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Received December 23, 2015
Accepted June 15, 2016
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Process modeling and optimization studies of high pressure membrane separation of CO2 from natural gas
1School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Seberang Prai Selatan, Pulau Pinang, Malaysia 2Center for Integrative Petroleum Research, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia 3, Dhahran 31261, Saudi Arabia
Korean Journal of Chemical Engineering, October 2016, 33(10), 2998-3010(13), 10.1007/s11814-016-0165-8
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Abstract
Process design and optimization methodology for high pressure membrane removal of CO2 from natural gas was developed. An approximate model based on plasticization pressure and permeability parameters at plasticization was proposed for quick evaluation of membrane materials for the high pressure operation. The model was derived by applying the partial immobilization assumption to the fundamental model of solution - diffusion mechanism along with a modified upper-bound curve. About ninety membranes obtained from literature were used to illustrate this methodology. The best three were selected for detailed process modeling and optimization. Process optimization was achieved via non-linear programming constraint optimization model. Gas processing cost was used as the objective function, while plasticization pressure and the CO2 concentration in the feed were used as the constraints. Membrane of 6FDA-durene had the lowest annual gas processing cost while 6FDA-DAM : DABA 2 : 1 had the highest optimum product purity.
Keywords
References
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Adams RT, Lee SS, Bae TH, Ward JK, Johnson JR, Jones CW, Nair S, Koros WJ, J. Membr. Sci., 367(1-2), 197 (2011)
Ahmad AL, Adewole JK, Leo CP, Ismail S, Sultan AS, Olatunji SO, J. Membr. Sci., 480, 39 (2015)
Xiao Y, Low BT, Hosseini SS, Chung TS, Paul DR, Prog. Polym. Sci, 34, 561 (2009)
Adewole JK, Ahmad AL, Ismail S, Leo CP, Int. J. Greenh. Gas. Con., 17, 46 (2013)
Scholes CA, Chen GQ, Stevens GW, Kentish SE, J. Membr. Sci., 346(1), 208 (2010)
Chung TS, Cao C, Wang R, J. Polym. Sci. B: Polym. Phys., 42(2), 354 (2004)
Spillman R, In Membrane Science and Technology, Richard DN, Stern SA, Eds., Elsevier (1995).
Bhide BD, Stern SA, J. Membr. Sci., 81, 209 (1993)
Qi RH, Henson MA, J. Membr. Sci., 121(1), 11 (1996)
Qi R, Henson MA, Sep. Purif. Technol., 13(3), 209 (1998)
Hao J, Rice PA, Stern SA, J. Membr. Sci., 320(1-2), 108 (2008)
Hao J, Rice PA, Stem SA, J. Membr. Sci., 209(1), 177 (2002)
Datta AK, Sen PK, J. Membr. Sci., 283(1-2), 291 (2006)
Yang DX, Wang Z, Wang JX, Wang SC, Ind. Eng. Chem. Res., 48(19), 9013 (2009)
Safari M, Ghanizadeh A, Montazer-Rahmati MM, Int. J. Greenh. Gas. Con., 3, 3 (2009)
Ahmad F, Lau KK, Shariff AM, Murshid G, Comput. Chem. Eng., 36, 119 (2012)
Peters L, Hussain A, Follmann M, Melin T, Hagg MB, Chem. Eng. J., 172(2-3), 952 (2011)
Bos A, Punt IGM, Wessling M, Strathmann H, J. Membr. Sci., 155(1), 67 (1999)
Bhide BD, Stern SA, J. Membr. Sci., 62, 13 (1991)
Vaughn J, Koros WJ, Macromolecules, 45(17), 7036 (2012)
Bos A, Punt IGM, Wessling M, Strathmann H, J. Polym. Sci. B: Polym. Phys., 36(9), 1547 (1998)
Wijmans JG, Baker RW, J. Membr. Sci., 107(1-2), 1 (1995)
Flaconneche B, Martin J, Klopffer MH, Oil Gas Sci. Technol. - Rev. IFP
Ahmad AL, Adewole JK, Ismail SB, Peng LC, Sultan AS, Defect Diffus Forum, 333, 135 (2013)
Vieth WR, Diffusion In Model and Through Polymers, Hanser Publishers, New York (1991).
