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Received January 29, 2016
Accepted May 2, 2016
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C2H6/CO2 oxidative dehydrogenation (ODH) reaction on nanostructured CrAPSO-34 catalyst: One-pot hydrothermal vs. conventional hydrothermal/impregnation catalyst synthesis
1Chemical Engineering Faculty, Sahand University of Technology, P. O. Box 51335-1996, Sahand New Town, Tabriz, Iran 2Reactor and Catalysis Research Center (RCRC),, Sahand University of Technology, P. O. Box 51335-1996, Sahand New Town, Tabriz, Iran
haghighi@sut.ac.ir
Korean Journal of Chemical Engineering, September 2016, 33(9), 2555-2566(12), 10.1007/s11814-016-0125-3
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Abstract
A series of Cr incorporated SAPO-34 catalysts varying in Cr content and a Cr supported SAPO-34 catalyst were prepared by one-pot hydrothermal and incipient-wetness impregnation methods, respectively. The synthesized materials were characterized by XRD, FESEM, TEM, BET, EDX dot mapping, TPD-NH3 and FTIR, and tested in ethane dehydrogenation with CO2 reaction. The incorporation of Cr3+ into the SAPO-34 framework and impregnation of Cr species were proved by TEM technique. With increase in the incorporated Cr content, smaller cubic crystals and amorphous particles were obtained. However, the extra-framework species probably appeared. Chromium impregnation led to micropore blockage and surface coverage partly, resulting in morphology change somewhat, significant decrease of surface area and acidity as evidenced by FESEM, TEM, BET and TPD-NH3 analysis. However, one-pot synthesis not only preserved the structure of SAPO-34 but also allowed higher surface area, more effective surface acidity and better chromium dispersion to be achieved, features that account for superior catalytic performance and stability of directly synthesized Cr rich catalyst. The Cr incorporated SAPO-34 catalyst containing rich amount of Cr exhibited the best catalytic activity, showing 38% ethylene yield at 700 ℃ even after 5 h on-stream operation.
References
Castro AJR, Marques SPD, Soares JM, Filho JM, Saraiva GD, Oliveira AC, Chem. Eng. J., 209, 345 (2012)
Botavina MA, Martra G, Agafonov YA, Gaidai NA, Nekrasov NV, Trushin DV, Coluccia S, Lapidus AL, Appl. Catal. A: Gen., 347(2), 126 (2008)
Deng S, Li SG, Li HQ, Zhang Y, Ind. Eng. Chem. Res., 48(16), 7561 (2009)
Michorczyk P, Ogonowski J, Niemczyk M, Appl. Catal. A: Gen., 374(1-2), 142 (2010)
Michorczyk P, Pietrzyk P, Ogonowski J, Microporous Mesoporous Mater., 161, 56 (2012)
Mimura N, Takahara I, Inaba M, Okamoto M, Murata K, Catal. Commun., 3, 257 (2002)
Shishido T, Shimamura K, Teramura K, Tanaka T, Catal. Today, 185(1), 151 (2012)
