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Received May 28, 2015
Accepted October 24, 2016
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Synthesis and characterization of polypyrrole doped by cage silsesquioxane with carboxyl groups
The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, 214122 Wuxi, P. R. China
Korean Journal of Chemical Engineering, February 2017, 34(2), 470-475(6), 10.1007/s11814-016-0296-y
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Abstract
Cage silsesquioxane with carboxyl groups (POSS-COOH) was successfully synthesized, after which it was added to polypyrrole (PPy) as a dopant to produce the doped PPy (PPy/POSS-COOH) solution. The PPy/POSSCOOH composites were characterized by FTIR (Fourier transformation infrared spectroscopy), SEM (Scanning electron microscopy), TGA (Thermo-gravimetric analysis), CV (Cyclic voltammetry) and RL (Reflection loss). Compared to PPy without POSS-COOH (un-PPy), the conductivity of PPy/POSS-COOH composites could be improved dramatically, reaching up to 0.850 S/cm at 25 °C. Under N2 atmosphere, the residual rate of PPy/POSS-COOH was 68% at 700 °C, 14% higher than the one of un-PPy. Meanwhile, PPy/POSS-COOH had a reflection loss below - 8 dB over 9.35 to 11.20GHz, with a minimum value of - 10.32 dB at 10.54 GHz, thus demonstrating higher microwave absorption than un-PPy. This method may provide a facile route to produce doped conducting polymers with POSS-COOH.
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References
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Li ZH, Wu DC, Liang YR, Fu RW, Matyjaszewski K, J. Am. Chem. Soc., 136(13), 4805 (2014)
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Phillips SH, Haddad TS, Tomczak SJ, Curr. opin. Solid State Mat. Sci., 8, 21 (2004)
Ni CH, Wu G, Zhu CP, Yao BL, J. Phys. Chem. C, 114, 13471 (2010)
Li QF, Xu YH, Yoon JS, Chen GX, J. Mater. Sci., 46(7), 2324 (2011)
Ak M, Gacal B, Kiskan B, Yagci Y, Toppare L, Polymer, 49(9), 2202 (2008)
Wang K, Guan X, Chai S, Zou Q, Zhang X, Zhang J, Biosens. Bioelectron., 64, 94 (2015)
Zhang ZP, Liang GZ, Lu TL, J. Appl. Polym. Sci., 103(4), 2608 (2007)
Feher FJ, Newman DA, Walzer JF, J. Am. Chem. Soc., 111, 1741 (1989)
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Wang ZZ, Bi H, Liu J, Sun T, Wu XL, J. Magn. Magn. Mater., 320, 2132 (2008)
