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Received June 2, 2016
Accepted August 11, 2016
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Density, refractive index and kinematic viscosity of MIPK, MEK and phosphonium-based ionic liquids and the excess and deviation properties of their binary systems
Department of Chemical Engineering, College of Engineering, Chungnam National University, Daejeon 34134, Korea 1Minerals and Materials Processing Division, Korea Institute of Geoscience and Mineral Resources, Daejeon 34132, Korea
sjpark@cnu.ac.kr
Korean Journal of Chemical Engineering, January 2017, 34(1), 214-224(11), 10.1007/s11814-016-0233-0
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Abstract
The density, refractive index, and kinematic viscosity were measured for extraction solvents for molybdenum: methyl ethyl ketone (MEK), methyl isopropyl ketone (MIPK), trihexyl tetradecyl phosphonium chloride ([P666,14] [Cl]), trihexyl tetradecyl phosphonium dicyanamide ([P666,14][DCA]) and trihexyl tetradecyl phosphonium bis (2,2,4-trimethyl pentyl) phosphinate ([P666,14][TMPP]) at atmospheric pressure for a temperature range of 288.15-318.15 K. The experimental data were correlated using the Daubert and Danner equation, a linear equation and the Goletz and Tassion equation. In addition, the excess molar volumes (VE) and the deviations in molar refractivity (ΔR) at 298.15 K were reported for the following binary systems: {MEK+[P666,14][Cl]}, {MEK+[P666,14][DCA]}, {MEK+[P666,14][TMPP]}, {MIPK+[P666,14][Cl]}, {MIPK+[P666,14][DCA]} and {MIPK+[P666,14][TMPP]}. The determined VE and ΔR values were correlated with the Redlich-Kister equation. The binary density and refractive index data at 298.15 K were also predicted using several mixing rules, and these results were then compared with the experimental data.
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Fortin TJ, Laesecke A, Freund M, Outcalt S, J. Chem. Thermodyn., 57, 276 (2013)
Chirico RD, Frenkel M, Magee JW, Diky V, Muzny CD, Kazakov AF, Kroenlein K, Abdulagatov I, Hardin GR, Acree WE, Brenneke JF, Brown PL, Cummings PT, de Loos TW, Friend DG, Goodwin ARH, Hansen LD, Haynes WM, Koga N, Mandelis A, Marsh KN, Mathias PM, McCabe , J. Chem. Eng. Data, 58(10), 2699 (2013)
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Neves CMSS, Carvalho PJ, Freire MG, Coutinho JAP, J. Chem. Thermodyn., 43(6), 948 (2011)
Rintelen JC, Saylor JH, Gross PM, J. Am. Chem. Soc., 59, 1129 (1937)
Fermeglia M, Lapasin R, Torriano G, J. Chem. Eng. Data, 35, 260 (1990)
Clara RA, Marigliano ACG, Solimo HN, J. Chem. Eng. Data, 51(4), 1473 (2006)
Mears TW, Fookson A, Pomerantz P, Rich EH, Dussinger CS, Howard FL, J. Res. Natl. Bur. Stand., 44, 299 (1950)
Almeida HFD, Lopes-da-Silva JA, Freire MG, Coutinho JAP, J. Chem. Thermodyn., 57, 372 (2013)
De Lorenzi L, Fermeglia M, Torriano G, J. Chem. Eng. Data, 43(2), 183 (1998)
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Oh JH, Park SJ, J. Chem. Eng. Data, 43(6), 1009 (1998)
Han KJ, Oh JH, Park SJ, Gmehling J, J. Chem. Eng. Data, 50(6), 1951 (2005)
Aminabhavi TM, Gopalakrishna B, J. Chem. Eng. Data, 40(4), 856 (1995)
Al-Dujaili AH, Yassen AA, Awwad AM, J. Chem. Eng. Data, 45, 647 (2000)
Akaike H, IEEE T. Automat. Contr., 19, 716 (1974)
Kirkup L, Data Analysis with Excel, Cambridge University Press:Cambridge (2002).
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Kauzman W, Eyring H, J. Am. Chem. Soc., 62, 3113 (1940)
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Nain AK, J. Chem. Eng. Data, 53(3), 850 (2008)
Nakata M, Sakurai M, J. Chem. Soc.-Faraday Trans., 83, 2449 (1987)