Takahara I, Chang WC, Mimura N, Saito M, Catal. Today, 45(1-4), 55 (1998)
Valenzuela RX, Bueno G, Solbes A, Sapina F, Martinez E, Corberan VC, Top. Catal., 15, 181 (2001)
Zhang F, Wu R, Yue Y, Yang W, Gu S, Miao C, Hua W, Gao Z, Microporous Mesoporous Mater., 145, 194 (2011)
Liu H, Zhang Z, Li H, Huang Q, J. Natural Gas Chem., 20, 311 (2011)
Michorczyk P, Ogonowski J, Kustrowski P, Chmielarz L, Appl. Catal. A: Gen., 349(1-2), 62 (2008)
Michorczyk P, Ogonowski J, Zenczak K, J. Mol. Catal. A-Chem., 349(1-2), 1 (2011)
Shi XJ, Ji SF, Wang K, Catal. Lett., 125(3-4), 331 (2008)
Blasco T, Nieto JM, Appl. Catal. A: Gen., 157(1-2), 117 (1997)
Setnicka M, Bulanek R, Capek L, Cicmanec P, J. Mol. Catal. A-Chem., 344(1-2), 1 (2011)
Piumetti M, Bonelli B, Massiani P, Dzwigaj S, Rossetti I, Casale S, Armandi M, Thomas C, Garrone E, Catal. Today, 179(1), 140 (2012)
Madeira LM, Portela MF, Catal. Rev.-Sci. Eng., 44(2), 247 (2002)
Dasireddy VDBC, Singh S, Friedrich HB, Appl. Catal. A: Gen., 421-422, 58 (2012)
Lisi L, Marchese L, Pastore HO, Frache A, Ruoppolo G, Russo G, Top. Catal., 22, 95 (2003)
Marchese L, Frache A, Gatti G, Coluccia S, Lisi L, Ruoppolo G, Russo G, Pastore HO, J. Catal., 208(2), 479 (2002)
Flick DW, Huff MC, Appl. Catal. A: Gen., 187(1), 13 (1999)
Zhu Q, Kondo JN, Ohnuma R, Kubota Y, Yamaguchi M, Tatsumi T, Microporous Mesoporous Mater., 112, 153 (2008)
Berube F, Kleitz F, Kaliaguine S, J. Mater. Sci., 44(24), 6727 (2009)
Rajic N, Stojakovic D, Hocevar S, Kaucic V, Zeolites, 13, 384 (1993)
Zhu Z, Hartmann M, Kevan L, Chem. Mater., 12, 2781 (2000)
Tan J, Liu Z, Bao X, Liu X, Han X, He C, Zhai R, Microporous Mesoporous Mater., 53, 97 (2002)
Wang T, Lu X, Yan Y, Microporous Mesoporous Mater., 168, 155 (2013)
Ye L, Cao F, Ying W, Fang D, Sun Q, J. Porous Mat., 18, 225 (2011)
Wojciech KJ, Lana IGD, J. Chem. Soc.-Faraday Trans., 93, 2583 (1997)
Izadbakhsh A, Farhadi F, Khorasheh F, Sahebdelfar S, Asadi M, Feng YZ, Appl. Catal. A: Gen., 364(1-2), 48 (2009)
Liu G, Tian P, Zhang Y, Li J, Xu L, Meng S, Liu Z, Microporous Mesoporous Mater., 114, 416 (2008)
Izadbakhsh A, Farhadi F, Khorasheh F, Sahebdelfar S, Asadi M, Yan ZF, Microporous Mesoporous Mater., 126, 1 (2009)
Aghaei E, Haghighi M, J. Porous Mat., 22, 187 (2015)
Charghand M, Haghighi M, Aghamohammadi S, Ultrason. Sonochem., 21, 1827 (2014)
Aghaei E, Haghighi M, Microporous Mesoporous Mater., 196, 179 (2014)
Ivanova T, Gesheva K, Cziraki A, Szekeres A, Vlaikova E, J. Phys. Condens. Series, 113, 1 (2008)
Mahmoud HR, J. Mol. Catal. A-Chem., 392, 216 (2014)
Liu G, Tian P, Li J, Zhang D, Zhou F, Liu Z, Microporous Mesoporous Mater., 111, 143 (2008)
Rahmani F, Haghighi M, J. Natural Gas Sci. Eng., 27(Part 3), 1684 (2015)
Aghamohammadi S, Haghighi M, Charghand M, Mater. Res. Bull., 50, 462 (2014)
