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Received August 26, 2015
Accepted November 17, 2015
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Removal of Cr(VI) from aqueous solution by rice husk derived magnetic sorbents
Faculty of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian 116034, China
Korean Journal of Chemical Engineering, April 2016, 33(4), 1416-1424(9), 10.1007/s11814-015-0248-y
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Abstract
A novel magnetic porous sorbent obtained from agricultural waste rice husk was successfully synthesized through a simple carbon-thermal method. The sorbent was characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, Fourier transform infrared spectroscopy, vibrating sample magnetometer, N2 sorption analysis, and X-ray photoelectron spectroscopy. The removal efficiency of the sorbent for Cr(VI) was also investigated. Chromium adsorption was fitted by the pseudo-second-order and Langmuir models. The maximum chromium adsorption capacity, Brunauer-Emmett-Teller surface area, and average Barrett-Joyner-Halenda pore size of the magnetic sorbent were 157.7mg·g-1, 134.1m2·g-1, and 4.99 nm, respectively. The saturated magnetization of the novel adsorbent was 77.8 emu·g.1, indicating that the material can facilitate separation and recovery from aqueous systems. The removal mechanisms of Cr(VI) were also discussed. The result illustrates that rice husk-derived magnetic carbonaceous materials are a potential adsorbent for Cr(VI) pollution treatment and provide a suitable method for the effective conversion of biomass waste, which may solve the problem of waste disposal and widen the applications of the materials.
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Gupta VK, Jain R, Nayak A, Agarwal S, Shrivastava M, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 31, 1062 (2011)
Gupta VK, Nayak A, Chem. Eng. J., 180, 81 (2012)
Saleh TA, Gupta VK, J. Colloid Interface Sci., 371, 101 (2012)
Khani H, Rofouei MK, Arab P, Gupta VK, Vafaei Z, J. Hazard. Mater., 183(1-3), 402 (2010)
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Gupta VK, Ali I, Saleh TA, Nayak A, Agarwal S, RSC Adv., 2, 6380 (2012)
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Mittal A, Mittal J, Malviya A, Gupta VK, J. Colloid Interface Sci., 344(2), 497 (2010)
Jain AK, Gupta VK, Bhatnagar A, Suhas, Sep. Sci. Technol., 38(2), 463 (2003)
Gupta VK, Ali I, Water Res., 35, 33 (2001)
Gupta VK, Sharma S, Yadav IS, Mohan D, J. Chem. Technol. Biotechnol., 71(2), 180 (1998)
Saleh TA, Agarwal S, Gupta VK, Appl. Catal. B: Environ., 106(1-2), 46 (2011)
Gupta VK, Kumar R, Nayak A, Saleh TA, Barakat MA, Adv. Colloid Interface Sci., 193-194, 24 (2013)
Gupta VK, Singh P, Rahman N, J. Colloid Interface Sci., 275(2), 398 (2004)
Gupta VK, Gupta B, Rastogi A, Agarwal S, Nayak A, Water Res., 45, 4047 (2011)
Gupta VK, Mittal A, Jhare D, Mittal J, RSC Adv., 2, 8381 (2012)
Gupta VK, Ali I, Saini VK, Van Gerven T, Van der Bruggen B, Vandecasteele C, Ind. Eng. Chem. Res., 44(10), 3655 (2005)
Wang LL, Guo YP, Zhu YC, Li Y, Qu YN, Rong CG, Ma XY, Wang ZC, Bioresour. Technol., 101(24), 9807 (2010)
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Guo YP, Qi JR, Yang SF, Yu KF, Wang ZC, Xu HD, Mater. Chem. Phys., 78, 132 (2002)
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Reddy DHK, Lee SM, Adv. Colloid Interface Sci., 201-202, 68 (2013)
Zhu XD, Liu YC, Zhou C, Luo G, Zhang SC, Chen JM, Carbon, 77, 627 (2014)
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Ndazi BS, Karlsson S, Tesha JV, Nyahumwa CW, Composites, 38, 925 (2007)
Chowdhury S, Mishra R, Saha P, Kushwaha P, Desalination, 265(1-3), 159 (2011)
Lin L, Zhai SR, Xiao ZY, Liu N, Song Y, Zhai B, An QD, Bioresour. Technol., 125, 172 (2012)
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Chen Y, Zhai SR, Liu N, Song Y, An QD, Song XW, Bioresour. Technol., 144, 401 (2013)
Ma JJ, Zhou LC, Dan WF, Zhang H, Shao YM, Bao C, Jing LY, J. Colloid Interface Sci., 446, 298 (2015)
Zhu HY, Fu YQ, Jiang R, Jiang JH, Xiao L, Zeng GM, Zhao SL, Wang Y, Chem. Eng. J., 173(2), 494 (2011)
Liu WF, Zhang J, Zhang CL, Ren L, Chem. Eng. J., 189-190, 295 (2012)
Zhuang LZ, Li QH, Chen JS, Ma BB, Chen SX, Chem. Eng. J., 253, 24 (2014)
Guo H, Zhang SF, Kou ZN, Zhai SR, Ma W, Yang Y, Carbohydr. Polym., 115, 177 (2015)
Qiu B, Wang YR, Sun DZ, Wang Q, Zhang X, Weeks BL, O’Connor R, Huang XH, Wei SY, Guo ZH, J. Mater. Chem. A, 3, 9817 (2015)
Anirudhan TS, Senan P, Sep. Sci. Technol., 46(9), 1430 (2011)
Liu ZG, Zhang FS, Bioresour. Technol., 101(7), 2562 (2010)
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Wang J, Yin X, Tang W, Ma H, Korean J. Chem. Eng., 32(9), 1889 (2015)
Hall KR, Eagleton LC, Acrivos A, Vermeulen T, Ind. Eng. Chem. Fundam., 5, 212 (1966)
Wu CL, Fan J, Jiang JH, Wang JJ, RSC Adv., 5, 47165 (2015)
Nethaji S, Sivasamy A, Mandal AB, Bioresour. Technol., 134, 94 (2013)
Sari A, Tuzen M, J. Hazard. Mater., 160(2-3), 349 (2008)
Zhang MM, Liu YG, Li TT, Xu WH, Zheng BH, Tan XF, Wang H, Guo YM, Guo FY, Wang SF, RSC Adv., 5, 46955 (2015)
Zhang LF, Xia W, Liu X, Zhang WQ, J. Mater. Chem. A, 3, 331 (2015)
