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Received April 12, 2016
Accepted May 5, 2016
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Characterization of the bio-oil and bio-char produced by fixed bed pyrolysis of the brown alga Saccharina japonica
Department of Chemical Engineering, Pukyong National University, 365 Sinseon-ro, Nam-gu, Busan 48513, Korea 1Department of Chemical Engineering, Kangwon National University, 346 Joongang-ro, Samcheok-si, Gangwon-do 25913, Korea 2Clean Energy Research Center, Korea Institute of Science and Technology, 5 Hwarang-ro 14-gil, Seongbuk-gu, Seoul 02792, Korea 3Research Institute of Petroleum Technology, Korea Petroleum Quality & Distribution Authority, 33 Yangcheong 3-gil, Cheongwon-gun, Chungcheongbuk-do 28115, Korea
woohc@pknu.ac.kr
Korean Journal of Chemical Engineering, September 2016, 33(9), 2691-2698(8), 10.1007/s11814-016-0131-5
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Abstract
Brown alga Saccharina japonica was pyrolyzed in a fixed bed reactor under conditions intended to maximize the yield of bio-oil and bio-char. The results revealed that the product distribution of bio-oil, bio-char, and gas was considerably influenced by the pyrolysis temperature (430-530 ℃) and holding time (4-10min). The maximum yields of bio-oil and bio-char were approximately 48.4 and 32.3wt%, respectively, when prepared at 450 oC for 8min with a carrier gas flow rate of 2.2 cm/s. The fuel properties of dewatered S. japonica bio-oil (DSB) included higher heating value (HHV), kinematic viscosity, density, moisture and ash content, pH, and flash and pour point. The possibility of blending 5-20 vol% DSB with No. 6 fuel oil (Bunker C oil) was also examined. The physicochemical properties of the bio-char exhibited decreased carbon and HHV, and increased inorganic elements and surface area, with increasing pyrolysis temperature.
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