Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received August 2, 2015
Accepted December 16, 2015
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
A comparative study of the effects of CuO, NiO, ZrO2 and CeO2 coupling on the photocatalytic activity and characteristics of ZnO
Eluvathingal Devassy Sherly
John Judith Vijaya†
Lourdusamy John Kennedy1
Arunachalam Meenakshisundaram2
Melcureraj Lavanya2
Catalysis and Nanomaterials Research Laboratory, Department of Chemistry, Loyola College, Chennai 600 034, India 1Materials Division, School of Advanced Sciences, Vellore Institute of Technology (VIT) University, Chennai Campus, Chennai 600 127, India 2R&D Division, Chennai Petroleum Corporation Limited, Manali, Chennai 600 068, India
Korean Journal of Chemical Engineering, April 2016, 33(4), 1431-1440(10), 10.1007/s11814-015-0285-6
Download PDF
Abstract
ZnO nanoparticles were coupled with CuO, NiO, ZrO2 and CeO2 in 2 : 1 molar ratio by a microwave assisted one pot solution combustion synthesis. Structural, morphological and optical properties of ZnO and coupled oxides were investigated by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDX), UV-Vis diffuse reflectance spectroscopy (DRS), photoluminescence spectroscopy (PL), Fourier transform infrared (FTIR) spectroscopy and Brunauer-Emmett-Teller (BET) surface area analysis. XRD data revealed the presence of two phases in the coupled oxides. Photocatalytic activity of pure ZnO and ZnO coupled oxides was compared for the degradation of 2,4-dichlorophenol (2,4-DCP) under near UV light (365 nm) irradiation and the rate constant (k) values were calculated from the kinetic studies. The coupled oxide, Zn2Ce with ZnO and CeO2 in 2 : 1 molar ratio showed maximum degradation efficiency due to the efficient interparticle electron transfer between ZnO and CeO2.
Keywords
References
Evgenidou E, Fytianos K, Poulios I, Appl. Catal. B: Environ., 59(1-2), 81 (2005)
Hernandez JRT, Morales ER, Blanco LR, Enriquez JP, Oskam G, Delgado FP, Morales BE, Alejandro MA, Flores LLD, Hernandez GP, Mater. Sci. Semicond. Process, 37, 87 (2015)
Sakthivel S, Neppolian B, Shankar MV, Arabindoo B, Palanichamy M, Murugesan V, Sol. Energy Mater. Sol. Cells, 77(1), 65 (2003)
Sin JC, Lam SM, Lee KT, Mohamed AR, J. Colloid Interface Sci., 401, 40 (2013)
Ao Y, Xu J, Fu D, Yuan C, Microporous Mesoporous Mater., 122, 1 (2009)
Zhang H, Zong R, Zhao J, Zhu Y, Environ. Sci. Technol., 42, 3803 (2008)
Wang Q, Chen CC, Zhao D, Ma WH, Zhao JC, Langmuir, 24(14), 7338 (2008)
Tennakone K, Bandara J, Appl. Catal. A: Gen., 208(1-2), 335 (2001)
Wang C, Zhao JC, Wang XM, Mai BX, Sheng GY, Peng P, Fu JM, Appl. Catal. B: Environ., 39(3), 269 (2002)
Changlin YU, Kai Y, Qing S, Jimmy YU, Fangfang CAO, Xin L, Chin. J. Catal., 32, 555 (2011)
Wang J, Liu P, Fu X, Li Z, Han W, Wang X, Langmuir, 25, 1218 (2008)
Zhang X, Qin J, Xue Y, Yu P, Zhang B, Wang L, Liu R, Sci. Rep., 4, 4596 (2014)
Chen P, Xiao TY, Li HH, Yang JJ, Wang Z, Yao HB, Yu SH, ACS Nano, 6, 712 (2011)
Zhang N, Zhang YH, Yang MQ, Tang ZR, Xu YJ, J. Catal., 299, 210 (2013)
Sun JX, Yuan YP, Qiu LG, Jiang X, Xie AJ, Shen YH, Zhu JF, J. Chem. Soc.-Dalton Trans., 41, 6756 (2012)
Bai XJ, Wang L, Zong RL, Lv YH, Sun YQ, Zhu YF, Langmuir, 29(9), 3097 (2013)
Hossain MM, Ku BC, Hahn JR, Appl. Surf. Sci., DOI:10.1016/j.apsusc.2015.01.191. (2015)
Saravanan R, Karthikeyan S, Gupta VK, Sekaran G, Narayanan V, Stephen A, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 33, 91 (2013)
Gajendiran J, Rajendran V, Mater. Lett., 116, 311 (2014)
Sathishkumar P, Sweena R, Wu JJ, Anandan S, Chem. Eng. J., 171(1), 136 (2011)
Singh KA, Pathak LC, Roy SK, Ceram. Int., 33, 1463 (2007)
Li J, Pan YB, Qiu FG, Wu YS, Guo JK, Ceram. Int., 34, 141 (2008)
Purohit RD, Sharma BP, Pillai KT, Tyagi AK, Mater. Res. Bull., 36(15), 2711 (2001)
Jia J, Zhang S, Wang P, Wang H, J. Hazard. Mater., 205-206, 150 (2012)
Pera-Titus M, Garcia-Molina V, Banos MA, Gimenez J, Esplugas S, Appl. Catal. B: Environ., 47(4), 219 (2004)
Chaliha S, Bhattacharyya KG, J. Chem. Eng., 139, 575 (2008)
Ohtani B, J. Photochem. Photobiol. C, 11, 157 (2010)
Krishnakumar B, Imae T, Miras J, Esquena J, Sep. Purif. Technol., 132, 281 (2014)
Cullity BD, Elements of X-ray diffraction, Addison-Wesley, Reading, Mass, USA, 3rd Ed. (1967).
