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Received July 5, 2015
Accepted December 30, 2015
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Kinetic, thermodynamic and equilibrium studies on the removal of copper ions from aqueous solutions by natural and modified clinoptilolites
Department of Mining and Metallurgical Engineering, Amirkabir University of Technology, Tehran, Iran
iranajad@aut.ac.ir
Korean Journal of Chemical Engineering, May 2016, 33(5), 1629-1639(11), 10.1007/s11814-015-0299-0
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Abstract
This paper presents the adsorption of Cu(II) ions from aqueous solution on Na and Fe-modified clinoptilolite. The copper adsorption experiments were performed in a batch system considering an optimum contact time of 24 h. Changes in the surfaces and structure were characterized by SEM data. According to the SEM results, it was anticipated that the removal efficiency of Fe-modified clinoptilolite was the highest compared with the natural and Namodified clinoptilolites. Adsorption of Cu(II) ions by modified clinoptilolites was investigated as a function of the initial Cu(II) concentration, solution pH, and temperature. According to the results, the maximum adsorbed Cu amount onto Fe-modified was 19.40mg/l at the optimum operating condition with a pH value of 5.5 and temperature of 60 ℃. According to the thermodynamic evaluations, positive ΔS and negative ΔG were found for the adsorption process showing that the adsorption reaction is a spontaneous process and more favorable at high temperatures. Sorption data have been interpreted in terms of Langmuir and Freundlich, Temkin and Dubinin-Radushkevich. The adsorption equilibrium was best described by the Langmuir adsorption isotherm. In addition, according to the Sips model, the sorption of Cu(II) ions on the Fe-modified clinoptilolite was found to be heterogeneous. The kinetic study showed that the Fe-modified clinoptilolite followed the pseudo-second order model. The results indicated that the clinoptilolite-rich tuff in its iron oxide form could be efficiently used for the removal of copper from aqueous solutions.
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Abdulkareem SA, Muzenda E, Afolabi AS, Kabuba J, Arabian J. Sci. Eng., 38, 2263 (2013)
Dimirkou A, Water Res., 41, 2763 (2007)
Doula MK, Dimirkou A, J. Hazard. Mater., 151(2-3), 738 (2008)
Dimirkou A, Ioannou A, Doula M, Adv. Colloid Interface Sci., 97, 37 (2002)
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Eren E, J. Hazard. Mater., 165(1-3), 63 (2009)
Maria DK, Water Res., 40, 3167 (2006)
Doula MK, Chemosphere, 67, 731 (2007)
Dimirkou A, Doula MK, Desalination, 224(1-3), 280 (2008)
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Doula MK, Water Res., 43, 3659 (2009)
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Lihareva N, Dimova L, Petrov O, Tzvetanova Y, Microporous Mesoporous Mater., 130, 32 (2010)
Yuh-Shan H, Scientometrics, 59, 171 (2004)
Kocaoba S, Orhan Y, Akyuz T, Desalination, 214(1-3), 1 (2007)