Koros WJ, Paul DR, Rocha AA, J. Polym. Sci. B: Polym. Phys., 14, 687 (1976)
Paul DR, Koros WJ, J. Polym. Sci. B: Polym. Phys., 14, 675 (1976)
Klopffer MH, Flaconneche B, Oil Gas Sci. Technol. - Rev. IFP, 56, 223 (2001)
McHattie JS, Koros WJ, Paul DR, Polymer, 32, 2618 (1991)
McHattie JS, Koros WJ, Paul DR, Polymer, 32, 840 (1991)
McHattie JS, Koros WJ, Paul DR, Polymer, 33, 1701 (1992)
Houde AY, Kulkarni SS, Kulkarni MG, J. Membr. Sci., 95(2), 147 (1994)
Kamps KMP, Teunis HA, Wessling M, Smolders CA, J. Membr. Sci., 74, 193 (1992)
Kumazawa H, Wang JS, Fukuda T, Sada E, J. Membr. Sci., 93(1), 53 (1994)
Srinivasan R, Auvil SR, Burban PM, J. Membr. Sci., 86(1-2), 67 (1994)
Wang R, Liu SL, Lin TT, Chung TS, Chem. Eng. Sci., 57(6), 967 (2002)
Stern SA, Saxena V, J. Membr. Sci., 7, 47 (1980)
Bos A, Punt IGM, Wessling M, Strathmann H, Sep. Purif. Technol., 14(1-3), 27 (1998)
Lin WH, Chung TS, J. Membr. Sci., 186(2), 183 (2001)
Chen XY, Rodrigue D, Kaliaguine S, Sep. Purif. Technol., 86, 221 (2012)
Kraftschik B, Koros WJ, Johnson JR, Karvan O, J. Membr. Sci., 428, 608 (2013)
Wind JD, Sirard SM, Paul DR, Green PF, Johnston KP, Koros WJ, Macromolecules, 36(17), 6433 (2003)
Mohr JM, Paul DR, Tullos GL, Cassidy PE, Polymer, 32, 13 (1991)
Bos A, Punt IGM, Wessling M, Strathmann H, J. Membr. Sci., 155(1), 67 (1999)
Bos A, Punt IGM, Wessling M, Strathmann H, Sep. Purif. Technol., 14(1-3), 27 (1998)
Houde AY, Krishnakumar B, Charati SG, Stern SA, J. Appl. Polym. Sci., 62(13), 2181 (1996)
Pixton MR, Paul DR, Polymer, 36(16), 3165 (1995)
Kratochvil AM, Koros WJ, Macromolecules, 41(21), 7920 (2008)
Wind JD, Sirard SM, Paul DR, Green PF, Johnston KP, Koros WJ, Macromolecules, 36(17), 6442 (2003)
Kumazawa H, Inamori K, Messaoudi B, Sada E, J. Membr. Sci., 97, 7 (1994)
Chern RT, Sheu FR, Jia L, Stannett VT, Hopfenberg HB, J. Membr. Sci., 35, 103 (1987)
Nakagawa T, Nishimura T, Higuchi A, J. Membr. Sci., 206(1-2), 149 (2002)
Zhang LL, Xiao YC, Chung TS, Jiang JW, Polymer, 51(19), 4439 (2010)
Ruiz-Trevino FA, Paul DR, J. Appl. Polym. Sci., 68(3), 403 (1998)
Qiu WL, Chen CC, Xu LR, Cui LL, Paul DR, Koros WJ, Macromolecules, 44(15), 6046 (2011)
Khan AL, Li XF, Vankelecom IFJ, J. Membr. Sci., 372(1-2), 87 (2011)
Tin PS, Chung TS, Liu Y, Wang R, Liu SL, Pramoda KP, J. Membr. Sci., 225(1-2), 77 (2003)
Hillock AMW, Koros WJ, Macromolecules, 40(3), 583 (2007)
Powell CE, Duthie XJ, Kentish SE, Qiao GG, Stevens GW, J. Membr. Sci., 291(1-2), 199 (2007)
Low BT, Chung TS, Chen HM, Jean YC, Pramoda KP, Macromolecules, 42(18), 7042 (2009)
Reimers MJ, Barbari TA, J. Polym. Sci. B: Polym. Phys., 32(1), 131 (1994)
Hu CC, Fu YJ, Lee KR, Ruaan RC, Lai JY, Polymer, 50(22), 5308 (2009)
Robeson LM, J. Membr. Sci., 62, 165 (1991)
Freeman BD, Macromolecules, 32(2), 375 (1999)
Robeson LM, Hwu HH, McGrath JE, J. Membr. Sci., 302(1-2), 70 (2007)
Robeson LM, J. Membr. Sci., 320(1-2), 390 (2008)
Alentiev AY, Yampolskii YP, J. Membr. Sci., 165(2), 201 (2000)
Rowe BW, Robeson LM, Freeman BD, Paul DR, J. Membr. Sci., 360(1-2), 58 (2010)
Robeson LM, Smith ZP, Freeman BD, Paul DR, J. Membr. Sci., 453, 71 (2014)
Kanehashi S, Nakagawa T, Nagai K, Duthie X, Kentish S, Stevens G, J. Membr. Sci., 298(1-2), 147 (2007)
Wind JD, Sirard SM, Paul DR, Green PF, Johnston KP, Koros WJ, Macromolecules, 36(17), 6433 (2003)
Baker RW, In Membrane Technology and Applications, John Wiley & Sons, Ltd. (2004).
Peters L, Hussain A, Follmann M, Melin T, Hagg MB, Chem. Eng. J., 172(2-3), 952 (2011)
Bos A, Punt IGM, Wessling M, Strathmann H, J. Polym. Sci. B: Polym. Phys., 36(9), 1547 (1998)
Edgar TF, Himmelblau DM, Lasdon LS, Optimization of Chemical Processes, McGraw-Hill, New York (2001).
Rao SS, Rao SS, Engineering Optimization: Theory and Practice, John Wiley & Sons, New Jersey (2009).
Adewole JK, Ahmad AL, Sultan AS, Ismail S, Leo CP, J. Polym. Res., 22, 1 (2015)