Saravanan R, Karthikeyan N, Gupta VK, Thirumal E, Thangadurai P, Narayanan V, Stephen A, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 33, 2235 (2013)
Ji P, Zhang J, Chen F, Anpo M, J. Phys. Chem. C, 112, 17809 (2008)
Liqiang J, Yichun Q, Baiqi W, Shudan L, Baojiang J, Libin Y, Wei F, Honggang F, Jiazhong S, Mater. Sol. Cells, 90, 1773 (2006)
Sakthivel S, Geissen SU, Bahnemanna DW, Murugesan V, Vogelpohl A, J. Photochem. Photobiol. A-Chem., 148, 283 (2002)
Chen SF, Zhang SJ, Liu W, Zhao W, J. Hazard. Mater., 155(1-2), 320 (2008)
Pozan GS, Isleyen M, Gokcen S, Appl. Catal. B: Environ., 140-141, 537 (2013)
Li C, Chen R, Zhang X, Shu S, Xiong J, Zheng Y, Dong W, Mater. Lett., 65, 1327 (2011)
Faisal M, Khan SB, Rahman MM, Jamal A, Akhtar K, Abdullah MM, J. Mater. Sci. Technol., 27, 594 (2011)
Taylor JH, Amberg CH, Can. J. Chem., 39, 535 (1961)
Fu M, Li YL, Wu SW, Lu P, Liu J, Dong F, Appl. Surf. Sci., 258(4), 1587 (2011)
Xu Y, Schoonen MAA, Am. Mineral., 85, 543 (2000)
Vinu R, Madras G, J. Indian Inst. Sci., 90, 189 (2010)
Bessekhouad Y, Robert D, Weber JV, Catal. Today, 101(3-4), 315 (2005)
Nishanthi ST, Iyyapushpam S, Sundarakannan B, Subramanian E, Padiyan DP, Appl. Surf. Sci., 313, 449 (2014)
Sherly ED, Vijaya JJ, Selvam NCS, Kennedy LJ, Ceram. Int., 40, 5681 (2014)
Lam SM, Sin JC, Abdullah AZ, Mohamed AR, Sep. Purif. Technol., 132, 378 (2014)
Hernandez JRT, Morales ER, Blanco LR, Enriquez JP, Oskam G, Delgado FP, Morales BE, Alejandro MA, Flores LLD, Hernandez GP, Mater. Sci. Semicond. Process, 37, 87 (2015)
Sakthivel S, Neppolian B, Shankar MV, Arabindoo B, Palanichamy M, Murugesan V, Sol. Energy Mater. Sol. Cells, 77(1), 65 (2003)
Sin JC, Lam SM, Lee KT, Mohamed AR, J. Colloid Interface Sci., 401, 40 (2013)
Ao Y, Xu J, Fu D, Yuan C, Microporous Mesoporous Mater., 122, 1 (2009)
Zhang H, Zong R, Zhao J, Zhu Y, Environ. Sci. Technol., 42, 3803 (2008)
Wang Q, Chen CC, Zhao D, Ma WH, Zhao JC, Langmuir, 24(14), 7338 (2008)
Tennakone K, Bandara J, Appl. Catal. A: Gen., 208(1-2), 335 (2001)
Wang C, Zhao JC, Wang XM, Mai BX, Sheng GY, Peng P, Fu JM, Appl. Catal. B: Environ., 39(3), 269 (2002)
Changlin YU, Kai Y, Qing S, Jimmy YU, Fangfang CAO, Xin L, Chin. J. Catal., 32, 555 (2011)
Wang J, Liu P, Fu X, Li Z, Han W, Wang X, Langmuir, 25, 1218 (2008)
Zhang X, Qin J, Xue Y, Yu P, Zhang B, Wang L, Liu R, Sci. Rep., 4, 4596 (2014)
Chen P, Xiao TY, Li HH, Yang JJ, Wang Z, Yao HB, Yu SH, ACS Nano, 6, 712 (2011)
Zhang N, Zhang YH, Yang MQ, Tang ZR, Xu YJ, J. Catal., 299, 210 (2013)
