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Received February 26, 2015
Accepted June 29, 2015
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Enhanced electrokinetic remediation of fluorine-contaminated soil by applying an ammonia continuous circulation system
Chemical Engineering and Pharmaceutics School, Henan University of Science and Technology, Luoyang, P. R. China
zhushufa@126.com
Korean Journal of Chemical Engineering, February 2016, 33(2), 547-552(6), 10.1007/s11814-015-0143-6
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Abstract
The objective of this research was to investigate the effects of ammonia continuous circulation enhanced electrokinetic remediation of fluorine contaminated soil and to analyze its influence on soil pH after remediation. An experimental study was carried out in self-made electrokinetic apparatus. The voltage gradient was set at 1.0V/cm and ammonia water with different concentrations was used as electrolyte which circulated in series. Comparative studies were made by using deionized water as electrolyte which circulated separately in one experiment and continuously in another. According to the experiment the continuous circulation of ammonia water increased the current value during the remediation process and maintained current through the soil cell stabler, which not only increased fluorine migration but also reduced energy consumption. Among the given ammonia concentrations (0, 0.01, 0.1 and 0.2mol/L) the removal rate increased with ammonia concentration. 0.2mol/L had the highest current (26.8mA), and the removal rate amounted up to 57.3%. By using ammonia circulation enhanced electrokinetic technology, the difference between pH values of cathode soil and anode soil became smaller. Ammonia continuous circulation enhanced electrokinetics can effectively remediate fluorine contaminated soil and the residual ammonia in the soil can also improve soil fertility.
References
Chinese Statistical Bulletin of Health and Family Planning Career Development in 2013.
Hao Y, Sun DJ, Wei HL, Zhao XH, Shen YF, Wang LH, Sun YF, Yu GQ, Chin. J. Endemiol., 21, 63 (2002)
Chen HF, Yan M, Yang XF, Chen Z, Wang GG, Dietrich SV, Xu YF, Xu JC, J. Hazard. Mater., 235-236, 201 (2012)
Xue SY, Li P, Wang SL, Nan ZR, Environ. Sci., 35, 1075 (2014)
Camargo JA, Chemosphere, 50, 251 (2003)
Wang LF, Huang JZ, Soc. Sci. Med., 41, 1191 (1995)
Agnew K, Cundy AB, Hopkinson L, Croudace IW, Warwick PE, Purdie P, J. Hazard. Mater., 186(2-3), 1405 (2011)
Wan JZ, Li ZR, Lu XH, Yuan SH, J. Hazard. Mater., 184(1-3), 184 (2010)
Ryu BG, Park GY, Yang JW, Baek K, Sep. Purif. Technol., 79(2), 170 (2011)
Paula G, Eduardo PM, Nazare C, Yadira R, Alexandra BR, Chemosphere, 117, 124 (2014)
Probstein RF, Hicks RE, Science, 260, 498 (1993)
Abou-Shady A, Peng C, J. Ind. Eng. Chem., 18(6), 2162 (2012)
Mena E, Ruiz C, Villasenor J, Rodrigo MA, Canizares P, J. Hazard. Mater., 283, 131 (2015)
Pomes V, Fernandez A, Costarramone N, Grano B, Houi D, Colloids Surf. A: Physicochem. Eng. Asp., 159, 481 (1999)
Kim DH, Jeon CS, Baek K, Ko SH, Yang JS, J. Hazard. Mater., 161(1), 565 (2009)
Zhu SF, Zhang JH, Dong TY, Environ. Earth. Sci., 59, 379 (2009)
Costarramone N, Tellier S, Grano B, Lecomte D, Astruc M, Environ. Technol., 21, 789 (2000)
Zhou M, Zhu S, Liu F, Zhou D, Korean J. Chem. Eng., 31(11), 2008 (2014)
Standard of agriculture sector of the People’s Republic of China, Determination of pH in soil. NY/T 1377-2007.
National Standard of the People’s Republic of China. Soil quality-Analysis of fluoride-Ion selective electrometry. GB/T 22104-2008.
National Standard of the People’s Republic of China. Solid waste-Determination of fluoride-Ion selective electrode method, GB/T 15555.11-1995.
