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Received September 4, 2015
Accepted December 16, 2015
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Novel alkali borosilicate glasses: Preparation, structural investigation and thermal study
1University of Rennes 1, ISCR, UMR CNRS 6226 263 av. du Général Leclerc, 35042 Rennes, France 2Faculty of Sciences of Sfax, Materials Science and Environment Laboratory, Sfax 3018, Tunisia 3, France
hassane.oudadesse@univ-rennes1.fr
Korean Journal of Chemical Engineering, April 2016, 33(4), 1456-1461(6), 10.1007/s11814-015-0287-4
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Abstract
Bioactive glasses are indicated for use as bone substitutes in orthopedic or dental surgery because of their high reactivity once in contact with the biological medium. Boron is known as a glass network former and an activator of the glasses bioactivity. In this work, bioactive glass was doped by 5, 10 and 20 wt% of B2O3 according to the melting process. Adding boron oxide with high content enhances glass materials’ bioactivity. Likewise, thanks to their solubility, borate-containing bioactive glasses were fluently used as orthopedic implants. The aim of our study was to investigate of boron effect on the thermal characteristics of our bioactive glass to better understand their proprieties in order for use as bone biomaterial. The obtained results proved that the more the boron content in the glass network increases, the more the melting temperature decreases and the more the thermal stability increases.
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Gadet MD, Nzietchueng RM, Hess K, Nabet P, Belleville F, Dousset B, Biol. Trace Elem. Res., 85, 23 (2002)
Hakki SS, Bozkurt BS, Hakki EE, J. Trace Elem. Med. Bio., 24, 243 (2010)
Torres FJ, Alarcon J, J. Non-Cryst. Solids, 34, 45 (2004)
Lee JH, Lee CK, Chang BS, Ryu HS, Seo JH, Hong KS, Kim H, J. Biomed. Mater. Res., 77, 352 (2006)
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Agathopoulos S, Tulyaganov DU, Ventura JMG, Kannan S, Saranti A, Karakassides MA, Ferreira JMF, J. Non-Cryst. Solids, 352, 322 (2006)
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Jastrzebski W, Sitarz M, Rokita M, Bulat K, Spectroc. Acta, 79, 722 (2011)
Kamitsos EI, Patsis AP, Karakassides MA, Chryssikos GD, J. Non-Cryst. Solids, 126, 52 (1990)
Sitarz M, J. Non-Cryst. Solids, 357, 1603 (2011)
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Zhong J, Bray PJ, J. Non-Cryst. Solids, 87, 226 (1986)
Barton J, Guillemet G, Le verre: science et technologie, Les Ulis: EDP Sciences (2004).
Flower GL, Reddy MS, Reddy MVR, Veeraiah N, A: Phys. Sci., 62, 315 (2014)
Furukawa T, White WB, J. Am. Ceram. Soc., 64, 443 (1981)
Richet P, Atake T, Yamashita I, J. Non-Cryst. Solids, 352, 3854 (2006)
Azooz MA, AbouAiad THM, Batal FHE, Tabii GE, Indian. J. Pure. Ap. Phy., 46, 880 (2008)
Bray PJ, Proceedings of the second international Conference on Borate Glasses, Crystals and Melts 1-20 (1997).
Shelby JE, Royal Society of Chemistry, 91, 108 (1997)
Rao KJ, Structural Chemistry of Glasses, 1st Ed., Elsevier Science, Amsterdam (2002).
Reddy MS, Raju GN, Nagarjuna G, Veeraiah N, J. Alloy. Compd., 438, 41 (2007)
Krogh-Moe J, Phys. Chem. Glasses-B, 6, 46 (1965)
Asai K, Yokokawa T, Trans. JIM, 9, 571 (1982)
Lee SK, Stebbins JF, Geochim. Cosmochim. Acta, 66, 303 (2002)
Miyoshi H, Chen D, Masuia H, Yazawa T, Akai T, J. Non-Cryst. Solids, 345-346, 99 (2004)
Grandjean A, Malki M, Simonnet C, J. Non-Cryst. Solids, 352, 2731 (2006)
Bardez I, These. Universite Pierre et Marie Curie, Paris IV. Serial number D-11, 71-77 (2004).
Souquet JL, Duclot M, Levy M, Solid State Ion., 105(1-4), 237 (1998)
