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Received March 9, 2016
Accepted May 25, 2016
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Thermogravimetric characteristics of α-cellulose and decomposition kinetics in a micro-tubing reactor
Department of Chemical Engineering, Kangwon National University, 346 Joongang-ro, Samcheok, Gangwon-do 25913, Korea 1Department of Plant and Environmental New Resources, Kyung Hee University, 1732 Doegyeong-daero, Giheung-gu, Yongin, Gyeonggi-do 17104, Korea 2Department of Chemical Engineering, Kyung Hee University, 1732 Doegyeong-daero, Giheung-gu, Yongin, Gyeonggi-do 17104, Korea
jhko@khu.ac.kr
Korean Journal of Chemical Engineering, November 2016, 33(11), 3128-3133(6), 10.1007/s11814-016-0143-1
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Abstract
The pyrolysis characteristics and kinetics of α-cellulose were investigated using thermogravimetric analyzer (TGA) and micro tubing reactor, respectively. Most of the α-cellulose decomposed between 250 and 400 ℃ at heating rate of 5-20 ℃/min. The apparent activation energy was observed in the range of 263.02 kJ mol-1 to 306.21 kJ mol-1 at the conversion of 10-80%. The kinetic parameters were determined by nonlinear least-squares regression of the experimental data, assuming first-order kinetics. It was found from the kinetic rate constants that the predominant reaction pathway was A(α-cellulose) to B(bio-oil) rather than A(α-cellulose) to C(gas; C1-C4) and/or to B(bio-oil) to C(gas; C1-C4) at temperatures of 340-360 ℃.
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Maiti S, Purakayastha S, Ghosh B, Fuel, 86(10-11), 1513 (2007)
Soysa R, Choi YS, Choi SK, Kim SJ, Han SY, Korean J. Chem. Eng., 33(2), 603 (2016)
Vamvuka D, Kakaras E, Kastanaki E, Grammelis P, Fuel, 82(15-17), 1949 (2003)
Wang G, Li W, Li BQ, Chen HK, Fuel, 87(4-5), 552 (2008)
Park HJ, Park YK, Dong JI, Kim JS, Jeon JK, Kim SS, Kim J, Song B, Park J, Lee KJ, Fuel Process. Technol., 90(2), 186 (2009)
Lee EH, Park R, Kim H, Park SH, Jung SC, Jeon JK, Kim SC, Park YK, J. Ind. Eng. Chem., In Press (2016)
Le TA, Ly HV, Kim J, Kim SS, Choi JH, Woo HC, Othman MR, Chem. Eng. J., 250, 157 (2014)
Ko JH, Park RS, Jeon JK, Kim DH, Jung SC, Kim SC, Park YK, J. Ind. Eng. Chem., 32, 109 (2015)
Ross AB, Jones JM, Kubacki ML, Bridgeman T, Bioresour. Technol., 99(14), 6494 (2008)
