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Received June 25, 2015
Accepted November 17, 2015
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Pt and Pt-Sn nanoparticles decorated conductive polymer-biowaste ash composite for direct methanol fuel cell
Nanotech Research Lab, Department of Chemistry, University College of Engineering Villupuram(A Constituent College of Anna University, Chennai), Kakuppam, Villupuram, 605 103, Tamilnadu, India
Korean Journal of Chemical Engineering, April 2016, 33(4), 1489-1499(11), 10.1007/s11814-015-0245-1
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Abstract
The present work is focused on the synthesis of platinum (Pt)and platinum-tin (Pt-Sn) nanoparticles decorated poly(aniline)-rice husk ash (PANI-RHA) composite by the chemical reduction of their respective metal salts. The obtained Pt/PANI-RHA and Pt-Sn/PANI-RHA composites were characterized by FT-IR, XRD, SEM, EDAX and HRTEM analysis. Platinum nanoparticles were also decorated on RHA and PANI for comparative studies. The synthesized electrocatalysts have been subjected to electrooxidation of methanol by cyclic voltammetry. It has been concluded that the Pt nanoparticles decorated PANI-RHA composite exhibits a remarkable enhancement for the electrochemical oxidation of methanol when compared with Pt/PANI and Pt/RHA composites. So, PANI-RHA composite has proven to be a good supporting material for alcohol fuel cell applications. Further, Pt-Sn bimetallic nanoparticles decorated PANI-RHA composite exhibit a remarkable enhancement for the electrochemical oxidation of methanol compared to that of Pt/PANI-RHA catalyst. Hence, the above results suggest that Pt-Sn/PANI-RHA composite is a potent and low cost electrocatalyst for fuel cell industries.
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Song HQ, Xiao P, Qiu XP, Zhu WT, J. Power Sources, 195(6), 1610 (2010)
Zhao YC, Wang FY, Tian JN, Yang XL, Zhan L, Electrochim. Acta, 55(28), 8998 (2010)
Selvaraj V, Alagar M, Hamerton I, J. Power Sources, 160(2), 940 (2006)
Selvaraj V, Alagar M, Electrochem. Commun., 9, 1145 (2007)
Hassan HB, J. Fuel Chem. Technol., 37, 346 (2009)
Hsieh CT, Lin JY, J. Power Sources, 188(2), 347 (2009)
Rahsepar M, Pakshir M, Piao Y, Kim H, Electrochim. Acta, 71, 246 (2012)
Long NV, Hien TD, Asaka T, Ohtaki M, Nogami M, Int. J. Hydrog. Energy, 36(14), 8478 (2011)
Vilian ATE, Chen SM, Piraman S, New J. Chem., DOI:10.1039/C4NJ01470G. (2015)
Yuan J, He B, Hong L, Lu J, Miao J, Niu L, J. Mater. Chem., 22, 19658 (2012)
Ren F, Wang C, Zha C, Jiang F, Yue R, Du Y, Yang P, Xu J, J. Mater. Chem. A, 1, 7255 (2013)
KokPoh C, Tian Z, Gao J, Liu Z, Lin J, Feng YP, Su F, J. Mater. Chem., 22, 13643 (2012)
Tsiouvaras N, Martinez-Huerta MV, Paschos O, Stimming U, Fierro JLG, Pena MA, Int. J. Hydrog. Energy, 35(20), 11478 (2010)
Zhang X, Zhang F, Guan RF, Chan KY, Mater. Res. Bull., 42(2), 327 (2007)
Hogarth MP, Ralph TR, Met. Rev., 46, 146 (2002)
Uchida M, Aoyama Y, Tanabe M, Yanagihara N, Eda N, Ohta A, J. Electrochem. Soc., 142(8), 2572 (1995)
Wu G, Chen YS, Xu BQ, Electrochem. Commun., 7, 1237 (2005)
Adam F, Retnam P, Iqbal A, Appl. Catal. A: Gen., 357(1), 93 (2009)
Adam F, Fook CL, J. Porous Mat., 16, 291 (2009)
