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Received November 22, 2015
Accepted January 11, 2016
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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CeO2-La2O3/ZSM-5 sorbents for high-temperature H2S removal
College of Mechanical Engineering, Tongji University, China 1School of Energy and Mechanical Engineering, Shanghai University of Electric Power, Shanghai 200090, China
wujiang207@163.com
Korean Journal of Chemical Engineering, June 2016, 33(6), 1837-1845(9), 10.1007/s11814-016-0013-x
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Abstract
Performance of CeO2-La2O3/ZSM-5 sorbents for sulfur removal was examined at temperature ranging from 500 ℃ to 700 ℃. The sulfur capacity of 5Ce5La/ZSM-5 was much bigger than that of CeO2/ZSM-5. H2 had a negative impact on the sulfidation; however, CO had little influence on sulfur removal. The characterization results showed that CeO2 and La2O3 were well dispersed on ZSM-5 because of the intimate admixing of La2O3 and CeO2, the major sulfidation products were Ce2O2S and La2O2S, the XRD and SEM results revealed that ZSM-5 structure could remain intact during preparation and sulfidation process, the H2-TPR showed that the reducibility of CeO2 can be remarkably enhanced by addition of La.
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References
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Chang LP, Zhang ZY, Ren XR, Li F, Xie KC, Energy Fuels, 23(1), 762 (2009)
