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Received April 18, 2016
Accepted July 30, 2016
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Rapid and effective removal of sodium lignosulfonate from aqueous solutions by in-situ formed magnesium hydroxide
Shandong Provincial Key Laboratory of Water Pollution Control and Resource Reuse, School of Environmental Science & Engineering, Shandong University, Jinan 250100, P. R. China 1Key Laboratory of Colloid & Interface Science of Education Ministry, Shandong University, Jinan 250100, P. R. China
wutao@sdu.edu.cn
Korean Journal of Chemical Engineering, December 2016, 33(12), 3541-3549(9), 10.1007/s11814-016-0219-y
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Abstract
We investigated the efficiency of in-situ formed magnesium hydroxide (Mg(OH)2) for the removal of sodium lignosulfonate (SLSN) from aqueous solution. Adsorption experiments considered the effects of various conditions such as pH, MgCl2 concentration, contact time, and temperature on SLSN removal efficiency. It was found that approximately 93%-99% SLSN was removed by in-situ formed Mg(OH)2. The adsorption was rapid, and the contact time required to reach complete adsorption equilibrium was less than 2min. Moreover, that the Mg(OH)2 lost about 0.5-3.0% adsorption capacity for SLSN when NO3-, HCO3-, H2PO4- and SO42- anions were simultaneously present with SLSN. The experimental data suggested that there was little competitive adsorption of SLSN with other coexisting anions on Mg(OH)2. The co-precipitation/adsorption process was exothermic and physical, involving weak interactions such as electrostatic attraction, hydrogen bonding, adhesive forces, and van der Waals forces between SLSN molecules and the binding sites on Mg(OH)2.
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References
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Hansen BR, Davies SR, Chem. Eng. Res. Des., 72(2), 176 (1994)
Babu K, Pal N, Saxena VK, Mandal A, Korean J. Chem. Eng., 33, 711 (2015)
Zhang J, Wang Y, Peng Q, Korean J. Chem. Eng., 30(6), 1284 (2013)
Cheng L, Ye LL, Sun DJ, Wu T, Li YJ, Chem. Eng. J., 264, 672 (2015)
Liu X, Zhao Y, Li Q, Jiao T, Niu J, J. Mol. Liq., 216, 185 (2016)
Jiang P, Li N, Ge J, Zhang G, Wang Y, Chen L, Zhang L, Colloids Surf. A: Physicochem. Eng. Asp., 443, 141 (2014)
Gong H, Xin X, Xu G, Wang Y, Colloids Surf. A: Physicochem. Eng. Asp., 317, 522 (2008)
Tichelkamp T, Teigen E, Nourani M, Oye G, Chem. Eng. Sci., 132, 244 (2015)
Al-Amodi AO, Al-Mubaiyedh UA, Sultan AS, Kamal MS, Hussein IA, Can. J. Chem. Eng., 94(3), 454 (2016)
Li F, He W, Sun D, Wu T, Li Y, J. Clean Prod., 104, 468 (2015)
Miao L, Li F, Sun D, Wu T, Li Y, J. Pet. Sci. Eng., 133, 18 (2015)
Adeel Z, Luthy RG, Environ. Sci. Technol., 29, 1032 (1995)
Cano ML, Dorn PB, Environ. Toxicol. Chem., 15, 684 (1996)
Qin Y, Yang D, Guo W, Qiu X, J. Ind. Eng. Chem., 27, 192 (2015)
Park S, Lee ES, Sulaiman WRW, J. Ind. Eng. Chem., 21, 1239 (2015)
Fox K, Holt M, Daniel M, Buckland H, Guymer I, Sci. Total Environ., 251, 265 (2000)
Zou W, Liu L, Li H, Han X, Korean J. Chem. Eng., 33(7), 2073 (2016)
Karidakis T, Agatzini-Leonardou S, Neou-Syngouna P, Hydrometallurgy, 76, 105 (2005)
