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Received July 29, 2015
Accepted February 5, 2016
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Electrochemical study of Magnetite-CH composite carbon paste modified electrode
Kings College of Engineering, Punalkulam 613303, India 1Research Scholar, Alagappa University, Karaikudi, India
alkavitha82@gmail.com
Korean Journal of Chemical Engineering, June 2016, 33(6), 1948-1953(6), 10.1007/s11814-016-0042-5
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Abstract
Magnetite nanoparticles were synthesized by coprecipitation and characterized. The average particle size was 22-50 nm by XRD and AFM. Chitosan was prepared from crab shells and characterized. Magnetite-chitosan composite carbon paste modified electrode was prepared and characterized by using XRD, FT-IR and SEM technique. The electrochemical responses of this Magnetite-CH composite electrode were studied in potassium ferrocyanide/KCl system using cyclic voltammetry and electrochemical impedance spectroscopy. The cyclic voltammetric and EIS studies indicated better electron transfer of magnetite-CH composite (3 : 1) carbon paste modified electrodes compared to bare, magnetite, chitosan composite electrodes. The surface parameters like surface coverage (τ), Diffusion coefficient (D0), and rate constant (kS) were studied. The shelf-life of the developed electrode system is about 12 weeks under refrigerated conditions.
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Zhang LY, Zhu XJ, Sun HW, Chi GR, Xu JX, Sun YL, Curr. Appl. Phys., 10(3), 828 (2010)
Wei Y, Ling X, Zou L, Lai D, Lu H, Xu Y, Colloids Surf. A: Physicochem. Eng. Asp., 482, 507 (2015)
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Deng KQ, Li CX, Qiu XY, Zhou JH, Hou ZH, J. Electroanal. Chem., 755, 197 (2015)
Gashti MP, Ourquin M, Stir M, Hulliger J, J. Mater. Chem., 1, 1501 (2013)
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Gashti MP, Burgener M, Stir M, Hulliger J, J. Colloid Interface Sci., 431, 49 (2014)
Pawlak A, Mucha M, Thermochim. Acta, 396, 153 (2013)
Solanki PR, Arya SK, Singh SP, Pandey MK, Malhotra BD, Sens. Actuators B-Chem., 123, 829 (2007)
