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Received June 9, 2015
Accepted November 11, 2015
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Dehydration of D-xylose over SiO2-Al2O3 catalyst:Perspective on the pathways for condensed products
1Department of Energy Systems Research, Ajou University, Suwon 16499, Korea 2Department of Chemical Engineering, Ajou University, Suwon 16499, Korea
mjpark@ajou.ac.kr
Korean Journal of Chemical Engineering, March 2016, 33(3), 806-811(6), 10.1007/s11814-015-0238-0
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Abstract
This work addresses the kinetic mechanism for the dehydration of D-xylose over the SiO2-Al2O3 solid catalyst, where the formation of condensed products is included in addition to the production of furfural and its decomposition. The kinetic modeling and parametric sensitivity show that the isomerization of D-xylose takes place in the early stages of the reaction, followed by the dehydration of isomers. Accordingly, the homogeneous polymerization of isomers is found to be dominant. The developed model is used to evaluate the effects of operating conditions on the catalytic performance; high temperature and D-xylose concentration guarantee high furfural yield.
References
Lange JP, van der Heide E, van Buijtenen J, Price R, ChemSusChem, 5, 150 (2012)
Zeitsch KJ, The Chemistry and Technology of Furfural and its Many By-products, Elsevier Science, Amsterdam (2000).
Aida TM, Shiraishi N, Kubo M, Watanabe M, Smith RL, J. Supercrit. Fluids, 55(1), 208 (2010)
Wang S, Du Y, Zhang P, Cheng X, Qu Y, Korean J. Chem. Eng., 31(12), 2286 (2014)
Weingarten R, Cho J, Conner JWC, Huber GW, Green Chem., 12, 1423 (2010)
Antal MJ, Leesomboon T, Mok WS, Richards GN, Carbohydr. Res., 217, 71 (1991)
Kim SB, Lee JH, Yang X, Lee J, Kim SW, Korean J. Chem. Eng., 32(11), 2280 (2015)
Lamminpaa K, Ahola J, Tanskanen J, Ind. Eng. Chem. Res., 51(18), 6297 (2012)
Garcia-Sancho C, Sadaba I, Moreno-Tost R, Merida-Robles J, Santamaria-Gonzalez J, Lopez-Granados and P. Maireles-Torres M, ChemSusChem, 6, 635 (2013)
Lima S, Antunes MM, Fernandes A, Pillinger M, Ribeiro MF, Valente AA, Appl. Catal. A: Gen., 388(1-2), 141 (2010)
Agirrezabal-Telleria I, Requies J, Guemez MB, Arias PL, Appl. Catal. B: Environ., 145, 34 (2014)
Crisci AJ, Tucker MH, Lee NY, Jang SG, Dumesic JA, Scott SL, ACS Catal., 1, 719 (2011)
Dias AS, Pillinger M, Valente AA, J. Catal., 229(2), 414 (2005)
Garcia-Sancho C, Agirrezabal-Telleria I, Guemez MB, Maireles-Torres P, Appl. Catal. B: Environ., 152-153, 1 (2014)
Agirrezabal-Telleria I, Larreategui A, Requies J, Guemez MB, Arias PL, Bioresour. Technol., 102(16), 7478 (2011)
Dias AS, Pillinger M, Valente AA, Appl. Catal. A: Gen., 285(1-2), 126 (2005)
Dias AS, Lima S, Carriazo D, Rives V, Pillinger M, Valente AA, J. Catal., 244(2), 230 (2006)
Agirrezabal-Telleria I, Hemmann F, Jager C, Arias PL, Kemnitz E, J. Catal., 305, 81 (2013)
Antunes MM, Lima S, Fernandes A, Candeias J, Pillinger M, Rocha SM, Ribeiro MF, Valente AA, Catal. Today, 195(1), 127 (2012)
Chareonlimkun A, Champreda V, Shotipruk A, Laosiripojana N, Fuel, 89(10), 2873 (2010)
Sadaba I, Lima S, Valente AA, Granados ML, Carbohydr. Res., 346, 2785 (2011)
Suzuki T, Yokoi T, Otomo R, Kondo JN, Tatsumi T, Appl. Catal. A: Gen., 408(1-2), 117 (2011)
You SJ, Kim YT, Park ED, React. Kinet. Mech. Catal., 111, 521 (2014)
Tanabe K, Holderich WF, Appl. Catal. A: Gen., 181(2), 399 (1999)
Hongsiri W, Danon B, de Jong W, Ind. Eng. Chem. Res., 53(13), 5455 (2014)
Ferreira LR, Lima S, Neves P, Antunes MM, Rocha SM, Pillinger M, Portugal I, Valente AA, Chem. Eng. J., 215-216, 772 (2013)
O'Neill R, Ahmad MN, Vanoye L, Aiouache F, Ind. Eng. Chem. Res., 48(9), 4300 (2009)
You SJ, Park N, Park ED, Park MJ, J. Ind. Eng. Chem., 21, 350 (2015)
Choudhary V, Sandler SI, Vlachos DG, ACS Catal., 2, 2022 (2012)
Choudhary V, Pinar AB, Sandler SI, Vlachos DG, Lobo RF, ACS Catal., 1, 1724 (2011)
Marcotullio G, De Jong W, Green Chem., 12, 1739 (2010)
Asghari FS, Yoshida H, Ind. Eng. Chem. Res., 45(7), 2163 (2006)
Weingarten R, Tompsett GA, Conner WC, Huber GW, J. Catal., 279(1), 174 (2011)
Dee SJ, Bell AT, ChemSusChem, 4, 1166 (2011)
van Putten RJ, van der Waal JC, de Jong E, Rasrendra CB, Heeres HJ, de Vries JG, Chem. Rev., 113(3), 1499 (2013)
Danon B, van der Aa L, de Jong W, Carbohydr. Res., 375, 145 (2013)
Lamminpaa K, Ahola J, Tanskanen J, RSC Adv., 4, 60243 (2014)
Kim S, Lee M, Park E, Lee S, Lee H, Park K, Park MJ, React. Kinet. Mech. Catal., 103, 267 (2011)
Williams DL, Dunlop AP, J. Ind. Eng. Chem., 40, 239 (1948)
Rose IC, Epstein N, Watkinson AP, Ind. Eng. Chem. Res., 39(3), 843 (2000)
Zeitsch KJ, The Chemistry and Technology of Furfural and its Many By-products, Elsevier Science, Amsterdam (2000).
