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Received June 30, 2016
Accepted September 25, 2016
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High speed spin coating in fabrication of Pebax 1657 based mixed matrix membrane filled with ultra-porous ZIF-8 particles for CO2/CH4 separation
1Gas Engineering Department, Ahvaz Faculty of Petroleum Engineering, Petroleum University of Technology (PUT), P. O. Box 63431, Ahvaz, Iran 2Faculty of Chemical Engineering, Iran University of Science and Technology (IUST), Narmak, Tehran, Iran 3, Iran 4Department of Petrochemical Engineering, Amirkabir University of Technology (AUT), Mahshahr, Iran
Korean Journal of Chemical Engineering, February 2017, 34(2), 440-453(14), 10.1007/s11814-016-0269-1
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Abstract
Modified ultra-porous ZIF-8 particles were used to prepare novel ZIF-8/Pebax 1657 mixed matrix membranes (MMMs) on PES support for separation of CO2 from CH4 using spin coating method. TEM and SEM were used to characterize modified ZIF-8 particles. SEM was also used to investigate the morphology of synthesized MMMs. The MMMs with thinner selective layer showed higher CO2 permeability and lower CO2/CH4 selectivity in permeation tests compared to MMMs with thicker selective layer. The plasticization was recognized as the main reason for rise in CO2 permeability and drop in CO2/CH4 selectivity of thinner MMMs. The gas sorption results showed that the high permeability of CO2 in MMMs is mainly due to the high solubility of this gas in MMMs, leading to high CO2/CH4 solubility selectivity for MMMs. The fractional free volume and void volume fraction of MMMs increased as the thickness of membrane decreased. Applying higher mixed feed pressures and permeation tests temperatures resulted in increase in CO2 permeability and decrease in CO2/CH4 selectivity. At highest testing temperature (60 °C), the CO2 permeability of synthesized MMMs with thinner selective layer remarkably increased.
References
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Cravillon J, Nayuk R, Springer S, Feldhoff A, Huber K, Wiebcke M, Chem. Mater., 23, 2130 (2011)
Gross AF, Sherman E, Vajo JJ, J. Chem. Soc.-Dalton Trans., 41, 5458 (2012)
Tsai CW, Langner EH, Microporous Mesoporous Mater., 221, 8 (2016)
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Fu YY, Yang CX, Yan XP, Chem. Commun., 49, 7162 (2013)
Qiu LG, Xu T, Li ZQ, Wang W, Wu Y, Jiang X, Tian XY, Zhang LD, Angew. Chem.-Int. Edit., 47, 9487 (2008)
Sun LB, Li JR, Park J, Zhou HC, J. Am. Chem. Soc., 134, 126 (2011)
Jomekian A, Behbahani RM, Mohammadi T, Kargari A, J. Solid State Chem., 235, 212 (2016)
Kim JH, Ha SY, Lee YM, J. Membr. Sci., 190(2), 179 (2001)
Zhao D, Ren J, Li H, Hua K, Deng M, J. Energ. Chem., 23, 227 (2014)
Norrman K, Ghanbari-Siahkali A, Larsen NB, Annual Reports Section “C” (Physical Chemistry), 101, 174 (2005)
Burmann P, Zornoza B, Tellez C, Coronas J, Chem. Eng. Sci., 107, 66 (2014)
Shen Y, Lua AC, Chem. Eng. J., 188, 199 (2012)
Bondi A, J. Phys. Chem., 68, 441 (1964)
Hua D, Ong YK, Wang Y, Yang TX, Chung TS, J. Membr. Sci., 453, 155 (2014)
Aroon MA, Ismail AF, Matsuura T, Montazer-Rahmati MM, Sep. Purif. Technol., 75(3), 229 (2010)
