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Received April 2, 2016
Accepted July 18, 2016
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Experimental solubility and absorption mechanism of dilute SO2 in aqueous diethylene glycol dimethyl ether solution
College of Chemical Engineering, Inner Mongolia University of Technology, Huhhot 010051, China 1Department of Applied Chemistry, College of Chemistry & Molecular Engineering, Peking University, Beijing 100871, China
xhwei@pku.edu.cn
Korean Journal of Chemical Engineering, December 2016, 33(12), 3493-3503(11), 10.1007/s11814-016-0211-6
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Abstract
SO2 absorption capabilities of DEGDME+H2O system with different compositions were systemically investigated. The DEGDME+H2O system exhibited superior SO2 absorption capability and optimal desorption property with a desorption rate of higher than 94% under the desorption conditions. In addition, it has been demonstrated that the DEGDME+H2O system possessed remarkable SO2 absorbing and releasing capability after multiple recycles. Moreover, GLE data were measured for dilute SO2 in the system of DEGDME+H2O, in which SO2 partial pressures were determined in the range of 0 to 140 Pa. By fitting of GLE data, HLC, ΔH, ΔS and ΔG of SO2 absorption process were obtained. UV, FTIR, 1H-NMR, and 13C-NMR spectra of absorbing systems in the SO2 absorption processes were studied to elucidate the absorption mechanism. On the basis of the spectral results, the intermolecular hydrogen bonding and S...O interaction between SO2 with the absorption system were discussed.
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References
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Pereda S, Thomsen K, Rasmussen P, Chem. Eng. Sci., 55(14), 2663 (2000)
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Zhang JB, Zhang PY, Chen GH, Han F, Wei XH, J. Chem. Eng. Data, 53(7), 1479 (2008)
Zhang JB, Liu LH, Huo TR, Liu ZY, Zhang T, Wei XH, J. Chem. Thermodyn., 43(10), 1463 (2011)
Zhang N, Zhang JB, Zhang YF, Bai J, Huo TR, Wei XH, Fluid Phase Equilib., 313, 7 (2012)
Guo B, Zhao T, Sha F, Zhang F, Li Q, Zhang J, Korean J. Chem. Eng., 33(6), 1883 (2016)
Sciamanna SF, Scott L, Ind. Eng. Chem. Res., 27, 492 (1988)
Revelli AL, Mutelet F, Jaubert JN, J. Phys. Chem. B, 114(40), 12908 (2010)
Sun SY, Yan YX, Sun ZC, Xu QX, Wei XH, RSC Adv., 5, 8706 (2015)
Niu YX, Gao F, Sun SY, Xiao JB, Wei XH, Fluid Phase Equilib., 344, 65 (2013)
Chang Y, Zhang J, Li Q, Li L, Guo B, Zhao T, Korean J. Chem. Eng., 31(2), 2245 (2014)
Douabul A, Riley J, J. Chem. Eng. Data, 24, 274 (1979)
Rumpf B, Maurer G, Fluid Phase Equilib., 81, 241 (1992)
Li H, Liu DZ, Wang FA, J. Chem. Eng. Data, 47(4), 772 (2002)
Li H, Jiao X, Chen W, Phys. Chem. Liq., 52, 349 (2014)
Rabe AE, Harris JF, J. Chem. Eng. Data, 8, 333 (1963)
Vosolsobe J, Simecek S, Michalek J, Kadler B, Chem. Prum., 15, 401 (1965)
Xu QX, Sun SY, Lan GJ, Xiao JB, Zhang JB, Wei XH, J. Chem. Eng. Data, 60(1), 2 (2015)
Dethlefsen C, Hvidt A, J. Chem. Thermodyn., 17, 193 (1985)
Aminabhavi TM, Gopalakrishna B, J. Chem. Eng. Data, 40(2), 462 (1995)
Rodriguez-Sevilla J, Alvarez M, Liminana G, Diaz MC, J. Chem. Eng. Data, 47(6), 1339 (2002)
Anthony JL, Maginn EJ, Brennecke JF, J. Phys. Chem. B, 106(29), 7315 (2002)
Henni A, Tontiwachwuthikul P, Chakma A, Can. J. Chem. Eng., 83(2), 358 (2005)
Bamford HA, Poster DL, Baker JE, Environ. Toxicol. Chem., 18, 1905 (1999)
Fu XC, Shen WX, Physical Chemistry, 5th Ed. Higher Press, Beijing (2005).
Jin MJ, Hou YC, Wu WZ, Ren SH, Tian SD, Xiao L, Lei ZG, J. Phys. Chem. B, 115(20), 6585 (2011)
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Douabul A, Riley J, J. Chem. Eng. Data, 24, 274 (1979)
Al-Enezi G, Ettouney H, El-Dessouky H, Fawzi N, Ind. Eng. Chem. Res., 40(5), 1434 (2001)
Shaw AC, Romero MA, Elder RH, Ewan BCR, Allen RWK, Int. J. Hydrog. Energy, 36(8), 4749 (2011)
Augusta S, Anal. Chem., 45, 1744 (1973)
Lasgabaster A, Abad MJ, Barral L, Eur. Polym. J., 42, 3121 (2006)
Vandam MH, Lamine AS, Roizard D, Lochon P, Roizard C, Ind. Eng. Chem. Res., 36(11), 4628 (1997)
Yarra M, Rachapudi BNP, Mallampalli LKS, Eur. J. Inorg. Chem., 5, 260 (2014)
Frech R, Huang WW, Macromolecules, 28, 1246 (1994)
William DH, Fleming I, Spectroscopy Methods in Org. chemistry, 6th Ed. New York, McGraw-Hill (2005).
Zhao XY, Sun XY, Spectral identification for organic molecular structure, 2th Ed. Beijing (2010).
