Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received December 12, 2015
Accepted June 24, 2016
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Fabrication of polysulfone/zinc oxide nanocomposite membrane:Investigation of pore forming agent on fouling behavior
School of Chemical Engineering, College of Engineering, University of Tehran, Tehran, P. O. Box 11155-4563, Iran 1Department of Chemical Engineering, College of Engineering, University of Isfahan, P. O. Box 81746-73441, Isfahan, Iran
mmehrnia@ut.ac.ir
Korean Journal of Chemical Engineering, November 2016, 33(11), 3184-3193(10), 10.1007/s11814-016-0178-3
Download PDF
Abstract
The aim of this research was to synthesize a polysulfone/Zinc oxide nanocomposite membrane (PSf/ZnO NCM) in order to mitigate membrane fouling. ZnO nanoparticles with an approximate size of 20 nm were blended with PSf matrix. To fabricate an efficient PSf/ZnO NCM, polyethylene glycol and polyvinyl pyrrolidone were used as pore former agent, based on which PEG-NCMs and PVP-NCMs were fabricated. The effect of the type of pore former and concentration of nanoparticles was evaluated on the structure and performance of nanocomposite membrane. According to SEM images, with the increase in the concentration of nanoparticles, membrane porosity grew as well. AFM analysis confirmed increased roughness with contact angle measurement showing enhanced hydrophilicity. The filtration performance implied that the presence of ZnO nanoparticles improves water flux. Moreover, ZnO nanoparticles elevated humic acid rejection up to 99.7% and 94.2% and decreased total filtration resistance up to 89% and 30% for PEG-NCMs and PVP-NCMs, respectively.
Keywords
References
Schafer AI, Fane AG, Waite TD, Nanofiltration: Principles and applications, Elsevier (2005).
Trouve E, Urbain V, Manem J, Water Sci. Technol., 30, 151 (2014)
Pabby AK, Rizvi SS, Requena AMS, Handbook of membrane separations: chemical, pharmaceutical, food, and biotechnological applications, CRC Press (2015).
Muhamad MS, Salim MR, Lau WJ, Korean J. Chem. Eng., 32(11), 2319 (2015)
Hemmati A, Dolatabad MM, Naeimpoor F, Pak A, Mohammdi T, Korean J. Chem. Eng., 29(3), 369 (2012)
Asatekin A, Menniti A, Kang ST, Elimelech M, Morgenroth E, Mayes AM, J. Membr. Sci., 285(1-2), 81 (2006)
Liang S, Qi GG, Xiao K, Sun JY, Giannelis EP, Huang X, Elimelech M, J. Membr. Sci., 463, 94 (2014)
Liang S, Xiao K, Mo Y, Huang X, J. Membr. Sci., 394-395, 184 (2012)
Zodrow K, Brunet L, Mahendra S, Li D, Zhang A, Li Q, Alvarez PJ, Water Res., 43, 715 (2009)
Li L, Zhao Z, Huang W, Peng PA, Sheng G, Fu J, Org. Geochem., 35, 1025 (2004)
Feng HJ, Hu LF, Mahmood Q, Long Y, Shen DS, Biochem. Eng. J., 39, 478 (2008)
Junaidi M, Leo C, Kamal S, Ahmad A, Water Sci. Technol., 67, 2102 (2013)
Liu J, Song Y, Ruan R, Liu Y, Water Sci. Technol., 72, 92 (2015)
Bratskaya S, Schwarz S, Chervonetsky D, Water Res., 38, 2955 (2004)
Ahmad A, Abdulkarim A, Ismail S, Ooi B, Desalin. Water Treat., 1 (2014)
Asghar HMA, Hussain SN, Roberts EPL, Brown NW, Korean J. Chem. Eng., 30(7), 1415 (2013)
Levine AD, Tchobanoglous G, Asano T, Water Pollution Control Federation, 805 (1985)
Leppard G, Mavrocordatos D, Perret D, Water Sci. Technol., 50, 1 (2004)
Hamid NAA, Ismail AF, Matsuura T, Zularisam AW, Lau WJ, Yuliwati E, Abdullah MS, Desalination, 273(1), 85 (2011)
Sutzkover-Gutman I, Hasson D, Semiat R, Desalin. Water Treat., 31, 42 (2011)
Mansouri J, Harrisson S, Chen V, J. Mater. Chem., 20, 4567 (2010)
Hong JM, He Y, Desalination, 302, 71 (2012)
Balta S, Sotto A, Luis P, Benea L, Van der Bruggen B, Kim J, J. Membr. Sci., 389, 155 (2012)
Homayoonfal M, Mehrnia MR, Rahmani S, Mojtahedi YM, J. Ind. Eng. Chem., 22, 357 (2014)
Yunos MZ, Harun Z, Basri H, Shohur MF, Jamalludin MR, Hassan S, Jurnal Teknologi, 65(4), 111 (2013)
Leo CP, Lee WPC, Ahmad AL, Mohammad AW, Sep. Purif. Technol., 89, 51 (2012)
Homayoonfal M, Akbari A, Mehrnia MR, Desalination, 263(1-3), 217 (2010)
Mehrnia MR, Mojtahedi YM, Homayoonfal M, Desalination, 372, 75 (2015)
Derakhsheshpoor R, Homayoonfal M, Akbari A, Mehrnia MR, J. Env. Health Sci. Eng., 11, 1 (2013)
Chakrabarty B, Ghoshal AK, Purkait AK, J. Membr. Sci., 315(1-2), 36 (2008)
Chakrabarty B, Ghoshal AK, Purkait MK, J. Membr. Sci., 325(1), 427 (2008)
Homayoonfal M, Mehrnia MR, Shariaty-Niassar M, Akbari A, Ismail AF, Matsuura T, Desalination, 354, 125 (2014)
Woodward P, First Ten Angstroms Inc., Portsmouth (1999).