Hui KS, Chao CYH, Kot SC, J. Hazard. Mater., 127(1-3), 89 (2005)
Sprynskyy M, Buszewski B, Terzyk AP, Namiesnik J, J. Colloid Interface Sci., 304(1), 21 (2006)
Inglezakis VJ, Loizidou MD, Grigoropoulou HP, J. Colloid Interface Sci., 261(1), 49 (2003)
Alvarez-Ayuso E, Garcia-Sanchez A, Querol X, Water Res., 37, 4855 (2003)
Oren AH, Kaya A, J. Hazard. Mater., 131(1-3), 59 (2006)
Moreno N, Querol X, Ayora C, Environ. Sci. Technol., 35, 3526 (2001)
Gedik K, Imamoglu I, J. Hazard. Mater., 155(1-2), 385 (2008)
Kocaoba S, Orhan Y, Akyuz T, Desalination, 214(1-3), 1 (2007)
Doula MK, Water Res., 40, 3167 (2006)
Ouki SK, Kavannagh M, Waste Manage. Res., 15, 383 (1997)
Eisenman G, Biophysical J., 2, 259 (1962)
Wingenfelder U, Nowack B, Furrer G, Schulin R, Water Res., 39, 3287 (2005)
Curkovic L, Cerjan-Stefanovic S, Filipan T, Water Res., 31, 1379 (1997)
Inglezakis VJ, Hadjiandreou KJ, Loizidou MD, Grigoropoulou HP, Water Res., 35, 2161 (2001)
CerjanStefanovic S, Curkovic L, Filipan T, Croat. Chem. Acta, 281 (1996)
Langmuir I, J. Am. Chem. Soc., 40, 1361 (1918)
Freundlich H, Z. Phys. Chem., 57, 385 (1906)
Frimmel FH, Huber L, Environ. Int., 22, 507 (1996)
McKay G, Otterburn MS, Sweeney AG, Water Res., 14, 21 (1980)
Gutierrez-Segura E, Solache-Rios M, Colin-Cruz A, Fall C, J. Environ. Manage., 97, 6 (2012)
Tempkin MI, Pyzhev V, Acta Phys. Chim., 12, 327 (1940)
Dada A, Olalekan A, Olatunya A, Dada O, J. Appl. Chem., 3, 38 (2012)
Gunay A, Arslankaya E, Tosun I, J. Hazard. Mater., 146(1-2), 362 (2007)
Dabrowski A, Adv. Colloid Interface Sci., 93, 135 (2001)
Peric J,Trgo M, Medvidovic NV, Water Res., 38, 1893 (2004)
Rouquerol J, Rouquerol F, Llewellyn P, Maurin G, Sing KS, Adsorption by powders and porous solids: principles, methodology and applications, Academic Press (2013).
Dubinin MM, Chem. Rev., 60, 235 (1960)
Hobson JP, J. Phys. Chem., 73, 2720 (1969)
Pavan FA, Dias SLP, Lima EC, Benvenutti EV, Dyes Pigment., 76, 64 (2008)
Vimonses V, Lei SM, Jin B, Chowd CWK, Saint C, Chem. Eng. J., 148(2-3), 354 (2009)
Georgiev D, Bogdanov B, Hristov Y, Markovska I, World Academy of Sci., Eng. Technol., 6, 1098 (2012)
Han RP, Zou WH, Zhang ZP, Shi J, Yang JJ, J. Hazard. Mater., 137(1), 384 (2006)
Wong KK, Lee CK, Low KS, Haron MJ, Process Biochem., 39(4), 437 (2003)
Acar FN, Eren Z, J. Hazard. Mater., 137(2), 909 (2006)
Sciban M, Klasnja M, Skrbic B, Wood Sci. Technol., 40, 217 (2006)
Shukla SR, Pai RS, Sep. Purif. Technol., 43(1), 1 (2005)
Li Q, Zhai JP, Zhang WY, Wang MM, Zhou J, J. Hazard. Mater., 141(1), 163 (2007)
Horsfall M, Abia AA, Spiff AI, Bioresour. Technol., 97(2), 283 (2006)
Shukla SR, Pai RS, Bioresour. Technol., 96(13), 1430 (2005)
Chubar N, Carvalho JR, Correia MJN, Colloids Surf. A: Physicochem. Eng. Asp., 238, 51 (2004)
Nasernejad B, Zadeh TE, Pour BB, Bygi ME, Zamani A, Process Biochem., 40(3-4), 1319 (2005)
Pehlivan E, Cetin S, Yanik BH, J. Hazard. Mater., 135(1-3), 193 (2006)
Wankasi D, Jnr MH, Spiff AI, Electronic. J. Biotechnol., 9, 587 (2006)
Namasivayam C, Kadirvelu K, Chemosphere, 34, 377 (1997)
