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Received July 15, 2015
Accepted November 11, 2015
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Influence of phosphorous addition on Bi3Mo2Fe1 oxide catalysts for the oxidative dehydrogenation of 1-butene
Division of Physical Science and Engineering, KAUST Catalysis Center (KCC), King Abdullah University of Science and Technology (KAUST), 4700 KAUST, Thuwal 23955-6900, Saudi Arabia 1Department of Chemical Engineering, Chungbuk National University, Chungbuk 28644, Korea
chshin@chungbuk.ac.kr
Korean Journal of Chemical Engineering, March 2016, 33(3), 823-830(8), 10.1007/s11814-015-0239-z
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Abstract
Bi3Mo2Fe1Px oxide catalysts were prepared by a co-precipitation method and the influence of phosphorous content on the catalytic performance in the oxidative dehydrogenation of 1-butene was investigated. The addition of phosphorous up to 0.4mole ratio to Bi3Mo2Fe1 oxide catalyst led to an increase in the catalytic performance; however, a higher phosphorous content (above P=0.4) led to a decrease of conversion. Of the tested catalysts, Bi3Mo2Fe1P0.4 oxide catalyst exhibited the highest catalytic performance. Characterization results showed that the catalytic performance was related to the quantity of a π-allylic intermediate, facile desorption behavior of adsorbed intermediates and ability for re-oxidation of catalysts.
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References
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Christmann HF, US Patent, 3,270,080 (1966).
Briand LE, Hirt AM, Wachs IE, J. Catal., 202, 268 (2002)
Tian HJ, Wachs IE, Briand LE, J. Phys. Chem. B, 109(49), 23491 (2005)
Matsuura I, Schut R, Hirakawa K, J. Catal., 63, 152 (1980)
Sears WM, Keeler WJ, Appl. Spectrosc., 46, 1898 (1992)
Veniaminov SA, Barannik GB, React. Kinet. Catal. Lett., 13, 413 (1980)
Miura H, Morikawa Y, Shirasaki T, J. Catal., 39, 22 (1975)
Grasselli RK, Burrington JD, Buttrey DJ, DeSanto P, Lugmair CG, Volpe AF, Weingand T, Top. Catal., 23, 5 (2003)
Uda T, Lin TT, Keulks GW, J. Catal., 62, 26 (1980)
Woo SI, Kim JS, Jun HK, J. Phys. Chem. B, 108(26), 8941 (2004)
Voge HH, Adams CR, Adv. Catal., 17, 151 (1967)
Vasil'ev AN, Galich PN, Chem. Tech. Fuels Oils, 33(3), 185 (1997)
Golunski SE, Walker AP, J. Catal., 204(1), 209 (2001)
Portela MF, Top. Catal., 15, 241 (2001)
