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Received July 14, 2015
Accepted February 22, 2016
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Metal hollow sphere electrocatalysts
1Graduate School of Energy & Environment, Seoul National University of Science and Technology, Seoul 08826, Korea 2Department of Chemistry, Birla Institute of Technology, Mesra, Deoghar off-campus, Deoghar - 814 142, Jharkhand, India 3Department of Chemistry, Surendra Institute of Engineering and Management,, Dhukuria, Siliguri - 734 009, Darjeeling, West Bengal, India 4, Korea 5Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, India
Korean Journal of Chemical Engineering, May 2016, 33(5), 1514-1529(16), 10.1007/s11814-016-0056-z
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Abstract
Metal micro-/nano hollow spheres have been widely applied in numerous fields during the last decade. This review will only focus on the synthetic strategies to synthesize hollow spherical structures in the enhancement of their electrocatalytic activity, especially the metal hollow spherical materials. We present a comprehensive overview of synthetic strategies for metal hollow spherical structures which have been approached specifically in electrochemical reactions. These synthetic methods are mainly categorized as hard templates, soft templates, sacrificial templates and without templates. The review further includes electrocatalytic approaches of hollow spherical metals in different electrochemical processes, especially the methanol electro-oxidation reaction for methanol fuel cell application and hydrogen and oxygen evolution reactions in water electrolyzer, as metal hollow spherical materials are especially applied in these specific reactions.
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References
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