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- In relation to this article, we declare that there is no conflict of interest.
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Received April 7, 2015
Accepted October 19, 2015
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Copyright © KIChE. All rights reserved.
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Constructing polyurethane foams of strong mechanical property and thermostability by two novel environment friendly bio-based polyols
1Institute of Chemical Industry of Forestry Products, CAF, Key Lab. of Biomass Energy and Material, Jiangsu Province, National Engineering Lab. for Biomass Chemical Utilization, Key and Open Lab. on Forest Chemical Engineering, SFA, Nanjing 210042, China 2Institute of Forest New Technology, CAF, Beijing 100091, China 3, China
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Korean Journal of Chemical Engineering, March 2016, 33(3), 1088-1094(7), 10.1007/s11814-015-0223-7
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Abstract
Two novel cardanol-based polyols were synthesized and used to construct polyurethane (PU) foams. The cardanol-based polyols with high reactivity were obtained from the epoxidation of cardanol, followed by the ring opening reaction of epoxy group with diethanolamine (DEA). Subsequently, PU foams were synthesized by these cardanolbased polyols. Compared with petroleum-based (PEG) PU foams, these green cardanol-based PU foams exhibit better mechanical property and higher thermostability. Scanning electron microscopy (SEM) tests show that the cells of cardanol-based PU foams are monodisperse, with fairly uniform spherical shape and regular size.
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References
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Myriam D, Maxime E, Remi A, Sylvain C, Bernard B, Polym. Rev., 52, 38 (2012)
Narine SS, Kong X, Bouzidi L, Sporns P, J. Am. Oil Chem. Soc., 84, 55 (2007)
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Pfister DP, Xia Y, Larock RC, ChemSusChem, 4, 703 (2011)
Petrovi ZS, Polym. Rev., 48, 109 (2008)
Balachandran VS, Jadhav SR, Vemula PK. John G, Chem. Soc. Rev., 42, 427 (2013)
Auvergne R, Caillol S, David G, Boutevin B, Pascault JP, Chem. Rev., 114(2), 1082 (2014)
Kumar PP, Paramashivappa R, Vithayathil PJ, Subba RPV, Srinivasa AR, J. Agric. Food Chem., 50, 4705 (2002)
Maia FJN, Ribeiro VGP, Lomonaco D, Luna FMT, Mazzetto SE, Ind. Crop. Prod., 36, 271 (2012)
Mohapatra S, Nando GB, RSC Adv., 4, 15406 (2014)
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Huang K, Zhang Y, Li M, Lian JW, Yang XH, Xia JL, Prog. Org. Coat., 74, 240 (2012)
Cardona F, Kin-Tak AL, Fedrigo J, J. Appl. Polym. Sci., 123(4), 2131 (2012)
Jaillet F, Darroman E, Ratsimihety A, Auvergne R, Boutevin B, Caillol S, Eur. J. Lip. Sci. Technol., 116, 63 (2014)
Guo A, Zhang W, Petrovic ZS, J. Mater. Sci., 41(15), 4914 (2006)
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Dombrow BA, Polyurethanes P, 2nd Ed. Reinhold Publishing Corp., New York (1965).
Rao BS, Palanisamy A, Eur. Polym. J., 49, 2365 (2013)
Zhang LQ, Zhang M, Hu LH, Zhou YH, Ind. Crop. Prod., 52, 380 (2014)
Suresh KI, ASC Sustainable Chem. Eng., 1, 232 (2013)
Rashmi BJ, Rusu D, Prashantha K, Lacrampe MF, Krawczak P, J. Appl. Polym. Sci., 128(1), 292 (2013)
Jin JF, Chen YL, Wang DN, Hu CP, Zhu S, Vanoverloop L, Randall D, J. Appl. Polym. Sci., 84(3), 598 (2002)
Zou XW, Qin TF, Wang Y, Huang LH, Han YM, Li Y, Bioresour. Technol., 114, 654 (2012)
Li S, Vatanparast R, Lemmetyinen H, Polymer, 41(15), 5571 (2000)
Huo SP, Nie MC, Kong ZW, Wu GM, Chen J, J. Appl. Polym. Sci., 125(1), 152 (2012)
Cateto CA, Barreiro MF, Rodrigues AE, Belgacem MN, React. Funct. Polym., 71(8), 863 (2011)
Elwell MJ, Ryan AJ, Grunbauer HJ, Vanlieshout HC, Polymer, 37(8), 1353 (1996)
Han H, Li SH, Zhu XL, Jiang XB, Kong XZ, RSC Adv., 4, 33520 (2014)
Luo N, Wang DN, Ying SK, Polymer, 37(16), 3577 (1996)
Rashmi BJ, Rusu D, Prashantha K, Lacrampe MF, Krawczak P, J. Appl. Polym. Sci., 128(1), 292 (2013)
Mu YB, Wan XB, Han ZX, Peng YX, Zhong S, J. Appl. Polym. Sci., 124(5), 4331 (2012)
Xue BL, Wen JL, Sun RC, ACS Sustainable Chem. Eng., 2, 1474 (2014)
Lan ZY, Daga R, Whitehouse R, McCarthy S, Schmidt D, Polymer, 55, 2635 (2014)
Tan SQ, Abraham T, Ference D, Macosko CW, Polymer, 52(13), 2840 (2011)
Silva VRD, Mosiewicki MA, Yoshida MI, Silva MCD, Stefani PM, Marcovich NE, Polym. Test, 32, 438 (2013)
Corcuera MA, Rueda L, Fernandez BA, Arbelaiz A, Marieta C, Mondragon I, Eceiza A, Polym. Degrad. Stabil., 95, 2175 (2010)
Kramer RH, Zammarano M, Linteris GT, Gedde UW, Gilman JW, Polym. Degrad. Stabil., 95, 1115 (2010)
Berta M, Lindsay C, Pans G, Camino G, Polym. Degrad. Stabil., 91, 1179 (2006)
Duquesne S, Bras ML, Bourbigot S, Delobe R, Camino G, Eling B, Lindsay C, Roels T, Polym. Degrad. Stabil., 74, 493 (2011)
Kong X, Narine SS, Biomacromolecules, 8(7), 2203 (2007)
