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Received January 27, 2016
Accepted April 19, 2016
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An experimental and kinetic study of toluene oxidation over LaMn1-xBxO3 and La0.8A0.2Mn0.3B0.7O3 (A=Sr, Ce and B=Cu, Fe) nano-perovskite catalysts
Department of Chemical & Petroleum Engineering, University of Tabriz, Tabriz, Iran 1Department of Applied Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran
Korean Journal of Chemical Engineering, September 2016, 33(9), 2628-2637(10), 10.1007/s11814-016-0108-4
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Abstract
Catalytic oxidation of toluene over perovskite-type oxides of the general formula LaMn1-xBxO3 (B=Cu, Fe and x=0, 0.3, 0.7) and La0.8A0.2Mn0.3B0.7O3 (A=Sr, Ce and B=Cu, Fe) was investigated, where the catalysts were synthesized by sol-gel auto combustion method. The catalysts were characterized by XRD, BET, H2-TPR, XPS, and SEM. Obtained XRD patterns confirmed the perovskites to be single-phase perovskite-type oxides. Specific surface areas of perovskites were obtained between 25-40m2/g. The perovskite catalysts showed high activity for the toluene oxidation. Based on the results, Fe-containing perovskite catalysts exhibited higher activity than Cu-containing perovskite catalysts. The substitution of Sr and Ce in A-site of the perovskite catalysts enhanced their activity for toluene oxidation. Among different synthesized catalysts in this research, La0.8Ce0.2Mn0.3Fe0.7O3 has the highest activity. Nearly complete elimination of toluene was achieved at 200 ℃ with this catalyst. Based on Langmuir-Hinshelwood mechanisms, kinetic studies were conducted on toluene oxidation, indicating LH-OS-ND (adsorption of reagents on same types of sites and non-dissociative adsorption of oxygen) as the most probable mechanism which could predict the experimental data with correlation coefficient of R2=0.9952.
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Behar S, Gomez-Mendoza NA, Gomez-Garcia MA, Swierczynski D, Quignard F, Tanchoux N, Appl. Catal. A: Gen., 504, 203 (2014)
Bedia J, Rosas JM, Rodriguez-Mirasol J, Cordero T, Appl. Catal. B: Environ., 94(1-2), 8 (2010)
