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Received January 7, 2015
Accepted February 18, 2016
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Investigation of synergistic adsorption between methyl orange and Cd(II) from binary mixtures on magnesium hydroxide modified clinoptilolite
School of Chemical Engineering and Energy, Zhengzhou University, 100# of Kexue Road, Zhengzhou 450001, P. R. China 1College of Public Health, Zhengzhou University, 100, 100# of Kexue Road, Zhengzhou 450001, P. R. China
whzou@zzu.edu.cn, whzou@163.com
Korean Journal of Chemical Engineering, July 2016, 33(7), 2073-2083(11), 10.1007/s11814-016-0048-z
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Abstract
The simultaneous removal of Methyl orange (MO) and Cd2+ (mainly from organo-metallic dyes) onto magnesium hydroxide modified clinoptilolite (MHMC) was described and compared to a single adsorbate situation. The adsorption performance was studied by batch experiments. The adsorption mechanism of MO and Cd2+ on MHMC was investigated. Langmuir and Dubinin-Raduskevich (D-R) isotherm successfully predicted the adsorption of MO and Cd2+ in single and binary systems. Maximum adsorption capacity calculated from Langmuir isotherm equation in single solution for MO and Cd2+ was 0.305 and 0.282mmol/g, respectively. In a binary system of MO/Cd2+, the adsorption capacity for both MO and Cd2+ was higher than in single solutions. The results indicated that the adsorption system of MO/Cd2+ presented a synergistic effect, not competitive adsorption, which suggested that MHMC can be used as an adsorbent for removal of dyes and heavy metal in the multi-solute system.
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References
Mall ID, Srivastava VC, Agarval NK, Dyes Pigment., 69, 210 (2006)
Alver E, Metin AU, Chem. Eng. J., 200-202, 59 (2012)
Kongsuwan A, Patnukao P, Pavasant P, J. Ind. Eng. Chem., 15(4), 465 (2009)
Al-Degs Y, Khraisheh MAM, Allen SJ, Ahmad MN, Walker GM, Chem. Eng. J., 128(2-3), 163 (2007)
Sismanoglu T, Kismir Y, Karakus S, J. Hazard. Mater., 184(1-3), 164 (2010)
Cao CY, Qu J, Wei F, Liu H, Song WG, ACS Appl. Mater. Inter., 4, 4283 (2012)
Kramer DA, Kirk-Othmer Encyclopedia of Chemical Technology, John Wiley & Sons, Inc. New Jersey, USA (2004).
Zou WH, Bai HJ, Zhao L, Li K, Han RP, J. Radioanal. Nucl. Chem., 288, 779 (2011)
Kyzas GZ, Lazaridis NK, Mitropoulos AC, Chem. Eng. J., 189-190, 148 (2012)
Han RP, Wang Y, Sun Q, Wang LL, Song JY, He XT, Dou CC, J. Hazard. Mater., 175(1-3), 1056 (2010)
Song JY, Zou WH, Bian YY, Su FY, Han RP, Desalination, 265(1-3), 119 (2011)
Han RP, Zhang LJ, Song C, Zhang MM, Zhu HM, Zhang LJ, Carbohydr. Polym., 79, 1140 (2010)
Tanyildizi MS, Chem. Eng. J., 168(3), 1234 (2011)
Rahman MS, Islam MR, Chem. Eng. J., 149(1-3), 273 (2009)
Gupta N, Kushwaha AK, Chattopadhyaya MC, J. Taiwan Inst. Chem. E., 43, 125 (2012)
Ahmed SA, Carbohydr. Polym., 83, 1470 (2011)
Hernandez-Montoya V, Perez-Cruz MA, Mendoza-Castillo DI, Moreno-Virgen MR, Bonilla-Petriciolet A, J. Environ. Manage., 116, 213 (2013)
Zou WH, Bai HJ, Gao SP, J. Chem. Eng. Data, 57(10), 2792 (2012)
Faria PCC, Orfao JJM, Pereira MFR, Water Res., 38, 2043 (2004)
Koh PY, Deposition and assembly of magnesium hydroxide nanostructures on zeolite 4a surfaces, Georgia Institute of Technology, Atlanta (2010).