Mafirad S, Mehrnia M, Sarrafzadeh M, Water Sci. Technol., 64, 1154 (2011)
Liao CJ, Zhao JQ, Yu P, Tong H, Luo YB, Desalination, 285, 117 (2012)
Li JF, Xu ZL, Yang H, Feng CP, Shi JH, J. Appl. Polym. Sci., 107(6), 4100 (2008)
Sadeghi I, Aroujalian A, Raisi A, Dabir B, Fathizadeh M, J. Membr. Sci., 430, 24 (2013)
Li JF, Xu ZL, Yang H, Feng CP, Shi JH, J. Appl. Polym. Sci., 107(6), 4100 (2008)
Agboola O, Maree J, Mbaya R, Zvinowanda CM, Molelekwa GF, Jullok N, Van der Bruggen B, Volodine A, Haesendonck CV, Korean J. Chem. Eng., 31(8), 1413 (2014)
Misdan N, Lau WJ, Ong CS, Ismail AF, Matsuura T, Korean J. Chem. Eng., 32(4), 753 (2015)
Mulder M, Basic Principles of Membrane Technology, Springer Science+Business Media Dordrecht, Netherlands (1996).
Koltuniewicz AB, Field RW, Arnot TC, J. Membr. Sci., 102, 193 (1995)
Han MJ, Nam ST, J. Membr. Sci., 202(1-2), 55 (2002)
Panda SR, De S, J. Polym. Res., 20, 1 (2013)
Brandes N, Welzel PB, Werner C, Kroh LW, J. Colloid Interface Sci., 299(1), 56 (2006)
Homayoonfal M, Mehrnia MR, Mojtahedi YM, Ismail AF, Desalin. Water Treat., 51, 3295 (2013)
Alhoshan M, Alam J, Dass LA, Al-Homaidi N, Adv. Polym. Technol., 32(4), 21369 (2013)
Moradihamedani P, Ibrahim NA, Ramimoghadam D, Yunus WMZW, Yusof NA, J. Appl. Polym. Sci., 131(16), 39745 (2014)
Gaur MS, Singh PK, Suruchi, Chauhan RS, J. Therm. Anal. Calorim., 111, 743 (2012)
Ismail AF, Hassan AR, Sep. Purif. Technol., 55(1), 98 (2007)
Chakrabarty B, Ghoshal AK, Purkait MK, J. Membr. Sci., 309(1-2), 209 (2008)
Trouve E, Urbain V, Manem J, Water Sci. Technol., 30, 151 (2014)
Pabby AK, Rizvi SS, Requena AMS, Handbook of membrane separations: chemical, pharmaceutical, food, and biotechnological applications, CRC Press (2015).
