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Received April 14, 2016
Accepted July 30, 2016
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Enhancing removal and recovery of magnesium from aqueous solutions by using modified zeolite and bentonite and process optimization
Department of Chemical Engineering, Tarbiat Modares University, Tehran 14115-114, Iran 1Research & Development Department, HOSSTECH Group, Singapore 528844, Singapore
Korean Journal of Chemical Engineering, December 2016, 33(12), 3529-3540(12), 10.1007/s11814-016-0218-z
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Abstract
Natural and modified zeolite and bentonite are investigated and characterized for extraction of magnesium from aqueous solutions. Magnesium removals as high as 85.21% and 81.73% were achieved by calcined bentonite and microwave radiated zeolite, respectively. The effects of various operational parameters were studied and optimized using selected isotherms. Maximum Mg (II) adsorption capacities of 26.24 and 35.67mg·g-1 were obtained on pristine and calcined bentonites, respectively. Thermodynamic studies suggest that magnesium adsorption on natural bentonite is spontaneous and endothermic (9.13 kj·mol-1). Also, desorption study of natural bentonite demonstrates that HNO3 is more effective by offering 89.11% desorption than other desorptive counterparts.
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References
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Xu D, Tan X, Chen C, Wang X, Appl. Clay Sci., 41, 37 (2008)
Thakre D, Rayalu S, Kawade R, Meshram S, Subrt J, Labhsetwar N, J. Hazard. Mater., 180(1-3), 122 (2010)
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Senturk HB, Ozdes D, Gundogdu A, Duran C, Soylak M, J. Hazard. Mater., 172(1), 353 (2009)
Naseem R, Tahir S, Water Res., 35, 3982 (2001)
Zheng H, Liu DH, Zheng Y, Liang SP, Liu Z, J. Hazard. Mater., 167(1-3), 141 (2009)
Karnitz O, Gurgel LVA, Gil LF, Carbohydr. Polym., 79, 184 (2010)
Aghakhani A, Mousavi SF, Mostafazadeh-Fard B, Rostamian R, Seraji M, Desalination, 275(1-3), 217 (2011)
Sepehr MN, Zarrabi M, Kazemian H, Amrane A, Yaghmaian K, Ghaffari HR, Appl. Surf. Sci., 274, 295 (2013)
Fu F, Wang Q, J. Environ. Manage., 92, 407 (2011)
Awual MR, Chem. Eng. J., 300, 264 (2016)
Greenlee LF, Lawler DF, Freeman BD, Marrot B, Moulin P, Water Res., 43, 2317 (2009)
Jamaly S, Darwish NN, Ahmed I, Hasan SW, Desalination, 354, 30 (2014)
Jeppesen T, Shu L, Keir G, Jegatheesan V, J. Clean Prod., 17, 703 (2009)
Le Dirach J, Nisan S, Poletiko C, Desalination, 182(1-3), 449 (2005)
Fu F, Wang Q, J. Environ. Manage., 92, 407 (2011)
Al Abdulgader H, Kochkodan V, Hilal N, Sep. Purif. Technol., 116, 253 (2013)
Birnhack L, Lahav O, Water Res., 41, 3989 (2007)
Muraviev D, Noguerol J, Valiente M, React. Funct. Polym., 28(2), 111 (1996)
Hosseini SS, Shahmirzadi MAA, Ir. J. Chem. Eng., 13, 91 (2015)
Hosseini SS, Bringas E, Tan NR, Ortiz I, Ghahramani M, Shahmirzadi MAA, J. Water Process Eng., 9, 78 (2016)
Shahmirzadi MAA, Hosseini SS, Ruan G, Tan NR, RSC Adv., 5, 49080 (2015)
Gupta VK, Ali I, Saleh TA, Nayak A, Agarwal S, RSC Adv., 2, 6380 (2012)
Mittal A, Mittal J, Malviya A, Gupta VK, J. Colloid Interface Sci., 340(1), 16 (2009)
Awual MR, Chem. Eng. J., 289, 65 (2016)
Awual MR, Yaita T, El-Safty SA, Shiwaku H, Suzuki S, Okamoto Y, Chem. Eng. J., 221, 322 (2013)
Awual MR, Yaita T, Shiwaku H, Suzuki S, Chem. Eng. J., 276, 1 (2015)
Gupta VK, Nayak A, Chem. Eng. J., 180, 81 (2012)
Gupta VK, Jain R, Mittal A, Saleh TA, Nayak A, Agarwal S, Sikarwar S, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 32, 12 (2012)