Bae TH, Liu JQ, Thompson JA, Koros WJ, Jones CW, Nair S, Microporous Mesoporous Mater., 139, 120 (2011)
Shen DZ, Fan JX, Zhou WZ, Gao BY, Yue QY, Kang Q, J. Hazard. Mater., 172(1), 99 (2009)
Buvaneswari N, Kannan C, J. Hazard. Mater., 189(1-2), 294 (2011)
Langmuir I, J. Am. Chem. Soc., 38, 2221 (1916)
Freundlich HMF, J. Phys. Chem., 57, 385 (1906)
Ozcan AS, Erdem B, Ozcan A, J. Colloid Interface Sci., 280(1), 44 (2004)
Auta M, Hameed BH, Chem. Eng. J., 171(2), 502 (2011)
Foo KY, Hameed BH, Chem. Eng. J., 156(1), 2 (2010)
El-Bayaa AA, Badawy NA, AlKhalik EA, J. Hazard. Mater., 170(2-3), 1204 (2009)
Murray JW, J. Colloid Interface Sci., 46, 357 (1974)
Lackovic K, Angove MJ, Wells JD, Johnson BB, J. Colloid Interface Sci., 269(1), 37 (2004)
Hameed BH, Ahmad AA, Aziz N, Desalination, 247(1-3), 551 (2009)
Ahmed MJ, Theydan SK, Ecotox. Environ. Safe., 84, 39 (2012)
Khaled A, El Nemr A, EI-Sikaily A, Abdelwahab O, J. Hazard. Mater., 165(1-3), 100 (2009)
Kannan N, Sundaram MM, Dyes Pigment., 51, 25 (2001)
Maksin DD, Nastasovic AB, Milutinovic-Nikolic AD, Surucic LT, Sandic ZP, Hercigonja RV, Onjia AE, J. Hazard. Mater., 209-210, 210 (2012)
Liu L, Wan YZ, Xie YD, Zhai R, Zhang B, Liu JD, Chem. Eng. J., 187, 210 (2012)
Barkakati P, Begum A, Das ML, Rao PG, Chem. Eng. J., 161(1-2), 34 (2010)
Dogan M, Ozdemir Y, Alkan M, Dyes Pigment., 75, 701 (2007)
Singh KK, Rastogi R, Hasan SH, J. Colloid Interface Sci., 290(1), 61 (2005)
Alver E, Metin AU, Chem. Eng. J., 200-202, 59 (2012)
Kongsuwan A, Patnukao P, Pavasant P, J. Ind. Eng. Chem., 15(4), 465 (2009)
Al-Degs Y, Khraisheh MAM, Allen SJ, Ahmad MN, Walker GM, Chem. Eng. J., 128(2-3), 163 (2007)
Sismanoglu T, Kismir Y, Karakus S, J. Hazard. Mater., 184(1-3), 164 (2010)
Cao CY, Qu J, Wei F, Liu H, Song WG, ACS Appl. Mater. Inter., 4, 4283 (2012)
Kramer DA, Kirk-Othmer Encyclopedia of Chemical Technology, John Wiley & Sons, Inc. New Jersey, USA (2004).
Zou WH, Bai HJ, Zhao L, Li K, Han RP, J. Radioanal. Nucl. Chem., 288, 779 (2011)
Kyzas GZ, Lazaridis NK, Mitropoulos AC, Chem. Eng. J., 189-190, 148 (2012)
Han RP, Wang Y, Sun Q, Wang LL, Song JY, He XT, Dou CC, J. Hazard. Mater., 175(1-3), 1056 (2010)
Song JY, Zou WH, Bian YY, Su FY, Han RP, Desalination, 265(1-3), 119 (2011)
Han RP, Zhang LJ, Song C, Zhang MM, Zhu HM, Zhang LJ, Carbohydr. Polym., 79, 1140 (2010)
Tanyildizi MS, Chem. Eng. J., 168(3), 1234 (2011)
Rahman MS, Islam MR, Chem. Eng. J., 149(1-3), 273 (2009)
Gupta N, Kushwaha AK, Chattopadhyaya MC, J. Taiwan Inst. Chem. E., 43, 125 (2012)
Ahmed SA, Carbohydr. Polym., 83, 1470 (2011)
Hernandez-Montoya V, Perez-Cruz MA, Mendoza-Castillo DI, Moreno-Virgen MR, Bonilla-Petriciolet A, J. Environ. Manage., 116, 213 (2013)
Zou WH, Bai HJ, Gao SP, J. Chem. Eng. Data, 57(10), 2792 (2012)
Faria PCC, Orfao JJM, Pereira MFR, Water Res., 38, 2043 (2004)
Koh PY, Deposition and assembly of magnesium hydroxide nanostructures on zeolite 4a surfaces, Georgia Institute of Technology, Atlanta (2010).
Bae TH, Liu JQ, Thompson JA, Koros WJ, Jones CW, Nair S, Microporous Mesoporous Mater., 139, 120 (2011)
Shen DZ, Fan JX, Zhou WZ, Gao BY, Yue QY, Kang Q, J. Hazard. Mater., 172(1), 99 (2009)
Buvaneswari N, Kannan C, J. Hazard. Mater., 189(1-2), 294 (2011)
Langmuir I, J. Am. Chem. Soc., 38, 2221 (1916)
Freundlich HMF, J. Phys. Chem., 57, 385 (1906)
Ozcan AS, Erdem B, Ozcan A, J. Colloid Interface Sci., 280(1), 44 (2004)
Auta M, Hameed BH, Chem. Eng. J., 171(2), 502 (2011)
Foo KY, Hameed BH, Chem. Eng. J., 156(1), 2 (2010)
El-Bayaa AA, Badawy NA, AlKhalik EA, J. Hazard. Mater., 170(2-3), 1204 (2009)
Murray JW, J. Colloid Interface Sci., 46, 357 (1974)
Lackovic K, Angove MJ, Wells JD, Johnson BB, J. Colloid Interface Sci., 269(1), 37 (2004)
Hameed BH, Ahmad AA, Aziz N, Desalination, 247(1-3), 551 (2009)
Ahmed MJ, Theydan SK, Ecotox. Environ. Safe., 84, 39 (2012)
Khaled A, El Nemr A, EI-Sikaily A, Abdelwahab O, J. Hazard. Mater., 165(1-3), 100 (2009)
Kannan N, Sundaram MM, Dyes Pigment., 51, 25 (2001)
Maksin DD, Nastasovic AB, Milutinovic-Nikolic AD, Surucic LT, Sandic ZP, Hercigonja RV, Onjia AE, J. Hazard. Mater., 209-210, 210 (2012)
Liu L, Wan YZ, Xie YD, Zhai R, Zhang B, Liu JD, Chem. Eng. J., 187, 210 (2012)
Barkakati P, Begum A, Das ML, Rao PG, Chem. Eng. J., 161(1-2), 34 (2010)
Dogan M, Ozdemir Y, Alkan M, Dyes Pigment., 75, 701 (2007)
Singh KK, Rastogi R, Hasan SH, J. Colloid Interface Sci., 290(1), 61 (2005)
