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Received January 17, 2016
Accepted May 14, 2016
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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A comparative study of CO2 and CH4 adsorption using activated carbon prepared from pine cone by phosphoric acid activation
Faculty of Chemical, Petroleum and Gas Engineering, Semnan University, Semnan, Iran 1Nanotechnology Institute, Chemical Engineering Department, Babol University of Technology, Babol, Iran
bkhoshandam@semnan.ac.ir
Korean Journal of Chemical Engineering, October 2016, 33(10), 2943-2952(10), 10.1007/s11814-016-0138-y
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Abstract
Adsorption of pure carbon dioxide and methane was examined on activated carbon prepared from pine cone by chemical activation with H3PO4 to determine the potential for the separation of CO2 from CH4. The prepared adsorbent was characterized by N2 adsorption-desorption, elemental analysis, FTIR, SEM and TEM. The equilibrium adsorption of CO2 and CH4 on AC was determined at 298, 308 and 318 K and pressure range of 1-16 bar. The experimental data of both gases were analyzed using Langmuir and Freundlich models. For CO2, the Langmuir isotherm presented a perfect fit, whereas the isotherm of CH4 was well described by Freundlich model. The selectivity of CO2 over CH4 by AC (CO2 : CH4=50 : 50, 298K, 5 bar), predicted by ideal adsorbed solution theory (IAST) model, was achieved at 1.68. These data demonstrated that pine cone-based AC prepared in this study can be successfully used in separation of CO2 from CH4.
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References
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Bae YS, Farha OK, Hupp JT, Snurr RQ, J. Mater. Chem., 19, 2131 (2009)
Prasetyo I, Do DD, Chem. Eng. Sci., 53(19), 3459 (1998)
Khalili S, Ghoreyshi AA, Jahanshahi M, Chem. Ind. Chem. Eng. Quart., 19, 153 (2013)
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Anirudhan TS, Radhakrishnan PG, Chem. Eng. J., 165(1), 142 (2010)
