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Received February 4, 2017
Accepted July 2, 2017
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Dry reforming of methane over Ni/SBA-15 catalysts prepared by homogeneous precipitation method
Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, P. R. China
qiulinzhang_kmust@163.com
Korean Journal of Chemical Engineering, November 2017, 34(11), 2823-2831(9), 10.1007/s11814-017-0182-2
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Abstract
Ni/SBA-15 catalyst was prepared by homogeneous precipitation method (Ni-HP) and used for dry reforming of methane (DRM). The related characterization results indicated that the Ni particles were highly dispersed with a size range of 2-5 nm. Compared with Ni/SBA-15 catalyst prepared by impregnation (Ni-IM), the reduction temperature of Ni-HP obtained from H2-TPR was greatly improved, suggesting the stronger metal-support interaction. After reacting at 700 °C for 100 h, the CH4 conversion of DRM over Ni-HP catalyst slightly decreased from 74.5% to 73.8%. While, for the Ni-IM catalyst, the CH4 conversion dropped from 61.7% to 37.3%. Furthermore, the average particle size of Ni-HP was 3.7 nm and 4.7 nm before and after the long-time stability test, respectively, ascribed to the good antisintering property. Although a certain amount of coke was produced, mainly with disorder filamentous carbon of basegrowth, the Ni/SBA-15 prepared by homogeneous precipitation exhibited excellent catalytic activity and stability.
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Liu ZC, Zhou J, Cao K, Yang WM, Gao HX, Wang YD, Li HX, Appl. Catal. B: Environ., 125, 324 (2012)
Mo L, Leong KKM, Kawi S, Catal. Sci. Technol., 4, 2107 (2014)
Daza CE, Gallego J, Mondragon F, Moreno S, Molina R, Fuel, 89(3), 592 (2010)
Liu DP, Quek XY, Wah HHA, Zeng GM, Li YD, Yang YH, Catal. Today, 148(3-4), 243 (2009)
Van Dillen AJ, Terorde RJAM, Lensveld DJ, Geus JW, De Jong KP, ChemInform, 34, 257 (2003)
Shiraz MHA, Rezaei M, Meshkani F, Korean J. Chem. Eng., 33(12), 3359 (2016)
Li XY, Li D, Tian H, Zeng L, Zhao ZJ, Gong JL, Appl. Catal. B: Environ., 202, 683 (2017)
Wang CZ, Sun NN, Zhao N, Wei W, Zhao YX, Catal. Today, 281, 268 (2017)
Liu ZC, Zhou J, Cao K, Yang WM, Gao HX, Wang YD, Li HX, Appl. Catal. B: Environ., 125, 324 (2012)
Zhang Q, Wu T, Zhang P, Qi R, Huang R, Song X, Gao L, RSC Adv., 4, 51184 (2014)
Zhao X, Cao Y, Li H, Zhang J, Shi L, Zhang D, RSC Adv., 7, 4735 (2017)
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Burattin P, Che M, Louis C, J. Phys. Chem. B, 101(36), 7060 (1997)
Burattin P, Che M, Louis C, J. Phys. Chem. B, 102(15), 2722 (1998)
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Zhao DY, Feng JL, Huo QS, Melosh N, Fredrickson GH, Chmelka BF, Stucky GD, Science, 279(5350), 548 (1998)
Moulijn JA, van Diepen AE, Kapteijn F, Appl. Catal. A: Gen., 212(1-2), 3 (2001)
Srivastava R, Srinivas D, Ratnasamy P, J. Catal., 233(1), 1 (2005)
Galvez ME, Albarazi A, Da Costa P, Appl. Catal. A: Gen., 504, 143 (2015)
He SY, He SF, Zhang L, Li XF, Wang J, He DD, Lu JC, Luo YM, Catal. Today, 258, 162 (2015)
Gadalla AM, Bower B, Chem. Eng. Sci., 43, 3049 (1988)
Zhang C, Yue H, Huang Z, Li S, Wu G, Ma X, Gong J, ACS Sustain. Chem. Eng., 1, 161 (2013)
Wang N, Chu W, Zhang T, Zhao XS, Int. J. Hydrog. Energy, 37(1), 19 (2012)
Yang YH, Lim S, Du GA, Chen Y, Ciuparu D, Haller GL, J. Phys. Chem. B, 109(27), 13237 (2005)
Lee JH, Koo KY, Jung UH, Park JE, Yoon WL, Korean J. Chem. Eng., 33(11), 3115 (2016)
Tomishige K, Chen YG, Fujimoto K, J. Catal., 181(1), 91 (1999)
Xu L, Miao Z, Song H, Chen W, Chou L, Catal. Sci. Technol., 4, 1759 (2014)
Gao XY, Hidajat K, Kawi S, J. CO2 Util., 15, 146 (2016)
Uchiyama S, Obayashi Y, Hayasaka T, Kawata N, Appl. Catal., 47, 155 (1989)
Zhang Q, Wang M, Zhang T, Wang Y, Tang X, Ning P, RSC Adv., 5, 94016 (2015)
Zhang ZL, Verykios XE, Catal. Today, 21, 589 (1994)
Yang WW, Liu HM, Li YM, Zhang J, Wu H, He DH, Catal. Today, 259, 438 (2016)
Zhou L, Li L, Wei N, Li J, Basset JM, ChemCatChem., 7, 2508 (2015)
Zhao XY, Li HR, Zhang JP, Shi LY, Zhang DS, Int. J. Hydrog. Energy, 41(4), 2447 (2016)
Zhao X, Cao Y, Li H, Zhang J, Shi L, Zhang D, RSC Adv., 7, 4735 (2017)
Yang WW, Liu HM, Li YM, Zhang J, Wu H, He DH, Catal. Today, 259, 438 (2016)
Yang W, Liu H, Li Y, Wu H, He D, Int. J. Hydrog. Energy, 41, 1513 (2015)
Fei H, Rui W, Chao Y, Driss H, Wei C, Hui Z, J. Energy Chem., 25, 709 (2016)
Yasyerli S, Filizgok S, Arbag H, Yasyerli N, Dogu G, Int. J. Hydrog. Energy, 36(8), 4863 (2011)
Wang N, Chu W, Zhang T, Zhao XS, Int. J. Hydrog. Energy, 37(1), 19 (2012)
Liu DP, Quek XY, Wah HHA, Zeng GM, Li YD, Yang YH, Catal. Today, 148(3-4), 243 (2009)