Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received April 23, 2016
Accepted August 1, 2016
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Structural evolution of hierarchical porous NiO/Al2O3 composites and their application for removal of dyes by adsorption
1School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu Province, China 2Institute of Green Chemistry and Chemical Technology, Jiangsu University, Zhenjiang 212013, Jiangsu Province, China
fxqiu@126.com
Korean Journal of Chemical Engineering, January 2017, 34(1), 41-53(13), 10.1007/s11814-016-0221-4
Download PDF
Abstract
Hierarchical porous NiO/Al2O3 composites were successfully prepared by two-steps. First, the core-shell structured Al2O3 microspheres were prepared via a template-free hydrothermal route using KAl(SO4)2·12H2O and Al2(SO4)3·18H2O as aluminum source. Then, the NiO/Al2O3 composites with micro- and nano-hierarchical structures were prepared by a hydrothermal method combining the subsequent calcination process. The obtained characterization result presented that the morphology of hierarchical Al2O3 microsphere tuned to irregular platelets by simply varying Ni/Al ratios. The BET analysis showed that the special surface area from 52.12m2 g-1 to 214.8m2 g-1 after two hydrothermal complex process. Effects of Ni/Al ratio, adsorbent dosage, Congo red (CR) concentration, coexisting ions, adsorption time and temperature were investigated. The obtained results indicated that NiO/Al2O3 composite had the high adsorption efficiency (99.6%) and great adsorption capacity (186.9mg g-1) under the optimum conditions. The adsorption isotherm and kinetics data were found to be well fitted and in good agreement with the Langmuir isotherm model and pseudo-second order model, respectively. The hierarchical porous NiO/Al2O3 composites presented remarkably higher adsorption efficiency during five recycling, which showed their potential as the highly efficient adsorbent for removal of CR in wastewater.
References
Peng XM, Huang DP, Odoom-Wubah T, Fu DF, Huang JL, Qin QD, J. Colloid Interface Sci., 430, 272 (2014)
Yang SX, Wang LY, Zhang XD, Yang WJ, Song GL, Chem. Eng. J., 275, 315 (2015)
Crini G, Bioresour. Technol., 97(9), 1061 (2006)
Lei CS, Zhu XF, Zhu BC, Yu JG, Ho WK, J. Colloid Interface Sci., 466, 238 (2016)
Gautam RK, Rawat V, Banerjee S, Sanroman MA, Soni S, Singh SK, Chattopadhyaya MC, J. Mol. Liq., 212, 227 (2015)
Pal B, Kaur R, Grover IS, J. Ind. Eng. Chem., 33, 178 (2016)
Jin LN, Qian XY, Wang JG, Aslan H, Dong MD, J. Colloid Interface Sci., 453, 270 (2015)
Liu MD, Xu J, Cheng B, Ho WK, Yu JG, Appl. Surf. Sci., 332, 121 (2015)
Zare K, Sadegh H, Shahryari-ghoshekandi R, Maazinejad B, Ali V, Tyagi I, Agarwal S, Gupta VK, J. Mol. Liq., 212, 266 (2015)
Gupta V, Millett C, Walia GK, Kinra S, Aggarwal A, Prabhakaran P, Bhogadi S, Kumar A, Gupta R, Prabhakaran D, J. Public Health, 23, 129 (2015)
Gupta VK, Suhas, J. Environ. Manage., 90, 2313 (2009)
Huang X, Bo XW, Zhao YX, Gao BY, Wang Y, Sun SL, Yue QY, Li Q, Bioresour. Technol., 165, 116 (2014)
Fang JM, Huang XY, Ouyang X, Wang X, Chem. Eng. J., 270, 309 (2015)
Zhang L, Jiao X, Chen D, Jiao M, Eur. J. Inorg. Chem., 2011, 5258 (2011)
Ottone C, Rivera VF, Fontana M, Bejtka K, Onida B, Cauda V, J. Mater. Sci. Technol., 30, 1167 (2014)
Peng C, Zhang J, Xiong Z, Zhao B, Liu P, Microporous Mesoporous Mater., 215, 133 (2015)
