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Received July 14, 2015
Accepted July 23, 2016
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Effect of calcination atmospheres on the catalytic performance of nano-CeO2 in direct synthesis of DMC from methanol and CO2
Department of Applied Chemistry, Taiyuan University of Technology, Taiyuan 030024, China 1State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
Korean Journal of Chemical Engineering, January 2017, 34(1), 29-36(8), 10.1007/s11814-016-0212-5
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Abstract
Nano-CeO2 was prepared through the calcination of Ce(OH)3 precursor in different atmospheres (H2, Ar, air, O2), which was prepared by a hydrothermal method, and then used as catalysts in the direct synthesis of dimethyl carbonate (DMC) from methanol and CO2. The results indicated that the catalyst calcined in O2 (CeO2-O2) showed an optimum catalytic performance, and the yield of DMC reached to 1.304mmol/mmolcat. In addition, reaction temperature and weight of catalyst were optimized. Based on characterizations of the catalysts, the ratio of Ce(IV)/Ce(III) and Lewis acid-base property of nano-CeO2 catalyst could be adjusted through different calcination atmosphere treatment. It was determined that the higher activity of CeO2-O2 catalyst is mainly attributed to its higher ratio of Ce(IV)/Ce(III) as well as abundant and moderate intensity Lewis acid base sites.
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