Ismail AF, Lorna W, Sep. Purif. Technol., 27(3), 173 (2002)
Ribeiro CP, Freernan BD, Paul DR, J. Membr. Sci., 377(1-2), 110 (2011)
Li Y, Chung TS, Int. J. Hydrog. Energy, 35(19), 10560 (2010)
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Dorosti F, Omidkhah M, Abedini R, J. Nat. Gas Sci. Eng., 25, 88 (2015)
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Mahajan R, Koros WJ, Polym. Eng. Sci., 42(7), 1432 (2002)
Moore TT, Mahajan R, Vu DQ, Koros WJ, AIChE J., 50(2), 311 (2004)
Vu DQ, Koros WJ, Miller SJ, J. Membr. Sci., 211(2), 311 (2003)
Ebrahimzadeh E, Matagi J, Fazlollahi F, Baxter LL, Appl. Therm. Eng., 96, 39 (2016)
Fazlollahi F, Bown A, Ebrahimzadeh E, Baxter LL, Energy, 90, 244 (2015)
Fazlollahi F, Bown A, Ebrahimzadeh E, Baxter LL, Energy, 103, 369 (2016)
Ebrahimzadeh E, Baxter LL, Appl. Therm. Eng., 102, 785 (2016)
Binns M, Oh SY, Kwak DH, Kim JK, Korean J. Chem. Eng., 32(3), 383 (2015)
Chen C, Kim J, Ahn WS, Korean J. Chem. Eng., 31(11), 1919 (2014)
Lin HQ, Van Wagner E, Raharjo R, Freeman BD, Roman I, Adv. Mater., 18(1), 39 (2006)
Rezakazemi M, Amooghin AE, Montazer-Rahmati MM, Ismail AF, Matsuura T, Prog. Polym. Sci, 39, 817 (2014)
Robeson LM, J. Membr. Sci., 320(1-2), 390 (2008)
Melgar VMA, Kim J, Othman MR, J. Ind. Eng. Chem., 28, 1 (2015)
Bastani D, Esmaeili N, Asadollahi M, J. Ind. Eng. Chem., 19(2), 375 (2013)
Venna SR, Carreon MA, Chem. Eng. Sci., 124, 3 (2015)
Nematollahi MH, Dehaghani AHS, Abedini R, Korean J. Chem. Eng., 33(2), 657 (2016)
Lilleparg J, Georgopanos P, Shishatskiy S, J. Membr. Sci., 467, 269 (2014)
Yang H, Xu Z, Fan M, Gupta R, Slimane RB, Bland AE, Wright I, J. Environ. Sci., 20, 14 (2008)
Buonomenna M, Yave W, Golemme G, RSC Adv., 2, 10745 (2012)
Hilke R, Pradeep N, Behzad AR, Nunes SP, Peinemann KV, J. Membr. Sci., 472, 39 (2014)
Ahmadpour E, Shamsabadi AA, Behbahani RM, Aghajani M, Kargari A, J. Nat. Gas Sci. Eng., 21, 518 (2014)
Ardestani MA, Babaluo AA, Peyravi M, Aghjeh MKR, Jannatdoost E, Desalination, 250(3), 1140 (2010)
Chen JC, Feng X, Penlidis A, Sep. Sci. Technol., 39, 149 (2005)
Chen YX, Wang B, Zhao L, Dutta P, Ho WSW, J. Membr. Sci., 495, 415 (2015)
Esposito E, Clarizia G, Bernardo P, Jansen JC, Sedlakova Z, Izak P, Curcio S, de Cindio B, Tasselli F, Chem. Eng. Process., 94, 53 (2015)
Feng S, Ren J, Li H, Hua K, Li X, Deng M, J. Energ. Chem., 22, 837 (2013)
Feng S, Ren J, Li Z, Li H, Hua K, Li X, Deng M, Int. J. Greenhouse Gas Control, 19, 41 (2013)
Ghadimi A, Mohammadi T, Kasiri N, Int. J. Hydrog. Energy, 40(31), 9723 (2015)
Li T, Pan Y, Peinemann KV, Lai Z, J. Membr. Sci., 425-426, 235 (2013)
Murali RS, Kumar KP, Ismail A, Sridhar S, Microporous Mesoporous Mater., 197, 291 (2014)
Murali RS, Sridhar S, Sankarshana T, Ravikumar YVL, Ind. Eng. Chem. Res., 49(14), 6530 (2010)
Nafisi V, Hagg MB, J. Membr. Sci., 459, 244 (2014)
Potreck J, Nijmeijer K, Kosinski T, Wessling M, J. Membr. Sci., 338(1-2), 11 (2009)
Rabiee H, Alsadat SM, Soltanieh M, Mousavi SA, Ghadimi A, J. Ind. Eng. Chem., 27, 223 (2015)
Rabiee H, Soltanieh M, Mousavi SA, Ghadimi A, J. Membr. Sci., 469, 43 (2014)
Rahman MM, Filiz V, Shishatskiy S, Abetz C, Neumann S, Bolmer S, Khan MM, Abetz V, J. Membr. Sci., 437, 286 (2013)
