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Received December 11, 2015
Accepted April 30, 2016
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Parametric study of pyrolysis and steam gasification of rice straw in presence of K2CO3
Humair Ahmed Baloch1 2†
Tianhua Yang1 3
Haipeng Sun1 3
Jie Li1 3
Sabzoi Nizamuddin2
Rundong Li1 3
Zhanguo Kou1 3
Yang Sun1 3
Abdul Waheed Bhutto2†
1Key Laboratory of Clean Energy of Liaoning Province, College of Energy and Environment, Shenyang Aerospace University, No. 37, South Daoyi Street, Daoyi Development District, Shenyang 110136, Liaoning, P. R. China 2Department of Chemical Engineering, Dawood University of Engineering and Technology, Karachi, Pakistan 3, China
humairbaloch@hotmail.com
Korean Journal of Chemical Engineering, September 2016, 33(9), 2567-2574(8), 10.1007/s11814-016-0121-7
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Abstract
A parametric study of pyrolysis and steam gasification of rice straw (RS) was performed to investigate the effect of the presence of K2CO3 on the behavior of gas evolution, gas component distribution, pyrolysis/gasification reactivity, the quality and volume of synthetic gas. During pyrolysis, with the increase in K2CO3 content in RS (i) the instantaneous CO2 concentration was increased while CO concentration was relatively stable; (ii) the yield of CO2 and H2 increased on the cost of CH4. During steam gasification of RS, with the increase in K2CO3 content in RS (i) the instantaneous concentration of CO2 and H2 increased while instantaneous concentration of CO and CH4 decreased; (ii) the yield of CO2 and H2 production and total yield increased; and (iii) yield of CO and CH4 production followed the order: 9% K2CO3 RS<6% K2CO3 RS
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References
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Franco C, Pinto F, Gulyurtlu I, Cabrita I, Fuel, 82(7), 835 (2003)
Ahmed T, Ahmad M, Lam H, Yusup S, Clean Technol. Environ. Policy, 15(3), 513 (2013)
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Mudge LK, Baker EG, Mitchell DH, Brown MD, J. Solar Energy Eng., 107(1), 88 (1985)
Lang RJ, Fuel, 65(10), 1324 (1986)
Li TC, Yan YJ, Ren ZW, Fuel Sci. Technol. Int., 14(7), 879 (1996)
Karimi A, Gray MR, Fuel, 90(1), 120 (2011)
McKee DW, Fuel, 62(2), 170 (1983)
Wood BJ, Sancier KM, Catal. Rev.-Sci. Eng., 26(2), 233 (1984)
McKee DW, Chem. Phys. Carbon, 16, 1 (1981)
Wang J, Jiang MQ, Yao YH, Zhang YM, Cao JQ, Fuel, 88(9), 1572 (2009)
Wu XT, Tang J, Wang J, Fuel, 165, 59 (2016)
Sutton D, Kelleher B, Ross JRH, Fuel Process. Technol., 73(3), 155 (2001)
Aznar MP, Caballero MA, Sancho JA, Frances E, Fuel Process. Technol., 87(5), 409 (2006)
Tada Y, Yasunishi A, KAGAKU KOGAKU RONBUNSHU, 14(4), 552 (1988)
Tan H, Wang S, Luo Z, Yu C, Cen K, J. Engineering Thermophysics, 26(5), 742 (2005)
Yang C, Yao J, Lu X, Yang X, Lin W, Acta Energiae Solars Thermophysics, 27(5), 496 (2006)
Nishimura M, Iwasaki S, Horio M, J. Taiwan Institute of Chemical Engineers, 40(6), 630 (2009)
Cao Y, Gao ZY, Jin J, Zhou HC, Cohron M, Zhao HY, Liu HY, Pan WP, Energy Fuels, 22(3), 1720 (2008)
Abuadala A, Dincer I, Thermochim. Acta, 507-508, 127 (2010)
Karimipour S, Gerspacher R, Gupta R, Spiteri RJ, Fuel, 103, 308 (2013)
Canabarro N, Soares J, Anchieta C, Kelling C, Mazutti M, Sustainable Chemical Processes, 1(1), 22 (2013)
Jenkins BM, Bakker RR, Wei JB, Biomass Bioenerg., 10(4), 177 (1996)
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