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- In relation to this article, we declare that there is no conflict of interest.
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Received June 15, 2015
Accepted July 30, 2015
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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1-Methyl-3-octylimidazolium tetrafluoroborate/AgO nanoparticles composite membranes for facilitated gas transport
Department of Chemistry, Sangmyung University, Seoul 110-743, Korea
swkang@smu.ac.kr
Korean Journal of Chemical Engineering, February 2016, 33(2), 666-668(3), 10.1007/s11814-015-0169-9
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Abstract
AgO nanoparticles (NPs) were generated in ionic liquid 1-methyl-3-octylimidazolium tetrafluoroborate (Moim+BF4 .). The formation of Ag NPs was attributable to the favorable interaction between the surface of particles and counteranions of ionic liquid. The generated AgO nanoparticles in Moim+BF4 . were confirmed by TEM, and the average size was 40 nm. Coordinative interactions of AgO NPs with Moim+BF4 . were investigated by FT-Raman spectroscopy. The prepared Moim+BF4 ./Ag NPs composites were utilized for CO2 separation membrane, and consequently, CO2 separation performance for composite membranes was improved compared with neat Moim+BF4 .. The ideal selectivity for CO2/N2 was 23.4 with a CO2 permeance of 18.7GPU was observed, while the neat Moim+BF4 . membrane showed a selectivity of 15.9 and a CO2 permeance of 12.7GPU.
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