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In relation to this article, we declare that there is no conflict of interest.
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Received June 19, 2015
Accepted December 11, 2015
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Novel ion-exchange nanocomposite membrane containing in-situ formed FeOOH nanoparticles: Synthesis, characterization and transport properties

School of Chemistry, College of Science, University of Tehran, Tehran, Iran 1Department of Chemistry, Faculty of Science, Arak University, Arak 38156-8-8349, Iran
Korean Journal of Chemical Engineering, April 2016, 33(4), 1380-1390(11), 10.1007/s11814-015-0275-8
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Abstract

A new type of cation-exchange nanocomposite membrane was prepared via in-situ formation of FeOOH nanoparticles in a blend containing sulfonated poly (2,6-dimethyl-1,4-phenylene oxide) and sulfonated polyvinylchloride by a simple one-step chemical method. Prepared nanocomposite membranes were characterized using Fourier transform infrared spectroscopy, scanning electron microscopy and X-ray diffraction. The SEM images showed uniform dispersion of FeOOH nanoparticles throughout the polymeric matrices. The effect of additive loading on physicochemical and electrochemical properties of prepared cation-exchange nanocomposite membranes was studied. Various characterizations showed that the incorporation of different amounts of FeOOH nanoparticles into the basic membrane structure had a significant influence on the membrane performance and could improve the electrochemical properties.

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