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Received February 24, 2016
Accepted April 19, 2016
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Influence of ultrasonication on preparation of novel material for heavy metal removal from wastewater
Saravanan Anbalagan
Senthil Kumar Ponnusamy†
Sundar Rajan Panneer Selvam
Abishek Sankaranarayan
Abhishek Dutta
Department of Chemical Engineering, SSN College of Engineering, Chennai 603 110, India
senthilchem8582@gmail.com
Korean Journal of Chemical Engineering, September 2016, 33(9), 2716-2731(16), 10.1007/s11814-016-0109-3
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Abstract
The present research introduces a new concept on rapid removal of Pb(II) ions from wastewater using novel agro-based material. The two types of materials such as sulfuric acid modified Caryota urens seeds (SMCUS) and ultrasonic assisted Caryota urens seeds (UACUS) were prepared and performance was compared for Pb(II) ions removal. The functional groups available on the C. urens were discussed by using FT-IR report. Adsorption influencing parameters such as initial metal ion concentration, pH, contact time, adsorbent dosage and temperature were studied to predict the optimum conditions. Several isotherm and kinetic models were applied to examine the experimental data. The present adsorption-adsorbate system best obeys the Freundlich and pseudo-first-order models. Langmuir monolayer capacity of the SMCUS and UACUS for Pb(II) ions was found to be 93.7 and 175.9mg/g, respectively. Thermodynamic parameters explain that the adsorption of Pb(II) ions was spontaneous and exothermic.
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Chen CS, Shih YJ, Huang YH, Chem. Eng. J., 279, 120 (2015)
Bhat A, Megeri GB, Thomas C, Bhargava H, Jeevitha C, Chandrashekar S, Madhu GM, J. Environ. Chem. Eng., 3, 30 (2015)
Pandey PK, Sharma SK, Sambi SS, J. Environ. Chem. Eng., 3, 2604 (2015)
Li XH, Wang Z, Li Q, Ma JX, Zhu MZ, Chem. Eng. J., 273, 630 (2015)
Mbamba CK, Batstone DJ, Alsina XF, Tait SA, Water Res., 68, 342 (2015)
Sahu OP, Chaudhari PK, J. Electroanal. Chem., 739, 122 (2015)
Alvarado L, Torres IR, Chen A, Sep. Purif. Methods, 105, 55 (2013)
Rajkumar P, Kumar PS, Priyadharshini M, Kirupha SD, Baskaralingam P, Sivanesan S, Environ. Eng. Manage. J., 13, 905 (2014)
Basu S, Mukherjee S, Kaushik A, Bastra VS, Balakrishnan M, J. Environ. Manage., 158, 55 (2015)
Sumisha A, Arthanareeswaran G, Thuyavan YL, Ismail AF, Chakraborty S, Ecotox. Environ. Safe., 121, 174 (2015)
Liu TY, Bian LX, Yuan HG, Pang B, Lin YK, Tong Y, Bruggen BV, Wang XL, J. Membr. Sci., 478, 2015 (2015)
Ochando-Pulido JM, Verardo V, Segura-Carretero A, Martinez-Ferez A, J. Ind. Eng. Chem., 31, 132 (2015)
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Largitte L, Laminie J, J. Environ. Chem. Eng., 3, 474 (2015)
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Song XL, Liu HY, Cheng L, Qu YX, Desalination, 255(1-3), 78 (2010)
Acharya J, Sahu JN, Mohanty CR, Meikap BC, Chem. Eng. J., 149(1-3), 249 (2009)
Kumar PS, Environ. Prog. Sustain. Energy, 33, 55 (2014)
Al Bahri M, Calvo L, Gilarranz MA, Rodriguez JJ, Chem. Eng. J., 203, 348 (2012)
Divband L, Boroomand S, Ma R, Moradzadeh M, Izadpanah Z, Bibak S, Bhatnagar A, J. Mol. Liq., 211, 448 (2015)
Suopajarvi T, Liimatainen H, Karjalainen M, Upola H, Niinimaki J, J. Water Process Eng., 5, 136 (2015)
Saravanan A, Kumar PS, Mugilan R, Res. Chem. Intermid, 41, 1 (2015)
Kumar PS, Abhinaya RV, Arthi V, Gayathrilakshmi K, Priyadharshini M, Sivanesan S, Environ. Eng. Manage. J., 13, 545 (2013)
Roosta M, Ghaedi M, Mohammadi M, Powder Technol., 267, 134 (2014)
Langmuir I, J. Am. Chem. Soc., 40, 1361 (1918)
Freundlich HMF, J. Phys. Chem., 57, 385 (1959)
Sips R, J. Phys. Chem., 16, 490 (1948)
Fritz W, Schlunder EU, Chem. Eng. Sci., 29, 1279 (1974)
Radke CJ, Praunsitz JM, Fritz EU, Myers AL, Chem. Eng. Sci., 33, 1097 (1978)
Toth J, J. Colloid Interface Sci., 225(2), 378 (2000)
Redlich O, Peterson DL, J. Phys. Chem., 63, 1024 (1959)
Baudu M, Ph.D Thesis, Universite. De. Rennes. I. (1990).
Lagergren S, Kungl. Svensk. Vetensk. Handl., 24, 1 (1898)
Ho YS, McKay G, Process Biochem., 34(5), 451 (1999)
Ho YS, McKay G, Adsorpt. Sci. Technol., 20, 797 (2002)
Ullah I, Nadeem R, Iqbal M, Manzoor Q, Ecol. Eng., 60, 99 (2013)
Ding DH, Lei ZF, Yang YN, Feng CP, Zhang ZY, J. Hazard. Mater., 270, 187 (2014)
Jiang TS, Liu WP, Mao YL, Zhang L, Cheng JL, Gong M, Zhao HB, Dai LM, Zhang S, Zhao Q, Chem. Eng. J., 259, 603 (2015)
Sen TK, Gomez D, Desalination, 267(2-3), 286 (2011)
Fadzil F, Ibrahim S, Hanafiah MAKM, Process Saf. Environ. Protect., 100, 1 (2016)
Li XH, Wang Z, Li Q, Ma JX, Zhu MZ, Chem. Eng. J., 273, 630 (2015)
Ebrahimzadeh H, Asgharinezhad AA, Moazzen E, Amini MM, Sadeghi O, J. Food Compos. Anal., 41, 74 (2015)
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Awual MR, Chem. Eng. J., 289, 65 (2016)
Afzali D, Fayazi M, J. Taiwan Inst. Chem. Eng., (Article in Press) (2016)
Sonmezay A, Oncel MS, Bektas N, Trans. Nonferrous Met. Soc. China, 22, 3131 (2012)
Hamad H, Ezzeddine Z, Kanaan S, Lakis F, Hijazi A, Moussawi M, Adv. Powder Technol., (Article in Press) (2016)
Depci T, Kul AR, Onal Y, Chem. Eng. J., 200-202, 224 (2012)
