Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received February 17, 2016
Accepted June 8, 2016
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Application of mesoporous magnetic carbon composite for reactive dyes removal: Process optimization using response surface methodology
Ahmad Jonidi Jafari1 2
Babak Kakavandi3 4†
Roshanak Rezaei Kalantary1 2
Hamed Gharibi5
Anvar Asadi6
Ali Azari7
Ali Akbar Babaei4
Afshin Takdastan4
1Research Center for Environmental Health Technology (RCEHT), Iran University of Medical Sciences, Tehran, Iran 2Department of Environmental Health Engineering, School of Public Health, Iran University of Medical Sciences, Tehran, Iran 3Student Research Committee, Ahvaz Jundishapur University of Medical Sciences, Ahvaz, Iran 4Department of Environmental Health Engineering, School of Health, Ahvaz Jundishapur University of Medical Sciences, Ahvaz, Iran 5School of Public Health, Shahroud University of Medical Sciences, Shahroud, Iran 6Department of Environmental Health Engineering, School of Public Health, Shahid Beheshti University of Medical Sciences, Tehran, Iran 7Department of Environmental Health Engineering, School of Public Health, Tehran University of Medical Sciences, Tehran, Iran
kakavandi.b@ajums.ac.ir, kakavandibvch@gmail.com
Korean Journal of Chemical Engineering, October 2016, 33(10), 2878-2890(13), 10.1007/s11814-016-0155-x
Download PDF
Abstract
Discharging the effluents of textile wastewaters into potable water resources can endanger the ecosystem, due to their reactivity, toxicity, and chemical stability. In this research, the application of powder activated carbon modified with magnetite nanoparticles (PAC-MNPs) as an adsorbent for removal of reactive dyes (Reactive black 5 (RB5) and reactive red 120 (RR120)) was studied in a batch system. The adsorption performance was evaluated as a function of temperature, contact time and different adsorbent and adsorbate concentrations. The levels of factors were statistically optimized using Box-Behnken Design (BBD) from the response surface methodology (RSM) to maximize the efficiency of the system. The adsorption process of both dyes was fit with the pseudo-second order kinetic and Langmuir isotherm models. The identified optimum conditions of adsorption were 38.7 ℃, 46.3 min, 0.8 g/L and 102mg/L for temperature, contact time, adsorbent dose, and initial dyes concentration, respectively. According to the Langmuir isotherm, the maximum sorption capacities of 175.4 and 172.4mg/g were obtained for RB5 and RR120, respectively. Thermodynamics studies indicated that the adsorption process of the reactive dyes was spontaneous, feasible, and endothermic. After five cycles, the adsorption efficiency was around 84 and 83% for RB5 and RR120, respectively. A high value of desorption was achieved, suggesting that the PAC-MNPs have a good potential in regeneration and reusability, and also can be effectively utilized in industrial applications. PAC-MNPs also show a good anti-interference potential for removal of reactive dyes in dye-industry wastewaters.
References
Babaei AA, Khataee A, Ahmadpour E, Sheydaei M, Kakavandi B, Alaee Z, Korean J. Chem. Eng., 33, 1352 (2015)
Gupta VK, Jain R, Mittal A, Saleh TA, Nayak A, Agarwal S, Sikarwar S, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 32, 12 (2012)
Mittal A, Mittal J, Malviya A, Gupta VK, J. Colloid Interface Sci., 340(1), 16 (2009)
Kalantry RR, Jafari AJ, Esrafili A, Kakavandi B, Gholizadeh A, Azari A, Desalination Water Treatment., 57, 6411 (2016)
Mittal A, Mittal J, Malviya A, Kaur D, Gupta VK, J. Colloid Interface Sci., 342(2), 518 (2010)
