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In relation to this article, we declare that there is no conflict of interest.
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Received February 4, 2017
Accepted July 2, 2017
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Dry reforming of methane over Ni/SBA-15 catalysts prepared by homogeneous precipitation method

Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, P. R. China
qiulinzhang_kmust@163.com
Korean Journal of Chemical Engineering, November 2017, 34(11), 2823-2831(9), 10.1007/s11814-017-0182-2
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Abstract

Ni/SBA-15 catalyst was prepared by homogeneous precipitation method (Ni-HP) and used for dry reforming of methane (DRM). The related characterization results indicated that the Ni particles were highly dispersed with a size range of 2-5 nm. Compared with Ni/SBA-15 catalyst prepared by impregnation (Ni-IM), the reduction temperature of Ni-HP obtained from H2-TPR was greatly improved, suggesting the stronger metal-support interaction. After reacting at 700 °C for 100 h, the CH4 conversion of DRM over Ni-HP catalyst slightly decreased from 74.5% to 73.8%. While, for the Ni-IM catalyst, the CH4 conversion dropped from 61.7% to 37.3%. Furthermore, the average particle size of Ni-HP was 3.7 nm and 4.7 nm before and after the long-time stability test, respectively, ascribed to the good antisintering property. Although a certain amount of coke was produced, mainly with disorder filamentous carbon of basegrowth, the Ni/SBA-15 prepared by homogeneous precipitation exhibited excellent catalytic activity and stability.

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