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Received November 24, 2015
Accepted December 30, 2015
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Environmental plasma-catalysis for the energy-efficient treatment of volatile organic compounds
Department of Chemical and Biological Engineering, Jeju National University, Jeju 690-756, Korea
smokie@jejunu.ac.kr
Korean Journal of Chemical Engineering, March 2016, 33(3), 735-748(14), 10.1007/s11814-015-0300-y
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Abstract
Nonthermal plasma (NTP) coupled with catalysis is a promising technique for the abatement of dilute volatile organic compounds (VOCs), because it is operable under mild reaction conditions, i.e., low temperature and atmospheric pressure. This review addresses the mechanistic aspects of catalyst activation by NTP, such as the generation and fixation of reactive species, facilitation of redox cycles, photocatalysis, and local heating, to clarify the combined effects of plasma and catalysis. The plasma-catalytic removal of VOCs preferentially requires the catalyst to have a large specific surface area, high surface oxygen storage capacity, and to be highly reducible. The energy consumption and deactivation of catalysts are considered by comparing continuous and cyclic operations in terms of specific input energy, VOC removal and energy efficiencies, and byproduct formation. Based on the information in the literature, a plasma-catalytic system operating in cyclic adsorption-oxidation mode is recommended for the treatment of air contaminated by dilute VOCs. Finally, the effects of NTP on the regeneration of deactivated catalysts are also discussed.
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Jarrige J, Vervisch P, Appl. Catal. B: Environ., 90(1-2), 74 (2009)
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Tang XJ, Feng FD, Ye LL, Zhang XM, Huang YF, Liu Z, Yan KP, Catal. Today, 211, 39 (2013)
Li W, Oyama ST, J. Am. Chem. Soc., 120(35), 9047 (1998)
Dinh MTN, Giraudon JM, Lamonier JF, Vandenbroucke A, De Geyter N, Leys C, Morent R, Appl. Catal. B: Environ., 147, 904 (2014)
Dinh MTN, Giraudon JM, Vandenbroucke AM, Morent R, Geyter ND, Lamonier JF, Appl. Catal. B: Environ., 172-173, 65 (2015)
Li YZ, Fan ZY, Shi JW, Liu ZY, Shangguan WF, Chem. Eng. J., 241, 251 (2014)
Vandenbroucke AM, Mora M, Sanchidrian CJ, Salguero FJR, Geyter ND, Leys C, Morent R, Appl. Catal. B: Environ., 156-157, 94 (2014)
Delagrange S, Pinard L, Tatibouet JM, Appl. Catal. B: Environ., 68(3-4), 92 (2006)
Li Y, Fan Z, Shi J, Liu Z, Zhou J, Shangguan W, Catal. Today, 256, 178 (2015)
Vandenbroucke AM, Dinh MTN, Nuns N, Giraudon JM, Geyter ND, Leys C, Morent R, Chem. Eng. J., 283, 668 (2016)
Ogata A, Saito K, Kim HH, Sugasawa M, Aritani H, Einaga H, Plasma Chem. Plasma Process., 30(1), 33 (2010)
Trinh QH, Mok YS, Catalysts, 5(2), 800 (2015)
Jo JO, Lee SB, Jang DL, Mok YS, IEEE Trans. Plasma Sci., 41(10), 3021 (2013)
Zhu X, Gao X, Yu X, Zheng C, Tu X, Catal. Today, 256, 108 (2015)
Trinh HQ, Mok YS, Chem. Eng. J., 251, 199 (2014)
Huang R, Lu M, Wang P, Chen Y, Wu J, Fu M, Chen L, Ye D, RSC Adv., 5, 72113 (2015)
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Ding HX, Zhu AM, Lu FG, Xu Y, Zhang J, Yang XF, J. Phys. D-Appl. Phys., 39(16), 3603 (2006)
