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Received February 7, 2016
Accepted July 2, 2016
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Enhancement of NO absorption in ammonium-based solution using heterogeneous Fenton reaction at low H2O2 consumption
Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, School of Energy and Environment, Southeast University, Nanjing 210096, Jiangsu, China
Korean Journal of Chemical Engineering, December 2016, 33(12), 3407-3416(10), 10.1007/s11814-016-0195-2
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Abstract
A novel NO removal system is designed, where NO is initially oxidized by .OH radicals from the decomposition of hydrogen peroxide (H2O2) over hematite and then absorbed by ammonium-based solution. According to the high performance liquid chromatography (HPLC) profile and the isopropanol injection experiments, the .OH radicals are proved to play a critical role in NO removal. The NO removal efficiency primarily depends on H2O2 concentration, gas hourly space velocity (GHSV), H2O2 feeding rate and reaction temperature, while the flue gas temperature slightly affects the NO removal efficiency. The low H2O2 consumption makes this system a promising technique in NO removal process using wet-method. The evolution of catalyst in reaction is analyzed by scanning electron microscopy (SEM), energy dispersive X-ray spectrometry (EDS), Fourier Transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). The nitrite ion and nitrate ion in aqueous solution are detected by the continuous phase flow analyzer. Finally, the macrokinetic parameters of the NO oxidation are obtained by using the initial rate method.
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References
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Zhang Q, Lee I, Joo JB, Zaera F, Yin Y, Acc. Chem. Res., 46, 1816 (2013)
Guo RT, Hao JK, Pan WG, Yu YI, Sep. Sci. Technol. (2014)
Zhao Y, Wen XY, Guo TX, Zhou JH, Fuel Process. Technol., 128, 54 (2014)
Fang P, Cen CP, Tang ZX, Zhong PY, Chen DS, Chen ZH, Chem. Eng. J., 168(1), 52 (2011)
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Guo TX, Experimental investigation on simultaneous removal of so 2 and no x in liquid phase by new-type complex absorbent, J. North China Electr. Power Univ., 69 (2011).
Zhao Y, Hao RL, Zhang P, Zhou SH, Energy Fuels, 28(10), 6502 (2014)
