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Received January 19, 2016
Accepted April 14, 2016
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Interactions among biomass components during co-pyrolysis in (macro)thermogravimetric analyzers
Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Department of Thermal Engineering, Tsinghua University, Beijing 100084, China 1Department of Earth and Environmental Engineering, Columbia University, New York, NY 10027, U.S.A., USA
hz2411@columbia.edu
Korean Journal of Chemical Engineering, September 2016, 33(9), 2638-2643(6), 10.1007/s11814-016-0102-x
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Abstract
The interactions of biomass components (hemicellulose, cellulose, and lignin) during co-pyrolysis were investigated in a thermogravimetric analyzer (TGA) as well as a self-designed Macro-TGA with higher heating rate and larger amount of sample. The overlap ratio (OR) was used to evaluate the interaction of biomass components quantitatively. In TGA, the pyrolysis of xylan was not significantly affected by cellulose, whereas the pyrolysis of cellulose was markedly influenced by xylan. The interactions between xylan and lignin were weak with an overlap ratio of 0.9869, whereas co-pyrolysis of cellulose and lignin was strongly inhibited by interactions with the overlap ratio of 0.9737. In Macro-TGA, interactions between components were stronger than that in TGA due to more considerable heat and mass transfer effect.
References
Guan QQ, Wei CH, Chai XD, Ning P, Tian SL, Gu JJ, Chen QL, Miao RR, Chin. J. Chem. Eng., 23(1), 205 (2015)
Wu C, Budarin VL, Gronnow MJ, De Bruyn M, Onwudili JA, Clark JH, Williams PT, J. Anal. Appl. Pyrolysis, 107, 276 (2014)
Giudicianni P, Cardone G, Ragucci R, J. Anal. Appl. Pyrolysis, 100, 213 (2013)
Hosoya T, Kawamoto H, Saka S, J. Anal. Appl. Pyrolysis, 85, 237 (2009)
Heidari A, Stahl R, Younesi H, Rashidi A, Troeger N, Ghoreyshi AA, J. Ind. Eng. Chem., 20(4), 2594 (2014)
Burhenne L, Messmer J, Aicher T, Laborie M, J. Anal. Appl. Pyrolysis, 101, 177 (2013)
Zhou H, Wu C, Onwudili JA, Meng A, Zhang Y, Williams PT, RSC Adv., 5, 11371 (2015)
Di Blasi C, Lanzetta M, J. Anal. Appl. Pyrolysis, 40-41, 287 (1997)
Dumitriu S, Polysaccharides: Structural Diversity and Functional Versatility, 2nd Ed., CRC Press, Boca Raton, Florida (2004).
Shen DK, Gu S, Bioresour. Technol., 100(24), 6496 (2009)
Hage RE, Brosse N, Chrusciel L, Sanchez C, Sannigrahi P, Ragauskas A, Polym. Degrad. Stabil., 94, 1632 (2009)
Chatel G, Rogers RD, ACS Sustain. Chem. Eng., 2, 322 (2014)
Zhou H, Wu CF, Onwudili JA, Meng AH, Zhang YG, Williams PT, Energy Fuels, 28(10), 6371 (2014)
Stefanidis SD, Kalogiannis KG, Iliopoulou EF, Michailof CM, Pilavachi PA, Lappas AA, J. Anal. Appl. Pyrolysis, 105, 143 (2014)
Hosoya T, Kawamoto H, Saka S, J. Anal. Appl. Pyrolysis, 78, 328 (2007)
Chayaporn S, Sungsuk P, Sunphorka S, Kuchonthara P, Piumsomboon P, Chalermsinsuwan B, Korean J. Chem. Eng., 32(6), 1081 (2015)
Wang G, Li W, Li BQ, Chen HK, Fuel, 87(4-5), 552 (2008)
Worasuwannarak N, Sonobe T, Tanthapanichakoon W, J. Anal. Appl. Pyrolysis, 78, 265 (2007)
Cho JM, Chu S, Dauenhauer PJ, Huber GW, Green Chem., 14, 428 (2012)
Zhang J, Chen T, Wu J, Wu J, RSC Adv., 4, 17513 (2014)
Long YF, Ruan L, Lv XY, Lv YJ, Su J, Wen YX, Chin. J. Chem. Eng., 23(10), 1691 (2015)
Soysa R, Choi YS, Choi SK, Kim SJ, Han SY, Korean J. Chem. Eng., 33(2), 603 (2016)
Chattopadhyay J, Kim CH, Kim RH, Pak DW, J. Ind. Eng. Chem., 15(1), 72 (2009)