Henrist C, Mathieu JP, Vogels C, Rulmont A, Cloots R, J. Cryst. Growth, 249(1-2), 321 (2003)
Liu SP, J. Ind. Eng. Chem., 20(4), 2401 (2014)
Yeh J, Yang H, Huang S, Polym. Degrad. Stabil., 50, 229 (1995)
Takagaki A, Sugisawa M, Lu DL, Kondo JN, Hara M, Domen K, Hayashi S, J. Am. Chem. Soc., 125(18), 5479 (2003)
Yu JC, Xu AW, Zhang LZ, Song RQ, Wu L, J. Phys. Chem. B, 108(1), 64 (2004)
Jiang WJ, Hua X, Han QF, Yang XJ, Lu LD, Wang X, Powder Technol., 191(3), 227 (2009)
Ranjit KT, Klabunde KJ, Chem. Mater., 17, 65 (2005)
Ding Y, Zhang G, Wu H, Hai B, Wang L, Qian Y, Chem. Mater., 13, 435 (2001)
Diao Y, Walawender WP, Sorensen CM, Klabunde KJ, Ricker T, Chem. Mater., 14, 362 (2002)
Fan W, Sun S, You L, Cao G, Song X, Zhang W, Yu H, J. Mater. Chem., 13, 3062 (2003)
Lv X, Li M, Ma X, Ma S, Gao Y, Tang L, Zhao J, Guo Y, Zhao X, Wang Z, Colloids Surf. A: Physicochem. Eng. Asp., 296, 97 (2007)
Deng Y, Dixon JB, White GN, Loeppert RH, Juo AS, Colloids Surf. A: Physicochem. Eng. Asp., 281, 82 (2006)
Wang P, Li C, Gong H, Wang H, Liu J, Ceram. Int., 37, 3365 (2011)
Liu H, Yi JH, Appl. Surf. Sci., 255(11), 5714 (2009)
An D, Ding X, Wang Z, Liu Y, Colloids Surf. A: Physicochem. Eng. Asp., 356, 28 (2010)
Schott H, J. Pharm. Sci., 70, 486 (1981)
Hunter R, Academic Press, London (1981).
Gustafsson J, KTH Department of Land and Water Resources Engineering, Stockholm, Sweden. Based on de Allison JD, Brown DS, Novo-Gradac KJ, MINTEQA2 ver 4, 1991 (2011).
Li F, Ye L, Li Y, Wu T, RSC Adv., 6, 31092 (2016)
Krishnan SV, Iwasaki I, Environ. Sci. Technol., 20, 1224 (1986)
Alkaram UF, Mukhlis AA, Al-Dujaili AH, J. Hazard. Mater., 169(1-3), 324 (2009)
Dogan M, Ozdemir Y, Alkan M, Dyes Pigment., 75, 701 (2007)
Wang SB, Li HT, J. Hazard. Mater., 126(1-3), 71 (2005)
Aman ZM, Brown EP, Sloan ED, Sum AK, Koh CA, Phys. Chem. Chem. Phys., 13, 19796 (2011)
Doppenschmidt A, Butt HJ, Langmuir, 16(16), 6709 (2000)
Aman ZM, Olcott K, Pfeiffer K, Sloan ED, Sum AK, Koh CA, Langmuir, 29(8), 2676 (2013)
Zhang C, Yang SG, Chen HZ, He H, Sun C, Appl. Surf. Sci., 301, 329 (2014)
Langmuir I, J. Am. Chem. Soc., 38, 2221 (1916)
Freundlich HMF, Zeitschrift Fur Physikalische Chemie (Leipzig), 57, 385 (1906)
de Escobar CC, Fisch A, dos Santos JHZ, Ind. Eng. Chem. Res., 54(1), 254 (2015)
Shakeri H, Arshadi M, Salvacion JWL, J. Colloid Interface Sci., 466, 186 (2016)
Fan JL, Zhang JA, Zhang CL, Ren LA, Shi QQ, Desalination, 267(2-3), 139 (2011)
Zhou YM, Zhang M, Wang XH, Huang Q, Min YH, Ma TS, Niu JY, Ind. Eng. Chem. Res., 53(13), 5498 (2014)
Li C, Zhong H, Wang S, Xue J, Zhang Z, J. Ind. Eng. Chem., 23, 344 (2015)
Gobi K, Mashitah MD, Vadivelu VM, Chem. Eng. J., 171(3), 1246 (2011)
Ho YS, McKay G, Process Saf. Environ. Protect., 76(4), 332 (1998)
Rawat J, Singh D, J. Inorg. Nucl. Chem., 40, 897 (1978)
Zhu L, Ren X, Yu S, Environ. Sci. Technol., 32, 3374 (1998)
Moustafa AM, McPhedran KN, Moreira J, El-Din MG, Environ. Sci. Technol., 48, 14472 (2014)
Geelhoed JS, Hiemstra T, Van Riemsdijk WH, Geochim. Cosmochim. Acta, 61, 2389 (1997)
Xi J, He M, Lin C, Microchem J., 97, 85 (2011)
Hansen BR, Davies SR, Chem. Eng. Res. Des., 72(2), 176 (1994)
