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Received December 8, 2015
Accepted April 23, 2016
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Efficient continuous epoxidation of biodiesel in a microstructured reactor
Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, P. R. China
Korean Journal of Chemical Engineering, September 2016, 33(9), 2622-2627(6), 10.1007/s11814-016-0115-5
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Abstract
Efficient continuous epoxidation of biodiesel with peracetic acid generated in situ from hydrogen peroxide and acetic acid was studied in detail in a microstructured reactor. The effects of micromixer type, reaction temperature, catalyst usage, flow rate and residence time were considered. Results show the T-type glass micro-structured reactor (TTGMR) outperforms the interdigital multilamination micromixer. Under the optimized conditions, the final product from TTGMR has an epoxy value of 6.5 and an iodine value of 2.2.
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Protasova LN, Bulut M, Ormerod D, Buekenhoudt A, Berton J, Stevens CV, Org. Process Res. Dev., 17, 760 (2013)
Yang JX, Hu DD, Li W, Yi SH, Chem. Eng. J., 267, 93 (2015)
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Deng QL, Shen RW, Zhao ZM, Yan MM, Zhang LX, Chem. Eng. J., 262, 1168 (2015)
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Lowe H, Hessel V, Lob P, Hubbard S, Org. Process Res. Dev., 10, 1144 (2005)
Nieuwland PJ, Koch K, van Harskamp N, Wehrens R, van Hest JCM, Rutjes FPJT, Chem.- Asian J., 5, 799 (2010)
Vajglova Z, Vesely M, Kristal J, Vychodilova H, Triska J, Jiricny V, Proce. Eng., 42, 1378 (2012)
Li B, Widlicka D, Boucher S, Hayward C, Lucas J, Murray JC, O’Neil BT, Pfisterer D, Samp L, VanAlsten J, Xiang Y, Young J, Org. Process Res. Dev., 16, 2031 (2012)
Rivas DF, Cintas P, Gardeniers HJGE, Chem. Commun., 48, 10935 (2012)
Paquot C, Hautfenne A, Fat and derivatives, 7th Ed., Blackwell Scientific Publications London (1987).
Song H, Tice JD, Ismagilov RF, Angew. Chem.-Int. Edit., 42, 768 (2003)
Ren B, Jiang Y, Tang KY, Qin SF, Zheng XJ, Chem. Ind. Eng. Pro., 26, 702 (2007)
Panic S, Loebbecke S, Tuercke T, Antes J, Boskovic D, Chem. Eng. J., 101(1-3), 409 (2004)
Gan LH, Goh SH, Ooi KS, J. Am. Oil Chem. Soc., 69, 347 (1992)
Petrovic ZS, Zlatanic A, Lava CC, Sinadinovic-Ficer S, Eur. J. Lipid Sci. Technol., 104, 293 (2002)
Campanella A, Baltanas MA, Chem. Eng. Process., 46(3), 210 (2007)
Goud VV, Patwardhan AV, Pradhan NC, Bioresour. Technol., 97(12), 1365 (2006)
Bringer MR, Gerdts CJ, Song H, Tice JD, Ismagilov RF, Philos. Trans. R. Soc. Lond. Ser. A-Math. Phys. Eng. Sci., 362, 1087 (2004)
Burns JR, Ramshaw C, Lab. Chip, 1, 10 (2001)
Dummann G, Quittmann U, Grschel L, Agar DW, Wrz O, Morgenschweis K, Catal. Today, 70-80, 433 (2003)
Piazza G, Foglia T, Nunez A, J. Am. Oil Chem. Soc., 78, 589 (2001)
Yue J, Rebrov EV, Schouten JC, Lab. Chip, 14, 1632 (2014)
Wiles C, Watts P, Chem. Commun., 47, 6512 (2011)
Kongyai C, Chalermsinsuwan B, Hunsom M, Korean J. Chem. Eng., 30(2), 327 (2013)
Klaas MRG, Warwel S, J. Am. Oil Chem. Soc., 73, 1453 (1996)
