 38 (2013)
Khan A, Badshah S, Airoldi C, Chem. Eng. J., 171(1), 159 (2011)
Khan A, Badshah S, Airoldi C, Polym. Bull., 72(2), 353 (2015)
Khan A, Wahid F, Ali N, Badshah S, Airoldi C, Desalin. Water Treat., 56, 1099 (2015)