Muhamad MS, Salim MR, Lau WJ, Korean J. Chem. Eng., 32(11), 2319 (2015)
Hemmati A, Dolatabad MM, Naeimpoor F, Pak A, Mohammdi T, Korean J. Chem. Eng., 29(3), 369 (2012)
Asatekin A, Menniti A, Kang ST, Elimelech M, Morgenroth E, Mayes AM, J. Membr. Sci., 285(1-2), 81 (2006)
Liang S, Qi GG, Xiao K, Sun JY, Giannelis EP, Huang X, Elimelech M, J. Membr. Sci., 463, 94 (2014)
Liang S, Xiao K, Mo Y, Huang X, J. Membr. Sci., 394-395, 184 (2012)
Zodrow K, Brunet L, Mahendra S, Li D, Zhang A, Li Q, Alvarez PJ, Water Res., 43, 715 (2009)
Li L, Zhao Z, Huang W, Peng PA, Sheng G, Fu J, Org. Geochem., 35, 1025 (2004)
Feng HJ, Hu LF, Mahmood Q, Long Y, Shen DS, Biochem. Eng. J., 39, 478 (2008)
Junaidi M, Leo C, Kamal S, Ahmad A, Water Sci. Technol., 67, 2102 (2013)
Liu J, Song Y, Ruan R, Liu Y, Water Sci. Technol., 72, 92 (2015)
Bratskaya S, Schwarz S, Chervonetsky D, Water Res., 38, 2955 (2004)
Ahmad A, Abdulkarim A, Ismail S, Ooi B, Desalin. Water Treat., 1 (2014)
Asghar HMA, Hussain SN, Roberts EPL, Brown NW, Korean J. Chem. Eng., 30(7), 1415 (2013)
Levine AD, Tchobanoglous G, Asano T, Water Pollution Control Federation, 805 (1985)
Leppard G, Mavrocordatos D, Perret D, Water Sci. Technol., 50, 1 (2004)
Hamid NAA, Ismail AF, Matsuura T, Zularisam AW, Lau WJ, Yuliwati E, Abdullah MS, Desalination, 273(1), 85 (2011)
Sutzkover-Gutman I, Hasson D, Semiat R, Desalin. Water Treat., 31, 42 (2011)
Mansouri J, Harrisson S, Chen V, J. Mater. Chem., 20, 4567 (2010)
Hong JM, He Y, Desalination, 302, 71 (2012)
Balta S, Sotto A, Luis P, Benea L, Van der Bruggen B, Kim J, J. Membr. Sci., 389, 155 (2012)
Homayoonfal M, Mehrnia MR, Rahmani S, Mojtahedi YM, J. Ind. Eng. Chem., 22, 357 (2014)
Yunos MZ, Harun Z, Basri H, Shohur MF, Jamalludin MR, Hassan S, Jurnal Teknologi, 65(4), 111 (2013)
Leo CP, Lee WPC, Ahmad AL, Mohammad AW, Sep. Purif. Technol., 89, 51 (2012)
Homayoonfal M, Akbari A, Mehrnia MR, Desalination, 263(1-3), 217 (2010)
Mehrnia MR, Mojtahedi YM, Homayoonfal M, Desalination, 372, 75 (2015)
Derakhsheshpoor R, Homayoonfal M, Akbari A, Mehrnia MR, J. Env. Health Sci. Eng., 11, 1 (2013)
Chakrabarty B, Ghoshal AK, Purkait AK, J. Membr. Sci., 315(1-2), 36 (2008)
Chakrabarty B, Ghoshal AK, Purkait MK, J. Membr. Sci., 325(1), 427 (2008)
Homayoonfal M, Mehrnia MR, Shariaty-Niassar M, Akbari A, Ismail AF, Matsuura T, Desalination, 354, 125 (2014)
Woodward P, First Ten Angstroms Inc., Portsmouth (1999).
Mafirad S, Mehrnia M, Sarrafzadeh M, Water Sci. Technol., 64, 1154 (2011)
Liao CJ, Zhao JQ, Yu P, Tong H, Luo YB, Desalination, 285, 117 (2012)
Li JF, Xu ZL, Yang H, Feng CP, Shi JH, J. Appl. Polym. Sci., 107(6), 4100 (2008)
Sadeghi I, Aroujalian A, Raisi A, Dabir B, Fathizadeh M, J. Membr. Sci., 430, 24 (2013)
Li JF, Xu ZL, Yang H, Feng CP, Shi JH, J. Appl. Polym. Sci., 107(6), 4100 (2008)
Agboola O, Maree J, Mbaya R, Zvinowanda CM, Molelekwa GF, Jullok N, Van der Bruggen B, Volodine A, Haesendonck CV, Korean J. Chem. Eng., 31(8), 1413 (2014)
Misdan N, Lau WJ, Ong CS, Ismail AF, Matsuura T, Korean J. Chem. Eng., 32(4), 753 (2015)
Mulder M, Basic Principles of Membrane Technology, Springer Science+Business Media Dordrecht, Netherlands (1996).
Koltuniewicz AB, Field RW, Arnot TC, J. Membr. Sci., 102, 193 (1995)
Han MJ, Nam ST, J. Membr. Sci., 202(1-2), 55 (2002)
Panda SR, De S, J. Polym. Res., 20, 1 (2013)
Brandes N, Welzel PB, Werner C, Kroh LW, J. Colloid Interface Sci., 299(1), 56 (2006)
Homayoonfal M, Mehrnia MR, Mojtahedi YM, Ismail AF, Desalin. Water Treat., 51, 3295 (2013)
Alhoshan M, Alam J, Dass LA, Al-Homaidi N, Adv. Polym. Technol., 32(4), 21369 (2013)
Moradihamedani P, Ibrahim NA, Ramimoghadam D, Yunus WMZW, Yusof NA, J. Appl. Polym. Sci., 131(16), 39745 (2014)
Gaur MS, Singh PK, Suruchi, Chauhan RS, J. Therm. Anal. Calorim., 111, 743 (2012)
Ismail AF, Hassan AR, Sep. Purif. Technol., 55(1), 98 (2007)
Chakrabarty B, Ghoshal AK, Purkait MK, J. Membr. Sci., 309(1-2), 209 (2008)