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Received February 2, 2016
Accepted June 14, 2016
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Laccase-catalyzed polymerization of m-phenylenediamine in aqueous buffers
Department of Chemical Engineering, College of Engineering, University of Ulsan, Ulsan 44610, Korea
Korean Journal of Chemical Engineering, October 2016, 33(10), 3011-3015(5), 10.1007/s11814-016-0163-x
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Abstract
In the laccase-catalyzed polymerization of m-phenylendiamine in 100% aqueous buffers, the yield of the polymer was strongly influenced by various reaction conditions such as the solution pH and the concentrations of laccase and m-phenylendiamine. When the reaction was performed at pH 3, the 100% synthetic yield of the polymer was achieved. As pH increased, the yield of the polymer decreased significantly to only 4.4% at pH 9. Effects of solution pH on the morphology and the thermal stability of the polymer were investigated in detail. The polymer synthesized at pH 3 has the typical aggregated morphology of globular particles, but being synthesized at pH 7, it has non-aggregated morphology. The thermal stability of the polymer deteriorated as reaction pH increased.
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