Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received September 28, 2015
Accepted December 4, 2015
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
V-promoted Ni/Al2O3 catalyst for synthetic natural gas (SNG) production:Catalyst preparation methodologies
State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China 1Institute of Chemical Engineering and Sciences, A*star, 1 Pesek Road, Jurong Island 627833, Singapore
fbsu@ipe.ac.cn
Korean Journal of Chemical Engineering, May 2016, 33(5), 1599-1605(7), 10.1007/s11814-015-0270-0
Download PDF
Abstract
The effect of preparation method on the catalytic performance of V-promoted Ni/Al2O3 catalysts for synthetic natural gas (SNG) production via CO methanation has been investigated. The Ni-V/Al2O3 catalysts were prepared by co-impregnation (CI) method, deposition precipitation (DP) method as well as two sequential impregnation (SI) methods with different impregnation sequence. Among the prepared catalysts, the one prepared by CI method exhibited the best catalytic performance due to its largest H2 uptake and highest metallic Ni dispersion. In a 91h-lifetime test, this catalyst showed high stability at high temperature and weight hourly space velocity. This work demonstrates that the catalytic performance of the V-promoted Ni/Al2O3 catalysts can be improved by carefully controlling the preparation method/conditions.
Keywords
References
Kopyscinski J, Schildhauer TJ, Biollaz SMA, Fuel, 89(8), 1763 (2010)
Liu Q, Gao JJ, Zhang MJ, Li HF, Gu FN, Xu GW, Zhong ZY, Su FB, RSC Adv., 4, 16094 (2014)
Liu Q, Gu FN, Gao JJ, Li HF, Xu GW, Su FB, J. Energy Chem., 23, 761 (2014)
Gao JJ, Liu Q, Gu FN, Liu B, Zhong ZY, Su FB, RSC Adv., 5, 22759 (2015)
Lee YH, Kim H, Choi HS, Lee DW, Lee KY, Korean J. Chem. Eng., 32(11), 2220 (2015)
Gao JJ, Jia CM, Li J, Gu FN, Xu GW, Zhong ZY, Su FB, Ind. Eng. Chem. Res., 51(31), 10345 (2012)
Jia CM, Gao JJ, Li J, Gu FN, Xu GW, Zhong ZY, Su FB, Catal. Sci. Technol., 3, 490 (2013)
Gao JJ, Jia CM, Li J, Zhang MJ, Gu FN, Xu GW, Zhong ZY, Su FB, J. Energy Chem., 22, 919 (2013)
Zhao AM, Ying WY, Zhang HT, Ma HF, Fang DY, Catal. Commun., 17, 34 (2012)
Yan XL, Liu Y, Zhao BR, Wang Z, Wang Y, Liu CJ, Int. J. Hydrog. Energy, 38(5), 2283 (2013)
Liu Q, Gu FN, Lu XP, Liu YJ, Li HF, Zhong ZY, Xu GW, Su FB, Appl. Catal. A: Gen., 488, 37 (2014)
Lu XP, Gu FN, Liu Q, Gao JJ, Liu YJ, Li HF, Jia LH, Xu GW, Zhong ZY, Su FB, Fuel Process. Technol., 135, 34 (2015)
Liu Q, Gao JJ, Gu FN, Lu XP, Liu YJ, Li HF, Zhong ZY, Liu B, Xu GW, Su FB, J. Catal., 326, 127 (2015)
Kip BJ, Smeets PAT, Vangrondelle J, Prins R, Appl. Catal., 33, 181 (1987)
Liu J, Li CM, Wang F, He S, Chen H, Zhao YF, Wei M, Evans DG, Duan X, Catal. Sci. Technol., 3, 2627 (2013)
Velu S, Gangwal SK, Solid State Ion., 177(7-8), 803 (2006)
Sehested J, Dahl S, Jacobsen J, Rostrup-Nielsen JR, J. Phys. Chem. B, 109(6), 2432 (2005)
Stockwell DM, Chung JS, Bennett CO, J. Catal., 112, 135 (1988)
Tanksale A, Beltramini JN, Dumesic JA, Lu GQ, J. Catal., 258(2), 366 (2008)
Gao JJ, Wang YL, Ping Y, Hu DC, Xu GW, Gu FN, Su FB, RSC Adv., 2, 2358 (2012)
Kang WR, Lee KB, Korean J. Chem. Eng., 30(7), 1386 (2013)
Liu Q, Gao JJ, Zhang MJ, Li HF, Gu FN, Xu GW, Zhong ZY, Su FB, RSC Adv., 4, 16094 (2014)
Liu Q, Gu FN, Gao JJ, Li HF, Xu GW, Su FB, J. Energy Chem., 23, 761 (2014)
Gao JJ, Liu Q, Gu FN, Liu B, Zhong ZY, Su FB, RSC Adv., 5, 22759 (2015)
Lee YH, Kim H, Choi HS, Lee DW, Lee KY, Korean J. Chem. Eng., 32(11), 2220 (2015)
Gao JJ, Jia CM, Li J, Gu FN, Xu GW, Zhong ZY, Su FB, Ind. Eng. Chem. Res., 51(31), 10345 (2012)
Jia CM, Gao JJ, Li J, Gu FN, Xu GW, Zhong ZY, Su FB, Catal. Sci. Technol., 3, 490 (2013)
Gao JJ, Jia CM, Li J, Zhang MJ, Gu FN, Xu GW, Zhong ZY, Su FB, J. Energy Chem., 22, 919 (2013)
Zhao AM, Ying WY, Zhang HT, Ma HF, Fang DY, Catal. Commun., 17, 34 (2012)
Yan XL, Liu Y, Zhao BR, Wang Z, Wang Y, Liu CJ, Int. J. Hydrog. Energy, 38(5), 2283 (2013)
Liu Q, Gu FN, Lu XP, Liu YJ, Li HF, Zhong ZY, Xu GW, Su FB, Appl. Catal. A: Gen., 488, 37 (2014)
Lu XP, Gu FN, Liu Q, Gao JJ, Liu YJ, Li HF, Jia LH, Xu GW, Zhong ZY, Su FB, Fuel Process. Technol., 135, 34 (2015)
Liu Q, Gao JJ, Gu FN, Lu XP, Liu YJ, Li HF, Zhong ZY, Liu B, Xu GW, Su FB, J. Catal., 326, 127 (2015)
Kip BJ, Smeets PAT, Vangrondelle J, Prins R, Appl. Catal., 33, 181 (1987)
Liu J, Li CM, Wang F, He S, Chen H, Zhao YF, Wei M, Evans DG, Duan X, Catal. Sci. Technol., 3, 2627 (2013)
Velu S, Gangwal SK, Solid State Ion., 177(7-8), 803 (2006)
Sehested J, Dahl S, Jacobsen J, Rostrup-Nielsen JR, J. Phys. Chem. B, 109(6), 2432 (2005)
Stockwell DM, Chung JS, Bennett CO, J. Catal., 112, 135 (1988)
Tanksale A, Beltramini JN, Dumesic JA, Lu GQ, J. Catal., 258(2), 366 (2008)
Gao JJ, Wang YL, Ping Y, Hu DC, Xu GW, Gu FN, Su FB, RSC Adv., 2, 2358 (2012)
Kang WR, Lee KB, Korean J. Chem. Eng., 30(7), 1386 (2013)