Acar YB, Alshawabkeh AN, Environ. Sci. Technol., 27, 2638 (1993)
Ryu BG, Park GY, Yang JW, Baek K, Sep. Purif. Technol., 79(2), 170 (2011)
Yuan C, Chiang TS, J. Hazard. Mater., 152(1), 309 (2008)
Costarramone N, Tellier S, Grano B, Lecomte D, Astruc M, Environ. Technol., 21, 789 (2000)
Ho SV, Athmer C, Sheridan PW, Environ. Sci. Technol., 33, 1092 (1999)
Chung HI, Kang BH, Eng. Geol., 53, 139 (1999)
Tasuma S, Mai M, Yohhei O, J. Hazard. Mater., 254-255, 310 (2013)
Chang JH, Cheng SF, J. Hazard. Mater., 141(1), 168 (2007)
Kim SO, Kim WS, Kim KW, Environ. Geochem. Health, 27, 443 (2005)
Al-Hamdan AZ, Reddy KR, Chemosphere, 71, 860 (2008)
Wenzel WW, Blum WEH, Soil Sci., 153, 357 (1992)
Barrow NJ, Ellis AS, J. Soil Sci., 37, 287 (1986)
Hao Y, Sun DJ, Wei HL, Zhao XH, Shen YF, Wang LH, Sun YF, Yu GQ, Chin. J. Endemiol., 21, 63 (2002)
Chen HF, Yan M, Yang XF, Chen Z, Wang GG, Dietrich SV, Xu YF, Xu JC, J. Hazard. Mater., 235-236, 201 (2012)
Xue SY, Li P, Wang SL, Nan ZR, Environ. Sci., 35, 1075 (2014)
Camargo JA, Chemosphere, 50, 251 (2003)
Wang LF, Huang JZ, Soc. Sci. Med., 41, 1191 (1995)
Agnew K, Cundy AB, Hopkinson L, Croudace IW, Warwick PE, Purdie P, J. Hazard. Mater., 186(2-3), 1405 (2011)
Wan JZ, Li ZR, Lu XH, Yuan SH, J. Hazard. Mater., 184(1-3), 184 (2010)
Ryu BG, Park GY, Yang JW, Baek K, Sep. Purif. Technol., 79(2), 170 (2011)
Paula G, Eduardo PM, Nazare C, Yadira R, Alexandra BR, Chemosphere, 117, 124 (2014)
Probstein RF, Hicks RE, Science, 260, 498 (1993)
Abou-Shady A, Peng C, J. Ind. Eng. Chem., 18(6), 2162 (2012)
Mena E, Ruiz C, Villasenor J, Rodrigo MA, Canizares P, J. Hazard. Mater., 283, 131 (2015)
Pomes V, Fernandez A, Costarramone N, Grano B, Houi D, Colloids Surf. A: Physicochem. Eng. Asp., 159, 481 (1999)
Kim DH, Jeon CS, Baek K, Ko SH, Yang JS, J. Hazard. Mater., 161(1), 565 (2009)
Zhu SF, Zhang JH, Dong TY, Environ. Earth. Sci., 59, 379 (2009)
Costarramone N, Tellier S, Grano B, Lecomte D, Astruc M, Environ. Technol., 21, 789 (2000)
Zhou M, Zhu S, Liu F, Zhou D, Korean J. Chem. Eng., 31(11), 2008 (2014)
Standard of agriculture sector of the People’s Republic of China, Determination of pH in soil. NY/T 1377-2007.
National Standard of the People’s Republic of China. Soil quality-Analysis of fluoride-Ion selective electrometry. GB/T 22104-2008.
National Standard of the People’s Republic of China. Solid waste-Determination of fluoride-Ion selective electrode method, GB/T 15555.11-1995.
Acar YB, Alshawabkeh AN, Environ. Sci. Technol., 27, 2638 (1993)
Ryu BG, Park GY, Yang JW, Baek K, Sep. Purif. Technol., 79(2), 170 (2011)
Yuan C, Chiang TS, J. Hazard. Mater., 152(1), 309 (2008)
Costarramone N, Tellier S, Grano B, Lecomte D, Astruc M, Environ. Technol., 21, 789 (2000)
Ho SV, Athmer C, Sheridan PW, Environ. Sci. Technol., 33, 1092 (1999)
Chung HI, Kang BH, Eng. Geol., 53, 139 (1999)
Tasuma S, Mai M, Yohhei O, J. Hazard. Mater., 254-255, 310 (2013)
Chang JH, Cheng SF, J. Hazard. Mater., 141(1), 168 (2007)
Kim SO, Kim WS, Kim KW, Environ. Geochem. Health, 27, 443 (2005)
Al-Hamdan AZ, Reddy KR, Chemosphere, 71, 860 (2008)
Wenzel WW, Blum WEH, Soil Sci., 153, 357 (1992)
Barrow NJ, Ellis AS, J. Soil Sci., 37, 287 (1986)