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Received July 26, 2016
Accepted October 15, 2016
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Heterogeneous photocatalytic degradation of phenol and derivatives by (BiPO4/H2O2/UV and TiO2/H2O2/UV) and the evaluation of plant seed toxicity tests
Léa Elias Mendes Carneiro Zaidan†
Joan Manuel Rodriguez-Díaz1
Daniella Carla Napoleão
Maria da Conceição Branco da Silva de Mendonça Montenegro2
Alberto da Nova Araújo2
Mohand Benachour
and Valdinete Lins da Silva
Chemical Engineering Department, Federal University of Pernambuco, Avenida Prof. Artur de Sá, s/n, 50740-521 Recife, Brazil 1Instituto de Investigación, Universidad Técnica de Manabí, Av. Urbina y Che Guevara, Portoviejo, Manabí, Ecuador 2Pharmacy Factory, REQUIMTE/Department of Chemical Sciences, University Porto, Rua Jorge Viterbo Ferreira, 228, Porto, 4050-313, Portugal
Korean Journal of Chemical Engineering, February 2017, 34(2), 511-522(12), 10.1007/s11814-016-0293-1
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Abstract
We examined the photocatalytic degradation of phenol from laboratory samples under UV radiation by using BiPO4/H2O2 and TiO2/H2O2 advanced oxidation systems. Both catalysts prepared were characterized by scanning electron microscopy, Fourier transform infrared and X-ray diffraction. Surface area tests showed about 3.46 and 31.33m2·g-1, respectively, for BiPO4 and TiO2. A central composite design was developed with the following variables--catalyst concentration, time and concentration of hydrogen peroxide--to optimize the degradation process. Removal rates of 99.99% for phenol degradation using BiPO4 and TiO2 were obtained, respectively. For mineralization of organic carbon were obtained 95,56% when using BiPO4 and 63,40% for TiO2, respectively. The lumped kinetic model represented satisfactorily the degradation of phenol process, using BiPO4/H2O2/UV (R2=0.9977) and TiO2/H2O2/UV (R2=0.9701) treatments. The toxicity tests using different seed species showed the benefits of the proposed advanced oxidation process when applied to waste waters containing these pollutants.
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