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Received October 20, 2015
Accepted April 30, 2016
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Synthesis of acrylic-lignosulfonate resin for crystal violet removal from aqueous solution
School of Science, Jiaozuo Teachers’ College, Jiaozuo Engineering Technology Research Center of Separation and Adsorption Materials, Jiaozuo, Henan 454000, China
xwj900128@126.com
Korean Journal of Chemical Engineering, September 2016, 33(9), 2659-2667(9), 10.1007/s11814-016-0119-1
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Abstract
A new acrylic-lignosulfonate resin (ALR) was obtained by radical polymerization using calcium lignosulfonate (LS-Ca) and acrylic acid (AA) as raw materials. ALR was characterized using FT-IR, SEM, TG-DSC and N2 adsorption.desorption surface area and pore size analyzer. Batch adsorption, including initial concentration, time, pH, dosage and temperature on the adsorption of crystal violet (CV) by ALR, was systematically studied. The ALR contained porous structure and the specific surface area of ALR was 190.55m2/g with average pore diameter 11.34 nm. The kinetic and equilibrium data fitted into the pseudo-second-order model and Freundlich isotherm model, respectively. The adsorption process was slightly influenced in the range of pH=3-12. The maximum adsorption capacity of CV was found to be as high as 150.40±4.80mg/g for 24 h at 25 ℃. Thermodynamic parameters were evaluated, and their values indicated that adsorption of CV on ALR was an exothermic process and spontaneous.
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Rafatullah M, Sulaiman O, Hashim R, Ahmad A, J. Hazard. Mater., 177(1-3), 70 (2010)
Gao HJ, Kan TT, Zhao SY, Qian YX, Cheng XY, Wu WL, Wang XD, Zheng LG, J. Hazard. Mater., 261, 83 (2013)
Vakili M, Rafatullah M, Salamatinia B, Abdullah AZ, Ibrahim MH, Tan KB, Carbohydr. Polym., 113, 115 (2014)
Cardoso NF, Lima EC, Royer B, Bach MV, Dotto GL, Pinto LAA, Calvete T, J. Hazard. Mater., 241-242, 146 (2012)
Gao HJ, Kan TT, Zhao SY, Qian YX, Cheng XY, Wu WL, Wang XD, Zheng LG, J. Hazard. Mater., 261, 83 (2013)
Ahmad T, Danish M, Rafatullah M, Ghazali A, Sulaiman O, Hashim R, Environ. Sci. Pollut. Res. Int., 19(5), 1464 (2012)
Ahmad T, Rafatullah M, Ghazali A, Sulaiman O, Hashim R, J. Environ. Sci. Health Part C, 29(3), 177 (2011)
Low LW, Teng TT, Rafatullah M, Morad N, Azahari B, Sep. Sci. Technol., 48(11), 1688 (2013)
Khan TA, Dahiya S, Ali I, Appl. Clay Sci., 69, 58 (2012)
Irem S, Khan QM, Islam E, Hashmat AJ, Haq MA, Afzal M, Mustafa T, Ecol. Eng., 58, 399 (2013)
Yao QX, Xie JJ, Zeng N, Ding C, Liu Y, J. Funct. Mater., 45, 129 (2014)
Xu WJ, Zhang WS, Li W, Yan JL, Shen GY, Li J, J. Appl. Polym. Sci., 126(1), 104 (2012)
Xu WJ, Zhang WS, Zhang SL, Petrochem. Technol., 43, 698 (2014)
Sun YF, Liu ZT, Fei ZH, Li ZX, Xing R, Acta Polym. Sin., 1, 107 (2014)
Guo XY, Zhang SZ, Shan XQ, J. Hazard. Mater., 151(1), 134 (2008)
Sciban MB, Klasnja MT, Antov MG, Ecol. Eng., 37, 2092 (2011)
He XJ, Xie JJ, Wei Y, Li S, Huang K, Han XQ, Zhang HY, Sci. Silvae. Sin., 47, 134 (2011)
da Silva LG, Ruggiero R, Gontijo PD, Pinto RB, Royer B, Lima EC, Fernandes THM, Calvete T, Chem. Eng. J., 168(2), 620 (2011)
Li ZL, Kong Y, Ge YY, Chem. Eng. J., 270, 229 (2015)
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Sciban MB, Klasnja MT, Antov MG, Ecol. Eng., 37, 2092 (2011)
Yao QX, Xie JJ, Liu JX, Kang HM, Liu Y, J. Polym. Res., 21, 465 (2014)
Nair V, Panigrahy A, Vinu R, Chem. Eng. J., 254, 491 (2014)
Ge Y, Xiao D, Li Z, Cui X, J. Mater. Chem. A, 2, 2136 (2014)
Pan JM, Wang B, Dai JD, Dai XH, Hang H, Ou HX, Yan YS, J. Mater. Chem., 22, 3360 (2012)
Jain S, Jayaram RV, Desalination, 250(3), 921 (2010)
Lafi R, Fradj A, Hafiane A, Hameed BH, Korean J. Chem. Eng., 31(12), 2198 (2014)
Zhan YC, Luo XB, Nie SS, Huang YN, Tu XM, Luo SL, Ind. Eng. Chem. Res., 50(10), 6355 (2011)
Hameed BH, Colloids Surf. A: Physicochem. Eng. Asp., 307, 45 (2007)
Zhang JP, Lin XY, Luo XG, Zhang C, Zhu H, Chem. Eng. J., 168(3), 1055 (2011)
Royer B, Cardoso NF, Lima EC, Macedo TR, Airoldi C, J. Hazard. Mater., 181(1-3), 366 (2010)
Sun CL, Wang CS, J. Mol. Struct., 956, 38 (2010)