Futamura S, Zhang AH, Einaga H, Kabashima H, Catal. Today, 72(3-4), 259 (2002)
Lu MJ, Huang R, Wu JL, Fu ML, Chen LM, Ye DQ, Catal. Today, 242, 274 (2015)
Ogata A, Kim HH, Oh SM, Futamura S, Thin Solid Films, 506-507, 373 (2006)
Chavadej S, Saktrakool K, Rangsunvigit P, Lobban LL, Sreethawong T, Chem. Eng. J., 132(1-3), 345 (2007)
Sano T, Negishi N, Sakai E, Matsuzawa S, J. Mol. Catal. A-Chem., 245(1-2), 235 (2006)
Hashimoto K, Irie H, Fujishima A, Jpn. J. Appl. Phys., 44(12), 8269 (2005)
Pekarek S, Mikes J, Krysa J, Appl. Catal. A: Gen., 502, 122 (2015)
Gandhi MS, Mok YS, Chemosphere, 117, 440 (2014)
Saulich K, Muller S, J. Phys. D-Appl. Phys., 46(4), 045201 (2013)
Kuroki T, Fujioka T, Kawabata R, Okubo M, Yamamoto T, IEEE Trans. Ind. Appl., 45(1), 10 (2009)
Rousseau A, Dantier A, Gatilova L, Ionikh Y, Ropcke J, Tolmachev YA, Plasma Sources Sci. Technol., 14(1), 70 (2005)
Kim HH, Ogata A, Futamura S, IEEE Trans. Plasma Sci., 34(3), 984 (2006)
Kim HH, Ogata A, Futamura S, Int. J. Plasma Environ. Sci. Technol., 1(1), 46 (2007)
Fan X, Zhu TL, Sun YF, Yan X, J. Hazard. Mater., 196, 380 (2011)
Zhao DZ, Li XS, Shi C, Fan HY, Zhu AM, Chem. Eng. Sci., 66(17), 3922 (2011)
California Department of Public Health, Emission testing method for California Specification 01350 (2010).
Trinh QH, Gandhi MS, Mok YS, Jpn. J. Appl. Phys., 54, 01AG04 (2015)
Mok YS, Kim DH, Curr. Appl. Phys., 11(5), S58 (2011)
Xu X, Wang P, Xu W, Wu J, Chen L, Fu M, Ye D, Chem. Eng. J., 283, 276 (2016)
Liang WJ, Ma L, Liu H, Li J, Chemosphere, 92(10), 1390 (2013)
Ogata A, Yamanouchi K, Mizuno K, Kushiyama S, Yamamoto T, Plasma Chem. Plasma Process., 19(3), 383 (1999)
Ding HX, Zhu AM, Yang XF, Li CH, Xu Y, J. Phys. D-Appl. Phys., 38(23), 4160 (2005)
Kuroki T, Hirai K, Kawabata R, Okubo M, Yamamoto T, IEEE Trans. Ind. Appl., 46(2), 672 (2010)
Trinh QH, Mok YS, Catal. Today, 256, 170 (2015)
Sivachandiran L, Thevenet F, Rousseau A, Plasma Chem. Plasma Process., 33(5), 855 (2013)
Sivachandiran L, Thevenet F, Rousseau A, Chem. Eng. J., 270(15), 327 (2015)
Kim KJ, Ahn HG, Microporous Mesoporous Mater., 152, 78 (2012)
Sultana S, Vandenbroucke AM, Leys C, Geyter ND, Morent R, Catalysts, 5(2), 718 (2015)
Teramoto Y, Kim HH, Negishi N, Ogata A, Catalysts, 5(2), 838 (2015)
Yang RT, Kikkinides ES, AIChE J., 41(3), 509 (1995)
Padin J, Yang RT, Chem. Eng. Sci., 55(14), 2607 (2000)
Kim H, Park J, Jung Y, Phys. Chem. Chem. Phys., 15, 19644 (2013)
Kim HH, Kim JH, Ogata A, J. Phys. D-Appl. Phys., 42(13), 135210 (2009)
Kim HH, Ogata A, Futamura S, Appl. Catal. B: Environ., 79(4), 356 (2008)
Trinh QH, Lee SB, Mok YS, J. Hazard. Mater., 285, 525 (2015)
Mallard WG, Westley F, Herron JT, Hampso R, NIST chemical kinetics database: Version 2Q98. Gaithersburg, MD, USA:NIST (1998).
Subrahmanyam C, Renken A, Kiwi-Minsker L, Appl. Catal. B: Environ., 65(1-2), 157 (2006)
Fan HY, Shi C, Li XS, Zhang S, Liu JL, Zhu AM, Appl. Catal. B: Environ., 119-120, 49 (2012)
HafezKhiabani N, Fathi S, Shokri B, Hosseini SI, Appl. Catal. A: Gen., 493, 8 (2015)
Yamamoto T, Asada S, Iida T, Ehara Y, IEEE Trans. Ind. Appl., 47(5), 2235 (2011)
Huang Y, Dai S, Feng F, Zhang X, Liu Z, Yan K, Environ. Sci. Pollut. Res., 22(23), 19240 (2015)