Sun JX, Yuan YP, Qiu LG, Jiang X, Xie AJ, Shen YH, Zhu JF, J. Chem. Soc.-Dalton Trans., 41, 6756 (2012)
Bai XJ, Wang L, Zong RL, Lv YH, Sun YQ, Zhu YF, Langmuir, 29(9), 3097 (2013)
Hossain MM, Ku BC, Hahn JR, Appl. Surf. Sci., DOI:10.1016/j.apsusc.2015.01.191. (2015)
Saravanan R, Karthikeyan S, Gupta VK, Sekaran G, Narayanan V, Stephen A, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 33, 91 (2013)
Gajendiran J, Rajendran V, Mater. Lett., 116, 311 (2014)
Sathishkumar P, Sweena R, Wu JJ, Anandan S, Chem. Eng. J., 171(1), 136 (2011)
Singh KA, Pathak LC, Roy SK, Ceram. Int., 33, 1463 (2007)
Li J, Pan YB, Qiu FG, Wu YS, Guo JK, Ceram. Int., 34, 141 (2008)
Purohit RD, Sharma BP, Pillai KT, Tyagi AK, Mater. Res. Bull., 36(15), 2711 (2001)
Jia J, Zhang S, Wang P, Wang H, J. Hazard. Mater., 205-206, 150 (2012)
Pera-Titus M, Garcia-Molina V, Banos MA, Gimenez J, Esplugas S, Appl. Catal. B: Environ., 47(4), 219 (2004)
Chaliha S, Bhattacharyya KG, J. Chem. Eng., 139, 575 (2008)
Ohtani B, J. Photochem. Photobiol. C, 11, 157 (2010)
Krishnakumar B, Imae T, Miras J, Esquena J, Sep. Purif. Technol., 132, 281 (2014)
Cullity BD, Elements of X-ray diffraction, Addison-Wesley, Reading, Mass, USA, 3rd Ed. (1967).
Saravanan R, Karthikeyan N, Gupta VK, Thirumal E, Thangadurai P, Narayanan V, Stephen A, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 33, 2235 (2013)
Ji P, Zhang J, Chen F, Anpo M, J. Phys. Chem. C, 112, 17809 (2008)
Liqiang J, Yichun Q, Baiqi W, Shudan L, Baojiang J, Libin Y, Wei F, Honggang F, Jiazhong S, Mater. Sol. Cells, 90, 1773 (2006)
Sakthivel S, Geissen SU, Bahnemanna DW, Murugesan V, Vogelpohl A, J. Photochem. Photobiol. A-Chem., 148, 283 (2002)
Chen SF, Zhang SJ, Liu W, Zhao W, J. Hazard. Mater., 155(1-2), 320 (2008)
Pozan GS, Isleyen M, Gokcen S, Appl. Catal. B: Environ., 140-141, 537 (2013)
Li C, Chen R, Zhang X, Shu S, Xiong J, Zheng Y, Dong W, Mater. Lett., 65, 1327 (2011)
Faisal M, Khan SB, Rahman MM, Jamal A, Akhtar K, Abdullah MM, J. Mater. Sci. Technol., 27, 594 (2011)
Taylor JH, Amberg CH, Can. J. Chem., 39, 535 (1961)
Fu M, Li YL, Wu SW, Lu P, Liu J, Dong F, Appl. Surf. Sci., 258(4), 1587 (2011)
Xu Y, Schoonen MAA, Am. Mineral., 85, 543 (2000)
Vinu R, Madras G, J. Indian Inst. Sci., 90, 189 (2010)
Bessekhouad Y, Robert D, Weber JV, Catal. Today, 101(3-4), 315 (2005)
Nishanthi ST, Iyyapushpam S, Sundarakannan B, Subramanian E, Padiyan DP, Appl. Surf. Sci., 313, 449 (2014)
Sherly ED, Vijaya JJ, Selvam NCS, Kennedy LJ, Ceram. Int., 40, 5681 (2014)
Lam SM, Sin JC, Abdullah AZ, Mohamed AR, Sep. Purif. Technol., 132, 378 (2014)
