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Received May 17, 2017
Accepted July 2, 2017
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Densities and excess volumes of aqueous monoethanolamine and diisopropanolamine systems at atmospheric pressure from 303.15 K to 333.15 K
Department of Chemical and Biomolecular Engineering, Seoul National University of Science & Technology, Seoul 01811, Korea 1Climate Change Research Division, Korea Institute of Energy Research, Daejeon 34129, Korea
Korean Journal of Chemical Engineering, October 2017, 34(10), 2725-2730(6), 10.1007/s11814-017-0188-9
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Abstract
The densities of water+monoethanolamine (MEA), water+diisopropanolamine (DIPA), DIPA+MEA binary systems and water+DIPA+MEA ternary system were measured over the full range of composition at temperatures from 303.15 K to 333.15 K by using an Anton Paar digital vibrating tube density meter (DMA4500). The experimental excess volumes were obtained from the experimental density results and fitted using the Redlich-Kister- Muggianu expression. The parameters obtained from the binary excess volume data were used for the correlation of ternary system with one additional ternary parameter for each isotherm. All investigated binary and ternary systems are completely miscible, because the values of excess volume are negative under the examined conditions.
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Yun SH, Kim YE, Choi JH, Nam SC, Chang J, Yoon YI, Korean J. Chem. Eng., 33(12), 3473 (2016)
Redlich O, Kister AT, Ind. Eng. Chem., 40, 345 (1948)