Rafatullah M, Sulaiman O, Hashim R, Ahmad A, J. Hazard. Mater., 177(1-3), 70 (2010)
Yao YY, Wang L, Sun LJ, Zhu S, Huang ZF, Mao YJ, Lu WY, Chen WX, Chem. Eng. Sci., 101, 424 (2013)
Ahmad MA, Alrozi R, Chem. Eng. J., 171(2), 510 (2011)
Ghaedi M, Sadeghian B, Pebdani AA, Sahraei R, Daneshfar A, Duran C, Chem. Eng. J., 187, 133 (2012)
Gupta VK, Jain R, Nayak A, Agarwal S, Shrivastava M, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 31, 1062 (2011)
Jaafarzadeh N, Kakavandi B, Takdastan A, Kalantary RR, Azizi M, Jorfi S, RSC Adv., 5, 84718 (2015)
Azari A, Kakavandi B, Kalantary RR, Ahmadi E, Gholami M, Torkshavand Z, Azizi M, J. Porous Mat., 22, 1083 (2015)
Esfahani AR, Hojati S, Azimi A, Farzadian M, Khataee A, J. Taiw. Inst. Chem. Eng., 49, 172 (2014)
Gupta VK, Ali I, Saleh TA, Siddiqui M, Agarwal S, Environ. Sci. Pollut. Res., 20, 1261 (2013)
Gupta VK, Suhas, J. Environ. Manage., 90, 2323 (2009)
Saleh TA, Gupta VK, Adv. Colloid Interface Sci., 211, 93 (2014)
Saleh TA, Gupta VK, Environ. Sci. Pollut. Res., 19, 1224 (2012)
Babaei AA, Bahrami M, Firouzi AF, Esfahani AR, Alidokht L, Desalination Water Treatment., 56, 3380 (2015)
Kakavandi B, Jafari AJ, Kalantary RR, Nasseri S, Esrafili A, Gholizadeh A, Azari A, J. Chem. Technol. Biotechnol., DOI:10.1002/jctb.4925. (2016)
Kakavandi B, Takdastan A, Jaafarzadeh N, Azizi M, Mirzaei A, Azari A, J. Photochem. Photobiol. A-Chem., 314, 178 (2016)
Gupta VK, Srivastava SK, Mohan D, Sharma S, Waste Manage., 17, 517 (1998)
Gupta VK, Nayak A, Chem. Eng. J., 180, 81 (2012)
Yang J, Dong Y, Li J, Liu Z, Min F, Li Y, Korean J. Chem. Eng., 32(11), 2247 (2015)
Kakavandi B, Kalantary RR, Jafari AJ, Nasseri S, Ameri A, Esrafili A, Azari A, CLEAN - Soil, Air, Water, 43, 1157 (2015)
Afshar A, Sadjadi SAS, Mollahosseini A, Eskandarian MR, Korean J. Chem. Eng., 33(2), 669 (2016)
Gong JL, Wang B, Zeng GM, Yang CP, Niu CG, Niu QY, Zhou WJ, Liang Y, J. Hazard. Mater., 164(2-3), 1517 (2009)
Gupta VK, Kumar R, Nayak A, Saleh TA, Barakat MA, Adv. Colloid Interface Sci., 193-194, 24 (2013)
Zhu HY, Jiang R, Xiao L, Li W, J. Hazard. Mater., 179(1-3), 251 (2010)
Huang J, Wu Z, Chen L, Sun Y, J. Mol. Liq., 209, 753 (2015)
American Society for Testing and Material (ASTM) (2012).
Tang Y, Liang S, Yu S, Gao N, Zhang J, Guo H, Wang Y, Colloids Surf. A: Physicochem. Eng. Asp., 406, 61 (2012)
Bayazit SS, Kerkez O, Chem. Eng. Res. Des., 92(11), 2725 (2014)
Singh KP, Gupta S, Singh AK, Sinha S, J. Hazard. Mater., 186(2-3), 1462 (2011)
Mohseni-Bandpi A, Kakavandi B, Kalantary RR, Azari A, Keramati A, RSC Adv., 5, 73279 (2015)
Nethaji S, Sivasamy A, Mandal AB, Bioresour. Technol., 134, 94 (2013)
Depci T, Chem. Eng. J., 181, 467 (2012)
Kakavandi B, Jahangiri-rad M, Rafiee M, Efahani AR, Babaei AA, Microporous Mesoporous Mater., 231, 192 (2016)
Muhamad MH, Abdullah SRS, Mohamad AB, Rahman RA, Kadhum AAH, J. Environ. Manage., 121, 179 (2013)
Mittal A, Kaur D, Malviya A, Mittal J, Gupta VK, J. Colloid Interface Sci., 337(2), 345 (2009)
Mittal A, Mittal J, Malviya A, Gupta VK, J. Colloid Interface Sci., 344(2), 497 (2010)
Konicki W, Pelech I, Mijowska E, Jasinska I, CLEAN-Soil Air Water, 42, 284 (2014)
Esfahani AR, Firouzi AF, Sayyad G, Kiasat A, Alidokht L, Khataee A, Res. Chem. Intermed., 40, 431 (2014)
Esfahani AR, Hojati S, Azimi A, Alidokht L, Khataee A, Farzadian M, Korean J. Chem. Eng., 31(4), 630 (2014)
Sulaymon AH, Abood WM, Desalination Water Treatment, 52, 5485 (2014)
Tanyildizi MS, Chem. Eng. J., 168(3), 1234 (2011)
Gupta VK, Nayak A, Agarwal S, Environ. Eng. Res., 20, 1 (2015)