Cai W, Yu J, Cheng B, Su BL, Jaroniec M, J. Phys. Chem. C, 113, 14739 (2009)
Li X, Feng JP, Guo JY, Wang AJ, Prins R, Duan XP, Chen YY, J. Catal., 334, 116 (2016)
Wang T, Chang L, Hatton B, Kong J, Chen G, Jia Y, Xiong D, Wong C, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 43, 310 (2014)
Fan T, Li X, Ding J, Zhang D, Guo Q, Microporous Mesoporous Mater., 108, 204 (2008)
Cho S, Kim S, Oh E, Jung SH, Lee KH, CrystEngComm, 11, 1650 (2009)
Lv PP, Zhao HL, Zeng ZP, Gao CH, Liu X, Zhang TH, Appl. Surf. Sci., 329, 301 (2015)
Wang R, Li Q, Xie D, Xiao H, Lu H, Appl. Surf. Sci., 279, 129 (2013)
Zhang XH, Li XX, Chen H, Li TB, Su W, Guo SD, Mater. Des., 92, 58 (2016)
Chandrasekhar SB, Sarma SS, Ramakrishna M, Babu PS, Rao TN, Kashyap BP, Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process., 591, 46 (2014)
Behnajady MA, Bimeghdar S, Chem. Eng. J., 239, 105 (2014)
Motahari F, Mozdianfard MR, Salavati-Niasari M, Process Saf. Environ. Protect., 93, 282 (2015)
Liu XL, Yan Y, Da ZL, Shi WD, Ma CC, Lv P, Tang YF, Yao GX, Wu YT, Huo PW, Yan YS, Chem. Eng. J., 241, 243 (2014)
Tong KS, Kassim MJ, Azraa A, Chem. Eng. J., 170(1), 145 (2011)
Chen SH, Yue QY, Gao BY, Xu X, J. Colloid Interface Sci., 349(1), 256 (2010)
Zhang T, Li QR, Liu Y, Duan YL, Zhang WY, Chem. Eng. J., 168(2), 665 (2011)
Dursun AY, Kalayci CS, J. Hazard. Mater., 123(1-3), 151 (2005)
Liang ZP, Feng YQ, Meng SX, Liang ZY, Process Biochem., 40(10), 3218 (2005)
Hameed BH, Mahmoud DK, Ahmad AL, J. Hazard. Mater., 158(1), 65 (2008)
Kennedy LJ, Vijaya JJ, Sekaran G, Kayalvizhi K, J. Hazard. Mater., 149(1), 134 (2007)
Liu QS, Zheng T, Wang P, Jiang JP, Li N, Chem. Eng. J., 157(2-3), 348 (2010)
Cheng B, Le Y, Cai WQ, Yu JG, J. Hazard. Mater., 185(2-3), 889 (2011)
Cai W, Yu J, Jaroniec M, J. Mater. Chem., 20, 4587 (2010)
Song Z, Chen L, Hu J, Richards R, Nanatechnol., 20, 275707 (2009)
Cai W, Hu Y, Chen J, Zhang G, Xia T, CrystEngComm, 14, 972 (2012)
Wang R, Li Q, Duan N, Zhang T, Lu H, Res. Chem. Intermed., 41, 7899 (2015)
Fei JB, Cui Y, Yan XH, Qi W, Yang Y, Wang KW, He Q, Li JB, Adv. Mater., 20(3), 452 (2008)
Shan R, Yan L, Yang Y, Yang K, Yu S, Yu H, Zhu B, Du B, J. Ind. Eng. Chem., 21, 561 (2015)
Lei CS, Zhu XF, Zhu BC, Yu JG, Ho WK, J. Colloid Interface Sci., 466, 238 (2016)
Singh K, Mohan S, Appl. Surf. Sci., 221(1-4), 308 (2004)
Leyva-Ramos R, Rivera-Utrilla J, Medellin-Castillo NA, Sanchez-Polo M, Chem. Eng. J., 158(3), 458 (2010)
Ho YS, Water Res., 40, 119 (2006)
Ho YS, McKay G, Water Res., 34, 735 (2000)
Zaghouane-Boudiaf H, Boutahala M, Int. J. Miner. Process., 100(3-4), 72 (2011)
Zaghouane-Boudiaf H, Boutahala M, Tiar C, Arab L, Garin F, Chem. Eng. J., 173(1), 36 (2011)
Wang L, Wang AQ, J. Hazard. Mater., 160(1), 173 (2008)
Ahmad R, Kumar R, Appl. Surf. Sci., 257(5), 1628 (2010)
Yang SX, Wang LY, Zhang XD, Yang WJ, Song GL, Chem. Eng. J., 275, 315 (2015)
Crini G, Bioresour. Technol., 97(9), 1061 (2006)
Lei CS, Zhu XF, Zhu BC, Yu JG, Ho WK, J. Colloid Interface Sci., 466, 238 (2016)
Gautam RK, Rawat V, Banerjee S, Sanroman MA, Soni S, Singh SK, Chattopadhyaya MC, J. Mol. Liq., 212, 227 (2015)
Pal B, Kaur R, Grover IS, J. Ind. Eng. Chem., 33, 178 (2016)
Jin LN, Qian XY, Wang JG, Aslan H, Dong MD, J. Colloid Interface Sci., 453, 270 (2015)
Liu MD, Xu J, Cheng B, Ho WK, Yu JG, Appl. Surf. Sci., 332, 121 (2015)
Zare K, Sadegh H, Shahryari-ghoshekandi R, Maazinejad B, Ali V, Tyagi I, Agarwal S, Gupta VK, J. Mol. Liq., 212, 266 (2015)