Seo DK, Park SS, Kim YT, Hwang J, Yu TU, J. Anal. Appl. Pyrolysis, 92, 209 (2011)
Biagini E, Fantei A, Tognotti L, Thermochim. Acta, 472(1-2), 55 (2008)
Zhou H, Wu C, Meng A, Zhang Y, Williams PT, J. Anal. Appl. Pyrolysis, 110, 264 (2014)
Zhou H, Long Y, Meng A, Chen S, Li Q, Zhang Y, RSC Adv., 5, 26509 (2015)
Yang HP, Yan R, Chen HP, Lee DH, Zheng CG, Fuel, 86(12-13), 1781 (2007)
Shen DK, Gu S, Bridgwater AV, J. Anal. Appl. Pyrolysis, 87, 199 (2010)
Zhou H, Long YQ, Meng AH, Li QH, Zhang YG, Thermochim. Acta, 566, 36 (2013)
Hosoya T, Kawamoto H, Saka S, J. Anal. Appl. Pyrolysis, 80, 118 (2007)
Wang SR, Guo XJ, Wang KG, Luo ZY, J. Anal. Appl. Pyrolysis, 91, 183 (2011)
Horne PA, Williams PT, Renew. Energy, 7, 131 (1996)
Couhert C, Commandre JM, Salvador S, Fuel, 88(3), 408 (2009)
Wu C, Budarin VL, Gronnow MJ, De Bruyn M, Onwudili JA, Clark JH, Williams PT, J. Anal. Appl. Pyrolysis, 107, 276 (2014)
Giudicianni P, Cardone G, Ragucci R, J. Anal. Appl. Pyrolysis, 100, 213 (2013)
Hosoya T, Kawamoto H, Saka S, J. Anal. Appl. Pyrolysis, 85, 237 (2009)
Heidari A, Stahl R, Younesi H, Rashidi A, Troeger N, Ghoreyshi AA, J. Ind. Eng. Chem., 20(4), 2594 (2014)
Burhenne L, Messmer J, Aicher T, Laborie M, J. Anal. Appl. Pyrolysis, 101, 177 (2013)
Zhou H, Wu C, Onwudili JA, Meng A, Zhang Y, Williams PT, RSC Adv., 5, 11371 (2015)
Di Blasi C, Lanzetta M, J. Anal. Appl. Pyrolysis, 40-41, 287 (1997)
Dumitriu S, Polysaccharides: Structural Diversity and Functional Versatility, 2nd Ed., CRC Press, Boca Raton, Florida (2004).
Shen DK, Gu S, Bioresour. Technol., 100(24), 6496 (2009)
Hage RE, Brosse N, Chrusciel L, Sanchez C, Sannigrahi P, Ragauskas A, Polym. Degrad. Stabil., 94, 1632 (2009)
Chatel G, Rogers RD, ACS Sustain. Chem. Eng., 2, 322 (2014)
Zhou H, Wu CF, Onwudili JA, Meng AH, Zhang YG, Williams PT, Energy Fuels, 28(10), 6371 (2014)
Stefanidis SD, Kalogiannis KG, Iliopoulou EF, Michailof CM, Pilavachi PA, Lappas AA, J. Anal. Appl. Pyrolysis, 105, 143 (2014)
Hosoya T, Kawamoto H, Saka S, J. Anal. Appl. Pyrolysis, 78, 328 (2007)
Chayaporn S, Sungsuk P, Sunphorka S, Kuchonthara P, Piumsomboon P, Chalermsinsuwan B, Korean J. Chem. Eng., 32(6), 1081 (2015)
Wang G, Li W, Li BQ, Chen HK, Fuel, 87(4-5), 552 (2008)
Worasuwannarak N, Sonobe T, Tanthapanichakoon W, J. Anal. Appl. Pyrolysis, 78, 265 (2007)
Cho JM, Chu S, Dauenhauer PJ, Huber GW, Green Chem., 14, 428 (2012)
Zhang J, Chen T, Wu J, Wu J, RSC Adv., 4, 17513 (2014)
Long YF, Ruan L, Lv XY, Lv YJ, Su J, Wen YX, Chin. J. Chem. Eng., 23(10), 1691 (2015)
Soysa R, Choi YS, Choi SK, Kim SJ, Han SY, Korean J. Chem. Eng., 33(2), 603 (2016)
Chattopadhyay J, Kim CH, Kim RH, Pak DW, J. Ind. Eng. Chem., 15(1), 72 (2009)
Seo DK, Park SS, Kim YT, Hwang J, Yu TU, J. Anal. Appl. Pyrolysis, 92, 209 (2011)
Biagini E, Fantei A, Tognotti L, Thermochim. Acta, 472(1-2), 55 (2008)
Zhou H, Wu C, Meng A, Zhang Y, Williams PT, J. Anal. Appl. Pyrolysis, 110, 264 (2014)
Zhou H, Long Y, Meng A, Chen S, Li Q, Zhang Y, RSC Adv., 5, 26509 (2015)
Yang HP, Yan R, Chen HP, Lee DH, Zheng CG, Fuel, 86(12-13), 1781 (2007)
Shen DK, Gu S, Bridgwater AV, J. Anal. Appl. Pyrolysis, 87, 199 (2010)
Zhou H, Long YQ, Meng AH, Li QH, Zhang YG, Thermochim. Acta, 566, 36 (2013)
Hosoya T, Kawamoto H, Saka S, J. Anal. Appl. Pyrolysis, 80, 118 (2007)
Wang SR, Guo XJ, Wang KG, Luo ZY, J. Anal. Appl. Pyrolysis, 91, 183 (2011)
Horne PA, Williams PT, Renew. Energy, 7, 131 (1996)
Couhert C, Commandre JM, Salvador S, Fuel, 88(3), 408 (2009)