Gupta VK, Jain R, Nayak A, Agarwal S, Shrivastava M, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 31, 1062 (2011)
Karthikeyan S, Gupta V, Boopathy R, Titus A, Sekaran G, J. Mol. Liq., 173, 153 (2012)
Mittal A, Mittal J, Malviya A, Gupta VK, J. Colloid Interface Sci., 344(2), 497 (2010)
Naushad M, ALOthman ZA, Inamuddin, Javadian H, J. Ind. Eng. Chem., 25, 35 (2015)
Naushad M, ALOthman ZA, Khan MR, ALQahtani NJ, ALSohaimi IH, J. Ind. Eng. Chem., 20(6), 4393 (2014)
Alqadami AA, Naushad M, Abdalla MA, Ahamad T, Alothman ZA, Alshehri SM, RSC Adv., 6, 22679 (2016)
Gupta VK, Agarwal S, Saleh TA, J. Hazard. Mater., 185, 17 (2011)
Naushad M, Ahamad T, Sharma G, Al-Muhtaseb AH, Albadarin AB, Alam MM, ALOthman ZA, Alshehri SM, Ghfar AA, Chem. Eng. J., 300, 306 (2016)
Sharma G, Kumar A, Naushad M, Pathania D, Sillanpaa M, J. Ind. Eng. Chem., 33, 201 (2016)
Sharma G, Naushad M, Kumar A, Devi S, Khan MR, Iranian Polym. J., 24, 1003 (2015)
Tofighy MA, Mohammadi T, Desalination, 268(1-3), 208 (2011)
Karapinar N, Donat R, Desalination, 249(1), 123 (2009)
Ozcan AS, Ozcan A, J. Colloid Interface Sci., 276(1), 39 (2004)
Sen TK, Gomez D, Desalination, 267(2-3), 286 (2011)
Cooney EL, Booker NA, Shallcross DC, Stevens GW, Sep. Sci. Technol., 34(12), 2307 (1999)
Wang SB, Peng YL, Chem. Eng. J., 156(1), 11 (2010)
Aytas S, Yurtlu M, Donat R, J. Hazard. Mater., 172(2-3), 667 (2009)
Lei LC, Li XJ, Zhang XW, Sep. Purif. Technol., 58(3), 359 (2008)
Bertagnolli C, Kleinubing SJ, Silva MGCD, Appl. Clay Sci., 53, 73 (2011)
Motsi T, Rowson NA, Simmons MJH, Int. J. Miner. Process., 92(1-2), 42 (2009)
Kul AR, Koyuncu H, J. Hazard. Mater., 179(1-3), 332 (2010)
Celik SU, Bozkurt A, Hosseini SS, Prog. Polym. Sci, 37, 1265 (2012)
Hosseini SS, Membranes and Materials for Separation and Purification of Hydrogen and Natural Gas, PhD Thesis, Department of Chemical and Biomolecular Engineering, National University of Singapore (2009).
Greenberg AR, Kujundzic E, William BK, Yeo A, Hosseini SS, Determination of pore size in porous materials by evaporative mass loss, US Patent, 20130042670 (2011).
Hosseini SS, Chung TS, J. Membr. Sci., 328(1-2), 174 (2009)
Krantz WB, Greenberg AR, Kujundzic E, Yeo A, Hosseini SS, J. Membr. Sci., 438, 153 (2013)
Hosseini SS, Chung TS, Polymer blends and carbonized polymer blends, US Patent 8,623,124 (2014).
Najari S, Hosseini SS, Omidkhah M, Tan NR, RSC Adv., 5, 47199 (2015)
Hosseini SS, Najari S, in Polymeric Membranes for Gas and Vapor Separations, Nanostructured Polymer Membranes: Applications Vol. 2, Visakh PM, Olga N, Wiley (2016).
Hosseini SS, Roodashti SM, Kundu PK, Tan NR, Can. J. Chem. Eng., 93(7), 1275 (2015)
Hosseini SS, Dehkordi JA, Kundu PK, Korean J. Chem. Eng., DOI:10.1007/s11814-016-0198-z. (2016)
Faghihian H, Nejati-Yazdinejad M, Adsorpt. Sci. Technol., 27, 107 (2009)
Kazemian H, Modarress H, Kazemi M, Farhadi F, Powder Technol., 196(1), 22 (2009)
Hayati-Ashtiani M, Part. Sci. Technol., 31(4), 419 (2013)
Kurama H, Zimmer A, Reschetilowski T, Chem. Eng. Technol., 25(3), 301 (2002)
Liu ZR, Zhou SQ, Process Saf. Environ. Protect., 88(1), 62 (2010)
Xu D, Tan X, Chen C, Wang X, Appl. Clay Sci., 41, 37 (2008)
Thakre D, Rayalu S, Kawade R, Meshram S, Subrt J, Labhsetwar N, J. Hazard. Mater., 180(1-3), 122 (2010)
Plazinski W, Rudzinski W, J. Phys. Chem. C, 113, 12495 (2009)
Inglezakis VJ, Stylianou MA, Gkantzou D, Loizidou MD, Desalination, 210(1-3), 248 (2007)
Senturk HB, Ozdes D, Gundogdu A, Duran C, Soylak M, J. Hazard. Mater., 172(1), 353 (2009)
Naseem R, Tahir S, Water Res., 35, 3982 (2001)
Zheng H, Liu DH, Zheng Y, Liang SP, Liu Z, J. Hazard. Mater., 167(1-3), 141 (2009)
Karnitz O, Gurgel LVA, Gil LF, Carbohydr. Polym., 79, 184 (2010)