Rahman MM, Shishatskiy S, Abetz C, Georgopanos P, Neumann S, Khan MM, Filiz V, Abetz V, J. Membr. Sci., 469, 344 (2014)
Kim JH, Lee YM, J. Membr. Sci., 193(2), 209 (2001)
Murali RS, Ismail AF, Rahman MA, Sridhar S, Sep. Purif. Technol., 129, 1 (2014)
Cravillon J, Munzer S, Lohmeier SJ, Feldhoff A, Huber K, Wiebcke M, Chem. Mater., 21, 1410 (2009)
Fang MQ, Wu CL, Yang ZJ, Wang T, Xia Y, Li JD, J. Membr. Sci., 474, 103 (2015)
Hwang S, Chi WS, Lee SJ, Im SH, Kim JH, Kim J, J. Membr. Sci., 480, 11 (2015)
Lee YR, Jang MS, Cho BY, Kwon HJ, Kim S, Ahn WS, Chem. Eng. J., 271, 276 (2015)
Nordin NAHM, Ismail A, Mustafa A, Murali RS, Matsuura T, RSC Adv., 4, 52530 (2014)
Papporello RL, Miro EE, Zamaro JM, Microporous Mesoporous Mater., 211, 64 (2015)
Wang Y, Xu Y, Ma H, Xu R, Liu H, Li D, Tian Z, Microporous Mesoporous Mater., 195, 50 (2014)
Jomekian A, Behbahani RM, Mohammadi T, Kargari A, Microporous Mesoporous Mater., 234, 43 (2016)
Lee YR, Kim J, Ahn WS, Korean J. Chem. Eng., 30(9), 1667 (2013)
Cravillon J, Schroder CA, Nayuk R, Gummel J, Huber K, Wiebcke M, Angew. Chem.-Int. Edit., 123, 8217 (2011)
Cao S, Gody G, Zhao W, Perrier S, Peng X, Ducati C, Zhao D, Cheetham AK, Chem. Sci., 4, 3573 (2013)
Bustamante EL, Fernandez JL, Zamaro JM, J. Colloid Interface Sci., 424, 37 (2014)
Cravillon J, Nayuk R, Springer S, Feldhoff A, Huber K, Wiebcke M, Chem. Mater., 23, 2130 (2011)
Gross AF, Sherman E, Vajo JJ, J. Chem. Soc.-Dalton Trans., 41, 5458 (2012)
Tsai CW, Langner EH, Microporous Mesoporous Mater., 221, 8 (2016)
Yamamoto D, Maki T, Watanabe S, Tanaka H, Miyahara MT, Mae K, Chem. Eng. J., 227, 145 (2013)
Zhang P, Sun F, Xiang Z, Shen Z, Yun J, Cao D, Energy Environ. Sci., 7, 442 (2014)
Fu YY, Yang CX, Yan XP, Chem. Commun., 49, 7162 (2013)
Qiu LG, Xu T, Li ZQ, Wang W, Wu Y, Jiang X, Tian XY, Zhang LD, Angew. Chem.-Int. Edit., 47, 9487 (2008)
Sun LB, Li JR, Park J, Zhou HC, J. Am. Chem. Soc., 134, 126 (2011)
Jomekian A, Behbahani RM, Mohammadi T, Kargari A, J. Solid State Chem., 235, 212 (2016)
Kim JH, Ha SY, Lee YM, J. Membr. Sci., 190(2), 179 (2001)
Zhao D, Ren J, Li H, Hua K, Deng M, J. Energ. Chem., 23, 227 (2014)
Norrman K, Ghanbari-Siahkali A, Larsen NB, Annual Reports Section “C” (Physical Chemistry), 101, 174 (2005)
Burmann P, Zornoza B, Tellez C, Coronas J, Chem. Eng. Sci., 107, 66 (2014)
Shen Y, Lua AC, Chem. Eng. J., 188, 199 (2012)
Bondi A, J. Phys. Chem., 68, 441 (1964)
Hua D, Ong YK, Wang Y, Yang TX, Chung TS, J. Membr. Sci., 453, 155 (2014)
Aroon MA, Ismail AF, Matsuura T, Montazer-Rahmati MM, Sep. Purif. Technol., 75(3), 229 (2010)
Ismail AF, Lorna W, Sep. Purif. Technol., 27(3), 173 (2002)
Ribeiro CP, Freernan BD, Paul DR, J. Membr. Sci., 377(1-2), 110 (2011)
Li Y, Chung TS, Int. J. Hydrog. Energy, 35(19), 10560 (2010)
Dorosti F, Omidkhah M, Abedini R, Chem. Eng. Res. Des., 92(11), 2439 (2014)
Dorosti F, Omidkhah M, Abedini R, J. Nat. Gas Sci. Eng., 25, 88 (2015)
Mahajan R, Koros WJ, Polym. Eng. Sci., 42(7), 1420 (2002)
Mahajan R, Koros WJ, Polym. Eng. Sci., 42(7), 1432 (2002)
Moore TT, Mahajan R, Vu DQ, Koros WJ, AIChE J., 50(2), 311 (2004)
Vu DQ, Koros WJ, Miller SJ, J. Membr. Sci., 211(2), 311 (2003)