Gupta V, Millett C, Walia GK, Kinra S, Aggarwal A, Prabhakaran P, Bhogadi S, Kumar A, Gupta R, Prabhakaran D, J. Public Health, 23, 129 (2015)
Gupta VK, Suhas, J. Environ. Manage., 90, 2313 (2009)
Huang X, Bo XW, Zhao YX, Gao BY, Wang Y, Sun SL, Yue QY, Li Q, Bioresour. Technol., 165, 116 (2014)
Fang JM, Huang XY, Ouyang X, Wang X, Chem. Eng. J., 270, 309 (2015)
Zhang L, Jiao X, Chen D, Jiao M, Eur. J. Inorg. Chem., 2011, 5258 (2011)
Ottone C, Rivera VF, Fontana M, Bejtka K, Onida B, Cauda V, J. Mater. Sci. Technol., 30, 1167 (2014)
Peng C, Zhang J, Xiong Z, Zhao B, Liu P, Microporous Mesoporous Mater., 215, 133 (2015)
Cai W, Yu J, Cheng B, Su BL, Jaroniec M, J. Phys. Chem. C, 113, 14739 (2009)
Li X, Feng JP, Guo JY, Wang AJ, Prins R, Duan XP, Chen YY, J. Catal., 334, 116 (2016)
Wang T, Chang L, Hatton B, Kong J, Chen G, Jia Y, Xiong D, Wong C, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 43, 310 (2014)
Fan T, Li X, Ding J, Zhang D, Guo Q, Microporous Mesoporous Mater., 108, 204 (2008)
Cho S, Kim S, Oh E, Jung SH, Lee KH, CrystEngComm, 11, 1650 (2009)
Lv PP, Zhao HL, Zeng ZP, Gao CH, Liu X, Zhang TH, Appl. Surf. Sci., 329, 301 (2015)
Wang R, Li Q, Xie D, Xiao H, Lu H, Appl. Surf. Sci., 279, 129 (2013)
Zhang XH, Li XX, Chen H, Li TB, Su W, Guo SD, Mater. Des., 92, 58 (2016)
Chandrasekhar SB, Sarma SS, Ramakrishna M, Babu PS, Rao TN, Kashyap BP, Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process., 591, 46 (2014)
Behnajady MA, Bimeghdar S, Chem. Eng. J., 239, 105 (2014)
Motahari F, Mozdianfard MR, Salavati-Niasari M, Process Saf. Environ. Protect., 93, 282 (2015)
Liu XL, Yan Y, Da ZL, Shi WD, Ma CC, Lv P, Tang YF, Yao GX, Wu YT, Huo PW, Yan YS, Chem. Eng. J., 241, 243 (2014)
Tong KS, Kassim MJ, Azraa A, Chem. Eng. J., 170(1), 145 (2011)
Chen SH, Yue QY, Gao BY, Xu X, J. Colloid Interface Sci., 349(1), 256 (2010)
Zhang T, Li QR, Liu Y, Duan YL, Zhang WY, Chem. Eng. J., 168(2), 665 (2011)
Dursun AY, Kalayci CS, J. Hazard. Mater., 123(1-3), 151 (2005)
Liang ZP, Feng YQ, Meng SX, Liang ZY, Process Biochem., 40(10), 3218 (2005)
Hameed BH, Mahmoud DK, Ahmad AL, J. Hazard. Mater., 158(1), 65 (2008)
Kennedy LJ, Vijaya JJ, Sekaran G, Kayalvizhi K, J. Hazard. Mater., 149(1), 134 (2007)
Liu QS, Zheng T, Wang P, Jiang JP, Li N, Chem. Eng. J., 157(2-3), 348 (2010)
Cheng B, Le Y, Cai WQ, Yu JG, J. Hazard. Mater., 185(2-3), 889 (2011)
Cai W, Yu J, Jaroniec M, J. Mater. Chem., 20, 4587 (2010)
Song Z, Chen L, Hu J, Richards R, Nanatechnol., 20, 275707 (2009)
Cai W, Hu Y, Chen J, Zhang G, Xia T, CrystEngComm, 14, 972 (2012)
Wang R, Li Q, Duan N, Zhang T, Lu H, Res. Chem. Intermed., 41, 7899 (2015)
Fei JB, Cui Y, Yan XH, Qi W, Yang Y, Wang KW, He Q, Li JB, Adv. Mater., 20(3), 452 (2008)
Shan R, Yan L, Yang Y, Yang K, Yu S, Yu H, Zhu B, Du B, J. Ind. Eng. Chem., 21, 561 (2015)
Lei CS, Zhu XF, Zhu BC, Yu JG, Ho WK, J. Colloid Interface Sci., 466, 238 (2016)
Singh K, Mohan S, Appl. Surf. Sci., 221(1-4), 308 (2004)
Leyva-Ramos R, Rivera-Utrilla J, Medellin-Castillo NA, Sanchez-Polo M, Chem. Eng. J., 158(3), 458 (2010)
Ho YS, Water Res., 40, 119 (2006)
Ho YS, McKay G, Water Res., 34, 735 (2000)
Zaghouane-Boudiaf H, Boutahala M, Int. J. Miner. Process., 100(3-4), 72 (2011)
Zaghouane-Boudiaf H, Boutahala M, Tiar C, Arab L, Garin F, Chem. Eng. J., 173(1), 36 (2011)
Wang L, Wang AQ, J. Hazard. Mater., 160(1), 173 (2008)
Ahmad R, Kumar R, Appl. Surf. Sci., 257(5), 1628 (2010)