Aida TM, Shiraishi N, Kubo M, Watanabe M, Smith RL, J. Supercrit. Fluids, 55(1), 208 (2010)
Wang S, Du Y, Zhang P, Cheng X, Qu Y, Korean J. Chem. Eng., 31(12), 2286 (2014)
Weingarten R, Cho J, Conner JWC, Huber GW, Green Chem., 12, 1423 (2010)
Antal MJ, Leesomboon T, Mok WS, Richards GN, Carbohydr. Res., 217, 71 (1991)
Kim SB, Lee JH, Yang X, Lee J, Kim SW, Korean J. Chem. Eng., 32(11), 2280 (2015)
Lamminpaa K, Ahola J, Tanskanen J, Ind. Eng. Chem. Res., 51(18), 6297 (2012)
Garcia-Sancho C, Sadaba I, Moreno-Tost R, Merida-Robles J, Santamaria-Gonzalez J, Lopez-Granados and P. Maireles-Torres M, ChemSusChem, 6, 635 (2013)
Lima S, Antunes MM, Fernandes A, Pillinger M, Ribeiro MF, Valente AA, Appl. Catal. A: Gen., 388(1-2), 141 (2010)
Agirrezabal-Telleria I, Requies J, Guemez MB, Arias PL, Appl. Catal. B: Environ., 145, 34 (2014)
Crisci AJ, Tucker MH, Lee NY, Jang SG, Dumesic JA, Scott SL, ACS Catal., 1, 719 (2011)
Dias AS, Pillinger M, Valente AA, J. Catal., 229(2), 414 (2005)
Garcia-Sancho C, Agirrezabal-Telleria I, Guemez MB, Maireles-Torres P, Appl. Catal. B: Environ., 152-153, 1 (2014)
Agirrezabal-Telleria I, Larreategui A, Requies J, Guemez MB, Arias PL, Bioresour. Technol., 102(16), 7478 (2011)
Dias AS, Pillinger M, Valente AA, Appl. Catal. A: Gen., 285(1-2), 126 (2005)
Dias AS, Lima S, Carriazo D, Rives V, Pillinger M, Valente AA, J. Catal., 244(2), 230 (2006)
Agirrezabal-Telleria I, Hemmann F, Jager C, Arias PL, Kemnitz E, J. Catal., 305, 81 (2013)
Antunes MM, Lima S, Fernandes A, Candeias J, Pillinger M, Rocha SM, Ribeiro MF, Valente AA, Catal. Today, 195(1), 127 (2012)
Chareonlimkun A, Champreda V, Shotipruk A, Laosiripojana N, Fuel, 89(10), 2873 (2010)
Sadaba I, Lima S, Valente AA, Granados ML, Carbohydr. Res., 346, 2785 (2011)
Suzuki T, Yokoi T, Otomo R, Kondo JN, Tatsumi T, Appl. Catal. A: Gen., 408(1-2), 117 (2011)
You SJ, Kim YT, Park ED, React. Kinet. Mech. Catal., 111, 521 (2014)
Tanabe K, Holderich WF, Appl. Catal. A: Gen., 181(2), 399 (1999)
Hongsiri W, Danon B, de Jong W, Ind. Eng. Chem. Res., 53(13), 5455 (2014)
Ferreira LR, Lima S, Neves P, Antunes MM, Rocha SM, Pillinger M, Portugal I, Valente AA, Chem. Eng. J., 215-216, 772 (2013)
O'Neill R, Ahmad MN, Vanoye L, Aiouache F, Ind. Eng. Chem. Res., 48(9), 4300 (2009)
You SJ, Park N, Park ED, Park MJ, J. Ind. Eng. Chem., 21, 350 (2015)
Choudhary V, Sandler SI, Vlachos DG, ACS Catal., 2, 2022 (2012)
Choudhary V, Pinar AB, Sandler SI, Vlachos DG, Lobo RF, ACS Catal., 1, 1724 (2011)
Marcotullio G, De Jong W, Green Chem., 12, 1739 (2010)
Asghari FS, Yoshida H, Ind. Eng. Chem. Res., 45(7), 2163 (2006)
Weingarten R, Tompsett GA, Conner WC, Huber GW, J. Catal., 279(1), 174 (2011)
Dee SJ, Bell AT, ChemSusChem, 4, 1166 (2011)
van Putten RJ, van der Waal JC, de Jong E, Rasrendra CB, Heeres HJ, de Vries JG, Chem. Rev., 113(3), 1499 (2013)
Danon B, van der Aa L, de Jong W, Carbohydr. Res., 375, 145 (2013)
Lamminpaa K, Ahola J, Tanskanen J, RSC Adv., 4, 60243 (2014)
Kim S, Lee M, Park E, Lee S, Lee H, Park K, Park MJ, React. Kinet. Mech. Catal., 103, 267 (2011)
Williams DL, Dunlop AP, J. Ind. Eng. Chem., 40, 239 (1948)
Rose IC, Epstein N, Watkinson AP, Ind. Eng. Chem. Res., 39(3), 843 (2000)
