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Received December 4, 2015
Accepted February 4, 2016
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Crystallization kinetics for carbon dioxide gas hydrate in fixed bed and stirred tank reactor

Chemical Engineering and Process Development Division, National Chemical Laboratory, Pune, India 1Department of Chemical Engineering, Indian Institute of Technology-BHU, Varanasi 221005, India 2Offshore Plant Resources R&D Center, Korea Institute of Industrial Technology, 1274 Jisa-dong, Gangseo-gu, Busan 618-230, Korea
k.rajnish@ncl.res.in
Korean Journal of Chemical Engineering, June 2016, 33(6), 1922-1930(9), 10.1007/s11814-016-0040-7
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Abstract

The phase change from germ nuclei to growth nuclei and subsequent volume transformation in a crystallization process was modeled by Avrami equations. The phase change during the hydrate formation was fitted with the classical Avrami model by utilizing gas uptake data. The idea is to understand the difference in growth behavior of hydrate crystals when in small pores compared to a stirred tank reactor which does not pose any physical restrictions to hydrate growth. The parameters n and k of the Avrami equation were determined explicitly for CO2 hydrate formation.

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