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Received April 24, 2016
Accepted July 12, 2016
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Production of butene and butadiene by oxidative dehydrogenation of butane over carbon nanomaterial catalysts
Chemical Engineering, Inha University, 100 Inha-ro, Nam-gu, Incheon 22212, Korea
sungwon.hwang@inha.ac.kr
Korean Journal of Chemical Engineering, December 2016, 33(12), 3417-3424(8), 10.1007/s11814-016-0206-3
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Abstract
C4 alkenes are generally used to produce synthetic rubbers, plastics, and other important chemicals. Transition metal oxides are traditionally used as catalysts to produce C4 alkenes from n-butane by oxidative dehydrogenation (ODH). On the other hand, metal-free carbon nanomaterials are receiving much attention as catalysts for ODH due to their environmental benignity, corrosion resistance, and unique surface properties. In this work, a systematic methodology was designed to measure conversion of the reactants, selectivity to main products, and other catalytic performances of a set of carbon catalysts, including graphite and activated carbon. The experiments were carried out under a wide range of reaction conditions, and the reaction mechanism and kinetics were developed based on Marsvan Krevelen interpretation of the experimental results.
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Gascon J, Tellez C, Herguido J, Menendez M, Appl. Catal. A: Gen., 248(1-2), 105 (2003)
Setnicka M, Cicmanec P, Tvaruzkova E, Bulanek R, Top. Catal., 56, 662 (2013)
Weyten H, Keizer K, Kinoo A, Luyten J, Leysen R, AIChE J., 43(7), 1819 (1997)
Batist PA, Bouwens JFH, Schuit GCA, Bouwens JFH, Schuit GCA, J. Catal., 25, 1 (1972)
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Pereira MFR, Figueiredo JL, Orfao JJ, Serp P, Kalck P, Kihn Y, Carbon, 42, 2807 (2004)
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Mars P, Van Krevelen DW, Chem. Eng. Sci., 3, 41 (1954)
Yang CN, Rev. Mod. Phys., 34, 694 (1962)
Schwaab M, Pinto JC, Chem. Eng. Sci., 62(10), 2750 (2007)