Rahmani F, Haghighi M, Amini M, J. Ind. Eng. Chem., 31, 142 (2015)
Allahyari S, Haghighi M, Ebadi A, Hosseinzadeh S, Energy Conv. Manag., 83, 212 (2014)
Khoshbin R, Haghighi M, Chin. J. Inorg. Chem., 28, 1967 (2012)
Aghaei E, Haghighi M, Powder Technol., 269, 358 (2015)
Aghamohammadi S, Haghighi M, Chem. Eng. J., 264, 359 (2015)
Charghand M, Haghighi M, Saedy S, Aghamohammadi S, Adv. Powder Technol., 25(6), 1728 (2014)
Sadeghpour P, Haghighi M, Particuology, 19, 69 (2015)
Debasis D, Panchanan P, J. Am. Ceram. Soc., 89, 1014 (2004)
Sajjadi SM, Haghighi M, Eslami AA, Rahmani F, J. Sol-Gel Sci. Technol., 67, 601 (2013)
Abdollahifar M, Haghighi M, Babaluo AA, Talkhoncheh SK, Ultrason. Sonochem., 31, 173 (2016)
Goula MA, Lemonidou AA, Efstathiou AM, J. Catal., 161(2), 626 (1996)
Xu BJ, Zheng B, Hua WM, Yue YH, Gao Z, J. Catal., 239(2), 470 (2006)
Chen SW, Qin ZF, Wang GF, Dong M, Wang JG, Fuel, 109, 43 (2013)
Urlan F, Marcu IC, Sandulescu I, Catal. Commun., 9, 2403 (2008)
Zhu QJ, Takiguchi M, Setoyama T, Yokoi T, Kondo JN, Tatsumi T, Catal. Lett., 141(5), 670 (2011)
Botavina MA, Martra G, Agafonov YA, Gaidai NA, Nekrasov NV, Trushin DV, Coluccia S, Lapidus AL, Appl. Catal. A: Gen., 347(2), 126 (2008)
Deng S, Li SG, Li HQ, Zhang Y, Ind. Eng. Chem. Res., 48(16), 7561 (2009)
Michorczyk P, Ogonowski J, Niemczyk M, Appl. Catal. A: Gen., 374(1-2), 142 (2010)
Michorczyk P, Pietrzyk P, Ogonowski J, Microporous Mesoporous Mater., 161, 56 (2012)
Mimura N, Takahara I, Inaba M, Okamoto M, Murata K, Catal. Commun., 3, 257 (2002)
Shishido T, Shimamura K, Teramura K, Tanaka T, Catal. Today, 185(1), 151 (2012)
Takahara I, Chang WC, Mimura N, Saito M, Catal. Today, 45(1-4), 55 (1998)
Valenzuela RX, Bueno G, Solbes A, Sapina F, Martinez E, Corberan VC, Top. Catal., 15, 181 (2001)
Zhang F, Wu R, Yue Y, Yang W, Gu S, Miao C, Hua W, Gao Z, Microporous Mesoporous Mater., 145, 194 (2011)
Liu H, Zhang Z, Li H, Huang Q, J. Natural Gas Chem., 20, 311 (2011)
Michorczyk P, Ogonowski J, Kustrowski P, Chmielarz L, Appl. Catal. A: Gen., 349(1-2), 62 (2008)
Michorczyk P, Ogonowski J, Zenczak K, J. Mol. Catal. A-Chem., 349(1-2), 1 (2011)
Shi XJ, Ji SF, Wang K, Catal. Lett., 125(3-4), 331 (2008)
Blasco T, Nieto JM, Appl. Catal. A: Gen., 157(1-2), 117 (1997)
Setnicka M, Bulanek R, Capek L, Cicmanec P, J. Mol. Catal. A-Chem., 344(1-2), 1 (2011)
Piumetti M, Bonelli B, Massiani P, Dzwigaj S, Rossetti I, Casale S, Armandi M, Thomas C, Garrone E, Catal. Today, 179(1), 140 (2012)
Madeira LM, Portela MF, Catal. Rev.-Sci. Eng., 44(2), 247 (2002)
Dasireddy VDBC, Singh S, Friedrich HB, Appl. Catal. A: Gen., 421-422, 58 (2012)
Lisi L, Marchese L, Pastore HO, Frache A, Ruoppolo G, Russo G, Top. Catal., 22, 95 (2003)