Xue YJ, Hou HB, Zhu SJ, Chem. Eng. J., 147(2-3), 272 (2009)
Elwakeel KZ, Rekaby M, J. Hazard. Mater., 188(1-3), 10 (2011)
Jain AK, Gupta VK, Bhatnagar A, Suhas, Sep. Sci. Technol., 38(2), 463 (2003)
Massoudinejad M, Asadi A, Vosoughi M, Gholami M, Kakavandi B, Karami MA, Korean J. Chem. Eng., 32(10), 2078 (2015)
Tunc O, Tanaci H, Aksu Z, J. Hazard. Mater., 163(1), 187 (2009)
Absalan G, Asadi M, Kamran S, Sheikhian L, Goltz DM, J. Hazard. Mater., 192(2), 476 (2011)
Li Z, Cao M, Zhang W, Liu L, Wang J, Ge W, Yuan Y, Yue T, Li R, Yu WW, Food Chem., 145, 749 (2014)
Celekli A, Ilgun G, Bozkurt H, Chem. Eng. J., 191, 228 (2012)
Azari A, Kalantary RR, Ghanizadeh G, Kakavandi B, Farzadkia M, Ahmadi E, RSC Adv., 5, 87377 (2015)
Gupta VK, Agarwal S, Saleh TA, J. Hazard. Mater., 185, 17 (2011)
Organization WH, Guidelines for drinking-water quality: First addendum to volume 1, Recommendations, World Health Organization (2006).
Gupta VK, Jain R, Mittal A, Saleh TA, Nayak A, Agarwal S, Sikarwar S, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 32, 12 (2012)
Mittal A, Mittal J, Malviya A, Gupta VK, J. Colloid Interface Sci., 340(1), 16 (2009)
Kalantry RR, Jafari AJ, Esrafili A, Kakavandi B, Gholizadeh A, Azari A, Desalination Water Treatment., 57, 6411 (2016)
Mittal A, Mittal J, Malviya A, Kaur D, Gupta VK, J. Colloid Interface Sci., 342(2), 518 (2010)
Rafatullah M, Sulaiman O, Hashim R, Ahmad A, J. Hazard. Mater., 177(1-3), 70 (2010)
Yao YY, Wang L, Sun LJ, Zhu S, Huang ZF, Mao YJ, Lu WY, Chen WX, Chem. Eng. Sci., 101, 424 (2013)
Ahmad MA, Alrozi R, Chem. Eng. J., 171(2), 510 (2011)
Ghaedi M, Sadeghian B, Pebdani AA, Sahraei R, Daneshfar A, Duran C, Chem. Eng. J., 187, 133 (2012)
Gupta VK, Jain R, Nayak A, Agarwal S, Shrivastava M, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 31, 1062 (2011)
Jaafarzadeh N, Kakavandi B, Takdastan A, Kalantary RR, Azizi M, Jorfi S, RSC Adv., 5, 84718 (2015)
Azari A, Kakavandi B, Kalantary RR, Ahmadi E, Gholami M, Torkshavand Z, Azizi M, J. Porous Mat., 22, 1083 (2015)
Esfahani AR, Hojati S, Azimi A, Farzadian M, Khataee A, J. Taiw. Inst. Chem. Eng., 49, 172 (2014)
Gupta VK, Ali I, Saleh TA, Siddiqui M, Agarwal S, Environ. Sci. Pollut. Res., 20, 1261 (2013)
Gupta VK, Suhas, J. Environ. Manage., 90, 2323 (2009)
Saleh TA, Gupta VK, Adv. Colloid Interface Sci., 211, 93 (2014)
Saleh TA, Gupta VK, Environ. Sci. Pollut. Res., 19, 1224 (2012)
Babaei AA, Bahrami M, Firouzi AF, Esfahani AR, Alidokht L, Desalination Water Treatment., 56, 3380 (2015)
Kakavandi B, Jafari AJ, Kalantary RR, Nasseri S, Esrafili A, Gholizadeh A, Azari A, J. Chem. Technol. Biotechnol., DOI:10.1002/jctb.4925. (2016)
Kakavandi B, Takdastan A, Jaafarzadeh N, Azizi M, Mirzaei A, Azari A, J. Photochem. Photobiol. A-Chem., 314, 178 (2016)
Gupta VK, Srivastava SK, Mohan D, Sharma S, Waste Manage., 17, 517 (1998)
Gupta VK, Nayak A, Chem. Eng. J., 180, 81 (2012)
Yang J, Dong Y, Li J, Liu Z, Min F, Li Y, Korean J. Chem. Eng., 32(11), 2247 (2015)
Kakavandi B, Kalantary RR, Jafari AJ, Nasseri S, Ameri A, Esrafili A, Azari A, CLEAN - Soil, Air, Water, 43, 1157 (2015)
Afshar A, Sadjadi SAS, Mollahosseini A, Eskandarian MR, Korean J. Chem. Eng., 33(2), 669 (2016)
Gong JL, Wang B, Zeng GM, Yang CP, Niu CG, Niu QY, Zhou WJ, Liang Y, J. Hazard. Mater., 164(2-3), 1517 (2009)
Gupta VK, Kumar R, Nayak A, Saleh TA, Barakat MA, Adv. Colloid Interface Sci., 193-194, 24 (2013)
Zhu HY, Jiang R, Xiao L, Li W, J. Hazard. Mater., 179(1-3), 251 (2010)
Huang J, Wu Z, Chen L, Sun Y, J. Mol. Liq., 209, 753 (2015)
American Society for Testing and Material (ASTM) (2012).