Adam F, Kandasamy K, Balakrishnan S, J. Colloid Interface Sci., 304(1), 137 (2006)
Adam F, Ahmed AE, Chem. Eng. J., 145(2), 328 (2008)
Friend RH, Gymer RW, Holmes AB, Burroughes JH, Marks RN, Taliani C, Bradley DDC, Dos Santos DA, Bredas JL, Logdlund M, Salaneck WR, Nature, 397(6715), 121 (1999)
Muller CD, Falcou A, Reckefuss N, Rojahn M, Wiederhirn V, Rudati P, Frohne H, Nuyken O, Becher H, Meerholz K, Nature, 421, 829 (2003)
Sirringhaus H, Tessler N, Friend RH, Science, 280(5370), 1741 (1998)
Dimitrakopoulos CD, Mascaro DJ, J. Res. De., 45, 11 (2001)
Yu G, Gao J, Hummelen JC, Wudl F, Heeger AJ, Science, 270(5243), 1789 (1995)
Brabec CJ, Sariciftci NS, Hummelen JC, Adv. Funct. Mater., 11(1), 15 (2001)
Malkaj P, Dalas E, Vitoratos E, Sakkopoulos S, J. Appl. Polym. Sci., 101(3), 1853 (2006)
Luo YC, Do JS, Sens. Actuators B-Chem., 115, 102 (2009)
MacDiarmid AG, Mu SL, Somasiri NLD, Wu W, Mol. Cryst. Liq. Cryst., 121, 173 (1985)
Koboyashi T, Yoneyama H, Tamura H, J. Electroanal. Chem., 177, 281 (1984)
Sazou D, Kosseoglou D, Electrochim. Acta, 51(12), 2503 (2006)
Habibi B, Pournaghi-Azar MH, Abdolmohammad-Zadeh H, Razmi H, Int. J. Hydrog. Energy, 34(7), 2880 (2009)
Arbizzani C, Biso M, Manferrari E, Mastragostino M, J. Power Sources, 178(2), 584 (2008)
Patra S, Munichandraiah N, Langmuir, 25(3), 1732 (2009)
Tintula KK, Pitchumani S, Sridhar P, Shukla AK, J. Chem. Sci., 122, 381 (2010)
Yano J, Shiraga T, Kitani A, J. New Mater. Electrochem. Syst., 11, 235 (2008)
Imyim A, Prapalimrungsi E, J. Hazard. Mater., 184(1-3), 775 (2010)
Ghorbani M, Eisazadeh H, Compos. Pt. B-Eng., 45, 1 (2013)
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Li WZ, Zhou WJ, Li HQ, Zhou ZH, Zhou B, Sun GQ, Xin Q, Electrochim. Acta, 49(7), 1045 (2004)
He CZ, Kunz HR, Fenton JM, J. Electrochem. Soc., 144(3), 970 (1997)
Colmati F, Antolini E, Gonzalez ER, Electrochim. Acta, 50(28), 5496 (2005)
Zhou WJ, Zhou ZH, Song SQ, Li WZ, Sun GQ, Tsiakaras P, Xin Q, Appl. Catal. B: Environ., 46(2), 273 (2003)
Ensafi AA, Jafari-Asl M, Rezaei B, Electrochim. Acta, 130, 397 (2014)
Cao HZ, Fan ZT, Hou GY, Tang YP, Zheng GQ, Electrochim. Acta, 125, 275 (2014)
Pant HC, Patra MK, Negi SC, Bhatia A, Vadera SR, Kumar N, Bull. Mat. Sci., 29, 379 (2006)
Razak SIA, Ahmad AL, Zein SHS, Boccaccini AR, Scr. Mater., 61, 592 (2009)
Wu YM, Li WS, Lu J, Du JH, Lu DS, Fu JM, J. Power Sources, 145(2), 286 (2005)
Mascaro LH, Santos MC, Machado SAS, Avac LA, J. Braz. Chem. Soc., 13, 529 (2002)
Wang JS, Shi RR, Guo X, Xi JY, Zhao JH, Song CY, Wang LC, Zhang JJ, Electrochim. Acta, 123, 309 (2014)
Seruga M, Metikoshukovic M, Valla T, Milun M, Hoffschultz H, Wandelt K, J. Electroanal. Chem., 407(1-2), 83 (1996)
Yu XW, Pickup PG, J. Power Sources, 182(1), 124 (2008)
Colmati F, Antolini E, Gonzalez ER, Electrochim. Acta, 50, 549 (2005)
Han F, Wang X, Lian J, Wang Y, Carbon, 50, 5498 (2012)
Yang X, Yang Q, Xu J, Lee CS, J. Mater. Chem., 22, 8057 (2012)
Tu DD, Wu B, Wang BX, Deng C, Gao Y, Appl. Catal. B: Environ., 103(1-2), 163 (2011)
Lee YW, Ko AR, Han SB, Kim HS, Park KW, Phys. Chem. Chem. Phys., 13, 5569 (2011)
Vilian ATE, Chen SM, Piraman S, New J. Chem., 39, 953 (2015)
Watanabe M, Motoo S, J. Electroanal. Chem., 60, 275 (1975)