Marchese L, Frache A, Gatti G, Coluccia S, Lisi L, Ruoppolo G, Russo G, Pastore HO, J. Catal., 208(2), 479 (2002)
Flick DW, Huff MC, Appl. Catal. A: Gen., 187(1), 13 (1999)
Zhu Q, Kondo JN, Ohnuma R, Kubota Y, Yamaguchi M, Tatsumi T, Microporous Mesoporous Mater., 112, 153 (2008)
Berube F, Kleitz F, Kaliaguine S, J. Mater. Sci., 44(24), 6727 (2009)
Rajic N, Stojakovic D, Hocevar S, Kaucic V, Zeolites, 13, 384 (1993)
Zhu Z, Hartmann M, Kevan L, Chem. Mater., 12, 2781 (2000)
Tan J, Liu Z, Bao X, Liu X, Han X, He C, Zhai R, Microporous Mesoporous Mater., 53, 97 (2002)
Wang T, Lu X, Yan Y, Microporous Mesoporous Mater., 168, 155 (2013)
Ye L, Cao F, Ying W, Fang D, Sun Q, J. Porous Mat., 18, 225 (2011)
Wojciech KJ, Lana IGD, J. Chem. Soc.-Faraday Trans., 93, 2583 (1997)
Izadbakhsh A, Farhadi F, Khorasheh F, Sahebdelfar S, Asadi M, Feng YZ, Appl. Catal. A: Gen., 364(1-2), 48 (2009)
Liu G, Tian P, Zhang Y, Li J, Xu L, Meng S, Liu Z, Microporous Mesoporous Mater., 114, 416 (2008)
Izadbakhsh A, Farhadi F, Khorasheh F, Sahebdelfar S, Asadi M, Yan ZF, Microporous Mesoporous Mater., 126, 1 (2009)
Aghaei E, Haghighi M, J. Porous Mat., 22, 187 (2015)
Charghand M, Haghighi M, Aghamohammadi S, Ultrason. Sonochem., 21, 1827 (2014)
Aghaei E, Haghighi M, Microporous Mesoporous Mater., 196, 179 (2014)
Ivanova T, Gesheva K, Cziraki A, Szekeres A, Vlaikova E, J. Phys. Condens. Series, 113, 1 (2008)
Mahmoud HR, J. Mol. Catal. A-Chem., 392, 216 (2014)
Liu G, Tian P, Li J, Zhang D, Zhou F, Liu Z, Microporous Mesoporous Mater., 111, 143 (2008)
Rahmani F, Haghighi M, J. Natural Gas Sci. Eng., 27(Part 3), 1684 (2015)
Aghamohammadi S, Haghighi M, Charghand M, Mater. Res. Bull., 50, 462 (2014)
Rahmani F, Haghighi M, Amini M, J. Ind. Eng. Chem., 31, 142 (2015)
Allahyari S, Haghighi M, Ebadi A, Hosseinzadeh S, Energy Conv. Manag., 83, 212 (2014)
Khoshbin R, Haghighi M, Chin. J. Inorg. Chem., 28, 1967 (2012)
Aghaei E, Haghighi M, Powder Technol., 269, 358 (2015)
Aghamohammadi S, Haghighi M, Chem. Eng. J., 264, 359 (2015)
Charghand M, Haghighi M, Saedy S, Aghamohammadi S, Adv. Powder Technol., 25(6), 1728 (2014)
Sadeghpour P, Haghighi M, Particuology, 19, 69 (2015)
Debasis D, Panchanan P, J. Am. Ceram. Soc., 89, 1014 (2004)
Sajjadi SM, Haghighi M, Eslami AA, Rahmani F, J. Sol-Gel Sci. Technol., 67, 601 (2013)
Abdollahifar M, Haghighi M, Babaluo AA, Talkhoncheh SK, Ultrason. Sonochem., 31, 173 (2016)
Goula MA, Lemonidou AA, Efstathiou AM, J. Catal., 161(2), 626 (1996)
Xu BJ, Zheng B, Hua WM, Yue YH, Gao Z, J. Catal., 239(2), 470 (2006)
Chen SW, Qin ZF, Wang GF, Dong M, Wang JG, Fuel, 109, 43 (2013)
Urlan F, Marcu IC, Sandulescu I, Catal. Commun., 9, 2403 (2008)
Zhu QJ, Takiguchi M, Setoyama T, Yokoi T, Kondo JN, Tatsumi T, Catal. Lett., 141(5), 670 (2011)