Tang Y, Liang S, Yu S, Gao N, Zhang J, Guo H, Wang Y, Colloids Surf. A: Physicochem. Eng. Asp., 406, 61 (2012)
Bayazit SS, Kerkez O, Chem. Eng. Res. Des., 92(11), 2725 (2014)
Singh KP, Gupta S, Singh AK, Sinha S, J. Hazard. Mater., 186(2-3), 1462 (2011)
Mohseni-Bandpi A, Kakavandi B, Kalantary RR, Azari A, Keramati A, RSC Adv., 5, 73279 (2015)
Nethaji S, Sivasamy A, Mandal AB, Bioresour. Technol., 134, 94 (2013)
Depci T, Chem. Eng. J., 181, 467 (2012)
Kakavandi B, Jahangiri-rad M, Rafiee M, Efahani AR, Babaei AA, Microporous Mesoporous Mater., 231, 192 (2016)
Muhamad MH, Abdullah SRS, Mohamad AB, Rahman RA, Kadhum AAH, J. Environ. Manage., 121, 179 (2013)
Mittal A, Kaur D, Malviya A, Mittal J, Gupta VK, J. Colloid Interface Sci., 337(2), 345 (2009)
Mittal A, Mittal J, Malviya A, Gupta VK, J. Colloid Interface Sci., 344(2), 497 (2010)
Konicki W, Pelech I, Mijowska E, Jasinska I, CLEAN-Soil Air Water, 42, 284 (2014)
Esfahani AR, Firouzi AF, Sayyad G, Kiasat A, Alidokht L, Khataee A, Res. Chem. Intermed., 40, 431 (2014)
Esfahani AR, Hojati S, Azimi A, Alidokht L, Khataee A, Farzadian M, Korean J. Chem. Eng., 31(4), 630 (2014)
Sulaymon AH, Abood WM, Desalination Water Treatment, 52, 5485 (2014)
Tanyildizi MS, Chem. Eng. J., 168(3), 1234 (2011)
Gupta VK, Nayak A, Agarwal S, Environ. Eng. Res., 20, 1 (2015)
Xue YJ, Hou HB, Zhu SJ, Chem. Eng. J., 147(2-3), 272 (2009)
Elwakeel KZ, Rekaby M, J. Hazard. Mater., 188(1-3), 10 (2011)
Jain AK, Gupta VK, Bhatnagar A, Suhas, Sep. Sci. Technol., 38(2), 463 (2003)
Massoudinejad M, Asadi A, Vosoughi M, Gholami M, Kakavandi B, Karami MA, Korean J. Chem. Eng., 32(10), 2078 (2015)
Tunc O, Tanaci H, Aksu Z, J. Hazard. Mater., 163(1), 187 (2009)
Absalan G, Asadi M, Kamran S, Sheikhian L, Goltz DM, J. Hazard. Mater., 192(2), 476 (2011)
Li Z, Cao M, Zhang W, Liu L, Wang J, Ge W, Yuan Y, Yue T, Li R, Yu WW, Food Chem., 145, 749 (2014)
Celekli A, Ilgun G, Bozkurt H, Chem. Eng. J., 191, 228 (2012)
Azari A, Kalantary RR, Ghanizadeh G, Kakavandi B, Farzadkia M, Ahmadi E, RSC Adv., 5, 87377 (2015)
Gupta VK, Agarwal S, Saleh TA, J. Hazard. Mater., 185, 17 (2011)
Organization WH, Guidelines for drinking-water quality: First addendum to volume 1, Recommendations, World Health Organization (2006).
